Tin (Sn) metal foil is a promising anode for next-generation high-energy–density lithium-ion batteries (LIBs) due to its high capacity and easy processibility. However, the pristine Sn foil anode suffers nonuniform a...Tin (Sn) metal foil is a promising anode for next-generation high-energy–density lithium-ion batteries (LIBs) due to its high capacity and easy processibility. However, the pristine Sn foil anode suffers nonuniform alloying/dealloying reaction with lithium (Li) and huge volume variation, leading to electrode pulverization and inferior electrochemical performance. Herein, we proposed that reduced grain size and elaborate porosity design of Sn foil can circumvent the nonuniform alloy reaction and buffer the volume change during the lithiation/delithiation cycling. Experimentally, we designed a three-dimensional interconnected porous Sn (3DIP-Sn) foil by a facile chemical alloying/dealloying approach, which showed improved electrochemical performance. The enhanced structure stability of the as-fabricated 3DIP-Sn foil was verified by chemo-mechanical simulations and experimental investigation. As expected, the 3DIP-Sn foil anode revealed a long cycle lifespan of 4400 h at 0.5 mA cm^(−2) and 1 mAh cm^(−2) in Sn||Li half cells. A 3DIP-Sn||LiFePO_(4) full cell with LiFePO_(4) loading of 7.1 mg cm^(−2) exhibited stable cycling for 500 cycles with 80% capacity retention at 70 mA g^(−1). Pairing with high-loading commercial LiNi0.6Co0.2Mn0.2O_(2) (NCM622, 18.4 mg cm^(−2)) cathode, a 3DIP-Sn||NCM622 full cell delivered a high reversible capacity of 3.2 mAh cm^(−2). These results demonstrated the important role of regulating the uniform alloying/dealloying reaction and circumventing the localized strain/stress in improving the electrochemical performance of Sn foil anodes for advanced LIBs.展开更多
An optimization strategy is presented concerning the aerodynamic performance of an impeller at the design point with a constraint of efficiency at the stall point, on the basis of the combination of three-dimensional ...An optimization strategy is presented concerning the aerodynamic performance of an impeller at the design point with a constraint of efficiency at the stall point, on the basis of the combination of three-dimensional inverse design method and the response surface methodology (RSM). A specific inlet angular momentum is given in the prescribed blade loading to facilitate the change of the blade inlet angle at either the hub or shroud of the impeller. Three variables, the inlet angular momentums at both the hub and shroud as well as a coefficient relation with blade loading, were chosen as the optimization variables after a sensitivity analysis, which is conducted by means of the orthogonal design experiment. The candidate impellers were generated by different angular momentum distributions determined by the Box-Behnken design, and the performances of corresponding compressors were simulated. The response surface models of the performances of the compressors were obtained at the design and stall points. Thus the optimal impeller was obtained and the compressor’s performance at the design flow rate could be predicted under the constraint of a specified efficiency at the stall flow rate. A comparison between the computational results of the original and optimized impeller indicates that a considerable improvement of the efficiency of the compressor over the whole working range is obtained, which confirms the validity of the optimization strategy.展开更多
Scheduled maintenance and condition-based online monitoring are among the focal points of recent research to enhance nuclear plant safety.One of the most effective ways to monitor plant conditions is by implementing a...Scheduled maintenance and condition-based online monitoring are among the focal points of recent research to enhance nuclear plant safety.One of the most effective ways to monitor plant conditions is by implementing a full-scope,plant-wide fault diagnostic system.However,most of the proposed diagnostic techniques are perceived as unreliable by operators because they lack an explanation module,their implementation is complex,and their decision/inference path is unclear.Graphical formalism has been considered for fault diagnosis because of its clear decision and inference modules,and its ability to display the complex causal relationships between plant variables and reveal the propagation path used for fault localization in complex systems.However,in a graphbased approach,decision-making is slow because of rule explosion.In this paper,we present an enhanced signed directed graph that utilizes qualitative trend evaluation and a granular computing algorithm to improve the decision speed and increase the resolution of the graphical method.We integrate the attribute reduction capability of granular computing with the causal/fault propagation reasoning capability of the signed directed graph and comprehensive rules in a decision table to diagnose faults in a nuclear power plant.Qualitative trend analysis is used to solve the problems of fault diagnostic threshold selection and signed directed graph node state determination.The similarity reasoning and detection ability of the granular computing algorithm ensure a compact decision table and improve the decision result.The performance of the proposed enhanced system was evaluated on selected faults of the Chinese Fuqing 2 nuclear reactor.The proposed method offers improved diagnostic speed and efficient data processing.In addition,the result shows a considerable reduction in false positives,indicating that the method provides a reliable diagnostic system to support further intervention by operators.展开更多
