Fe(83.2-x)CoxP(10)C6Cu(0.8)(x=0,4,6,8 and 10)alloys with a high amorphous-forming ability and good softmagnetic properties were successfully synthesized.Saturation magnetic flux density(Bs)is effectively enhanced from...Fe(83.2-x)CoxP(10)C6Cu(0.8)(x=0,4,6,8 and 10)alloys with a high amorphous-forming ability and good softmagnetic properties were successfully synthesized.Saturation magnetic flux density(Bs)is effectively enhanced from 1.53 T to 1.61 T for as-quenched alloy by minor Co addition,which is consistent well with the result of the linear relationship between average magnetic moment and magnetic valence.For Cocontained alloys,the value of corecivity(Hc)is mainly determined by magneto-crystalline anisotropy,while effective permeability(μe)is dominated by grain size and average saturation polarization.After proper heat treatment,the Fe(79.2)Co4P(10)C6Cu(0.8)nanocrystalline alloy exhibited excellent soft-magnetic properties including a high Bsof 1.8 T,a low Hcof 6.6 A/m and a highμeof 15,510,which is closely related to the high volume fraction of α-(Fe,Co)grains and refined uniform nanocrystalline microstructure.展开更多
The Fe_(81.3)Si_(4)B_(13–x)PxCu_(1.7) soft magnetic alloys with high Cu and proper P elements addition were synthesized with the aim of ensuring the amorphous forming ability(AFA)while expanding the crystallization w...The Fe_(81.3)Si_(4)B_(13–x)PxCu_(1.7) soft magnetic alloys with high Cu and proper P elements addition were synthesized with the aim of ensuring the amorphous forming ability(AFA)while expanding the crystallization window(CW).It is found that the atomic ratio of P/Cu of∼3 is advantageous for AFA whereas a small amount of P addition promotes the precipitation ofα-Fe grains and excessive P addition induces surface crystallization behavior of the present alloys.High Cu concentration can expand the annealing temperature(Ta)window whereas proper P addition effectively expands the annealing time(ta)window.The Fe_(81.3)Si_(4)B_(13-x)PxCu_(1.7) soft magnetic alloy was successfully synthesized with a large Ta window of up to 130°C and ta window of 90 min,which is a breakthrough for nanocrystalline alloys with high saturation magnetization.Microstructure analysis reveals that the ultra-wide CW is related to the unique nucleation mechanism,that is,theα-Fe grains are precipitated attaching to the Cu or CuP clusters and enveloping the Cu clusters,resulting in the high number density ofα-Fe nanocrystals.The ultra-wide CW promises the potential material in flexibly choosing the annealing process according to the performance.展开更多
基金supported by the National Key Research and Development Program of China (Grant No. 2016YFB0300502)the National Natural Science Foundation of China (Grant Nos. 51631003, 51401052, 51871237 and 51501037)
文摘Fe(83.2-x)CoxP(10)C6Cu(0.8)(x=0,4,6,8 and 10)alloys with a high amorphous-forming ability and good softmagnetic properties were successfully synthesized.Saturation magnetic flux density(Bs)is effectively enhanced from 1.53 T to 1.61 T for as-quenched alloy by minor Co addition,which is consistent well with the result of the linear relationship between average magnetic moment and magnetic valence.For Cocontained alloys,the value of corecivity(Hc)is mainly determined by magneto-crystalline anisotropy,while effective permeability(μe)is dominated by grain size and average saturation polarization.After proper heat treatment,the Fe(79.2)Co4P(10)C6Cu(0.8)nanocrystalline alloy exhibited excellent soft-magnetic properties including a high Bsof 1.8 T,a low Hcof 6.6 A/m and a highμeof 15,510,which is closely related to the high volume fraction of α-(Fe,Co)grains and refined uniform nanocrystalline microstructure.
基金supported by the National Natural Science Foundation of China(No.51871237)the Natural Science Foundation of Jiangsu Province(No.BK20201282)Atom probe tomography research was conducted at the Inter-University 3D Atom Probe Tomography Unit of City University of Hong Kong supported by the CityU(No.9360161).
文摘The Fe_(81.3)Si_(4)B_(13–x)PxCu_(1.7) soft magnetic alloys with high Cu and proper P elements addition were synthesized with the aim of ensuring the amorphous forming ability(AFA)while expanding the crystallization window(CW).It is found that the atomic ratio of P/Cu of∼3 is advantageous for AFA whereas a small amount of P addition promotes the precipitation ofα-Fe grains and excessive P addition induces surface crystallization behavior of the present alloys.High Cu concentration can expand the annealing temperature(Ta)window whereas proper P addition effectively expands the annealing time(ta)window.The Fe_(81.3)Si_(4)B_(13-x)PxCu_(1.7) soft magnetic alloy was successfully synthesized with a large Ta window of up to 130°C and ta window of 90 min,which is a breakthrough for nanocrystalline alloys with high saturation magnetization.Microstructure analysis reveals that the ultra-wide CW is related to the unique nucleation mechanism,that is,theα-Fe grains are precipitated attaching to the Cu or CuP clusters and enveloping the Cu clusters,resulting in the high number density ofα-Fe nanocrystals.The ultra-wide CW promises the potential material in flexibly choosing the annealing process according to the performance.