Metallic tin(Sn)foil is a promising candidate anode for lithium-ion batteries(LIBs)due to its metallurgical processability and high capacity.However,it suffers low initial Coulombic efficiency and inferior cycling sta...Metallic tin(Sn)foil is a promising candidate anode for lithium-ion batteries(LIBs)due to its metallurgical processability and high capacity.However,it suffers low initial Coulombic efficiency and inferior cycling stability due to its uneven alloying/dealloying reactions,large volume change and stress,and fast electrode structural degradation.Herein,we report an undulating LiSn electrode fabricated by a scalable two-step procedure involving mechanical lithography and chemical prelithiation of Sn foil.With the combination of experimental measurements and chemo-mechanical simulations,it was revealed the obtained undulating LiSn/Sn electrode could ensure better mechanical stability due to the pre-swelling state from Sn to Li x Sn and undulating structure of lithography in comparison with plane Sn,homogenize the electrochemical alloying/dealloying reactions due to the activated surface materials,and compensate Li loss during cycling due to the introduction of excess Li from Li_(x)Sn,thus enabling enhanced electrochemical performance.Symmetric cells consisting of undulating LiSn/Sn electrode with an active thickness of∼5 um displayed stable cycling over 1000 h at 1 mA cm^(-2) and 1 mAh cm^(-2) with a low average overpotential of<15 mV.When paired with commercial LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)(NCM622)cathode with high mass loading of 15.8 mg cm^(-2),the full cell demonstrated a high capacity of 2.4 mAh cm^(-2) and outstanding cycling stability with 84.9% capacity retention at 0.5 C after 100 cycles.This work presents an advanced LiSn electrode with stress-regulation design toward high-performance LIBs,and sheds light on the rational electrode design and processing of other high-capacity lithium alloy anodes.展开更多
The high flow-rate centrifugal fan needs a three-dimensional impeller to achieve a high efficiency. In this paper, the design procedure of a high-efficiency three-dimensional centrifugal fan is presented. First, the m...The high flow-rate centrifugal fan needs a three-dimensional impeller to achieve a high efficiency. In this paper, the design procedure of a high-efficiency three-dimensional centrifugal fan is presented. First, the main dimensions of the fan were calculated by using the conventional one-dimensional method. Then, the blade loading or the angular momentum distribution along the meridional streamline on the blade surfaces is prescribed. After that, the three-dimensional blade is determined by using the streamline curvature method. With the aid of numerical simulations, the performance of the three-dimensional fan was improved and some of the key influence factors were investigated. The analyses indicate that, as to the high flow-rate centrifugal fan, the Stanitz modified formula is recommended to calculate the separation radius, rb. A proper increase in the separation radius is beneficial for the fan’s performance. It is also indicated that a decrease in the angular momentum on the hub leads to an increase in total pressure efficiency, under the condition of a given constant mean angular momentum at the outlet of the blade. In addition, the installation of a fairing on the hub plate can improve the fan’s efficiency evidently when the streamline curvature method is adopted to design the three-dimensional impeller.展开更多
In this study,large-scale Te-doped polycrystalline SnSe nanopowders were synthesized by a facile hydrothermal approach and the effect of Te doping on the thermoelectric properties of SnSe was fully investigated.It is ...In this study,large-scale Te-doped polycrystalline SnSe nanopowders were synthesized by a facile hydrothermal approach and the effect of Te doping on the thermoelectric properties of SnSe was fully investigated.It is found that the carrier concentration increases due to the reduction of band gap by alloying with Te,which contributes to significant enhancement of electrical conductivity especially at room temperature.Combined with the moderated Seebeck coefficient,a high power factor of 4.59μW cm 1 K 2 is obtained at 773 K.Furthermore,the lattice the rmal conductivity is greatly reduced upon Te substitution owing to the atomic point defect scattering.Benefiting from the synergistically optimized both electrical-and thermal-transport properties by Te-doping,thermoelectric performance of polycrystalline SnSe is enhanced in the whole temperature range with a maximum ZT of-0.79 at a relatively low temperature(773 K) for SnSe0.85Te0.15.This study provides a low-cost and simple lowtemperature method to mass production of SnSe with high thermoelectric performance for practical applications.展开更多
The attack angle may greatly affect the hypersonic plasma sheaths around the re-entry vehicle,thereby affecting the transmission characteristics of electromagnetic(EM)waves in the sheaths.In this paper,we propose an i...The attack angle may greatly affect the hypersonic plasma sheaths around the re-entry vehicle,thereby affecting the transmission characteristics of electromagnetic(EM)waves in the sheaths.In this paper,we propose an integrated three-dimensional(3D)model with various attack angles and realistic flying conditions of radio attenuation measurement C-II(RAM C-II)re-entry tasks for analyzing the effect of the attack angle on the transmission characteristics of EM waves in the sheaths.It is shown that the electron density and collision frequency of the sheath on the windward side can be increased by an order of magnitude with the increase of the attack angle.Meanwhile,the thickness of the sheath on the leeward side is increased where the electron density and collision frequency are reduced.The EM waves are mainly reflected on the windward plasma sheath due to the cutoff effect,and the radio-frequency(RF)blackout is mitigated if the antenna is positioned on the leeward side.Thus,by planning the trajectory properly and installing the antenna accordingly during the re-entry,it is possible to provide an approach for mitigation of the RF blackout problem to an extent.展开更多
The efficient development and exploitation of shale oil depends on long-distance horizontal wells. As the degreeof cleaning of the wellbore plays a key role in these processes, in this study, this problem is investiga...The efficient development and exploitation of shale oil depends on long-distance horizontal wells. As the degreeof cleaning of the wellbore plays a key role in these processes, in this study, this problem is investigated experimentallyby focusing on the dimensionless cuttings bed height. A method is proposed to calculate the horizontalwellhydraulic extension taking into account the influence of the wellbore cleaning degree on the wellborepressure distribution and assess the effect of a variety of factors such as the bottom hole pressure, the circulatingpressure drop, the drilling pump performance and the formation properties. The analysis shows that the hydraulicextension of horizontal wells decreases with an increase in the cuttings bed height, and the higher the displacementof drilling fluid, the faster the hydraulic extension declines. The annular pressure drop of the horizontalsection increases with the increase of the cuttings bed height, resulting in a higher bottom-hole pressure. Severalarguments are provided to guide the safe drilling of shale oil horizontal wells and overcome the limits of currenttechnological approaches.展开更多
Organic luminescent radicals are promising for optoelectronic applications,yet their practical implementation remains hindered by aggregation-caused quenching(ACQ)in aggregated states.In this study,we present a molecu...Organic luminescent radicals are promising for optoelectronic applications,yet their practical implementation remains hindered by aggregation-caused quenching(ACQ)in aggregated states.In this study,we present a molecular design strategy that enables unprecedented intrinsic luminescence from pure radicals across multiple aggregated states,including crystalline states,powders,and amorphous films,through the incorporation of sterically demanding TPP(2,4,6-triisopropylphenyl)groups.Comprehensive photophysical characterization coupled with structural analysis reveals that the TPP moieties effectively suppress detrimental intermolecular interactions,particularly exchange coupling andπ–πstacking between radical centers.The luminescent properties were analyzed via systematic theoretical calculations.The universality of this design principle is further demonstrated through its successful application to diradical systems,including Chichibabin’s and Muller’s hydrocarbons,which exhibit significantly enhanced emission in aggregated states.This work establishes a generalizable strategy for designing stable and efficient luminescent radicals in aggregated states,opening new avenues for radical-based optoelectronic devices.展开更多
With the gradual upgradation of global energy consumption and the associated development of multi-energy sources,the pace of unified energy planning and design has been accelerated and the concept of multi-energy syst...With the gradual upgradation of global energy consumption and the associated development of multi-energy sources,the pace of unified energy planning and design has been accelerated and the concept of multi-energy system(MES)has been formed.The industrial structure of industrial park(IP)consists of production and marketing of multi-energy sources,which makes IP become an ideal application scenario for MES.The coupling between multi-sources raises the complexity level of IP,which requires the demand side analysis in IP as it enables customers to actively participate in energy planning and development.This paper presents the concept and operation strategies of integrated demand response(IDR),and its model classification is analyzed in detail.Optimization model and IDR with varying time period are studied in IP to determine their impacts on the system.A detailed survey of different techniques in both operation strategies and model classification is presented and the classification is based on pros and cons.Finally,key issues and outlooks are discussed.展开更多
This paper describes the research on a largescale dispatchable grid-connected photovoltaic(PV)system for supplying power to the grid for dispatch instead of supplying the electricity to a local load.In order to maximi...This paper describes the research on a largescale dispatchable grid-connected photovoltaic(PV)system for supplying power to the grid for dispatch instead of supplying the electricity to a local load.In order to maximise the value of the solar energy,a hybrid electricity storage consisting of batteries and supercapacitors is used with the PV system.This paper proposes a control strategy focusing on theDCpower at theDClink rather than at the grid-connected inverter.Two typical sets of real data,collected from existing sites,are used to demonstrate the practicality of the system.Finally,the simulation results are used to demonstrate the good performance and feasibility of the proposed system together with the proposed control strategy.展开更多
N-type Se&Lu-codoped Bi2Te3 nanopowders were prepared by hydrothermal method and sintered by spark plasma sintering technology to form dense samples.By further doping Se element into Lu-doped Bi2Te3 samples,the th...N-type Se&Lu-codoped Bi2Te3 nanopowders were prepared by hydrothermal method and sintered by spark plasma sintering technology to form dense samples.By further doping Se element into Lu-doped Bi2Te3 samples,the thickness of the nanosheets has the tendency to become thinner.The electrical conductivity of Lu0.1Bi1.9Te3−xSex material is reduced with the increasing Se content due to the reduced carrier concentration,while the Seeback coefficient values are enhanced.The lattice thermal conductivity of the Lu0.1Bi1.9Te3−xSex is greatly reduced due to the introduced point defects and atomic mass fluctuation.Finally,the Lu0.1Bi1.9Te2.7Se0.3 sample obtained a maximum ZT value of 0.85 at 420 K.This study provides a low-cost and simple low-temperature method to mass production of Se&Lu-codoped Bi2Te3 with high thermoelectric performance for practical applications.展开更多
Radical-based light-emitting diodes are an innovative type of organic light-emitting diodes(OLEDs),which adopt luminescent radicals as emitters,aiming at improving the external quantum efficiency(EQE)of OLEDs.Research...Radical-based light-emitting diodes are an innovative type of organic light-emitting diodes(OLEDs),which adopt luminescent radicals as emitters,aiming at improving the external quantum efficiency(EQE)of OLEDs.Research on luminescent radicals and the corresponding devices is a multidisciplinary field involving organic chemistry,solid-state physics,photochemistry,electronics,and others.The relevant theories have been established step-by-step in recent years.展开更多
Solar cells convert sun light into electricity,but have the major drawbacks of high initial cost,low photo-conversion efficiency and intermittency.The current-voltage characteristics of the solar cells depend on solar...Solar cells convert sun light into electricity,but have the major drawbacks of high initial cost,low photo-conversion efficiency and intermittency.The current-voltage characteristics of the solar cells depend on solar insolation level and temperature,which lead to the variation of the maximum power point(MPP).Herein,to improve photovoltaic(PV)system efficiency,and increase the lifetime of the battery,a microcontroller-based battery charge controller with maximum power point tracker(MPPT)is designed for harvesting the maximum power available from the PV system under given insolation and temperature conditions.Among different MPPT techniques,perturb and observe(P&O)technique gives excellent results and thus is used.This work involves the design of MPPT charge controller using DC/DC buck converter and microcontroller.A prototype MPPT charge controller is tested with a 200 W PV panel and lead acid battery.The results show that the designed MPPT controller improves the efficiency of the PV panel when compared to conventional charge controllers.展开更多
基金This work is financially supported by the National Natural Science Foundation of China(Grant Nos.52072137,51802105).
文摘Tin (Sn) metal foil is a promising anode for next-generation high-energy–density lithium-ion batteries (LIBs) due to its high capacity and easy processibility. However, the pristine Sn foil anode suffers nonuniform alloying/dealloying reaction with lithium (Li) and huge volume variation, leading to electrode pulverization and inferior electrochemical performance. Herein, we proposed that reduced grain size and elaborate porosity design of Sn foil can circumvent the nonuniform alloy reaction and buffer the volume change during the lithiation/delithiation cycling. Experimentally, we designed a three-dimensional interconnected porous Sn (3DIP-Sn) foil by a facile chemical alloying/dealloying approach, which showed improved electrochemical performance. The enhanced structure stability of the as-fabricated 3DIP-Sn foil was verified by chemo-mechanical simulations and experimental investigation. As expected, the 3DIP-Sn foil anode revealed a long cycle lifespan of 4400 h at 0.5 mA cm^(−2) and 1 mAh cm^(−2) in Sn||Li half cells. A 3DIP-Sn||LiFePO_(4) full cell with LiFePO_(4) loading of 7.1 mg cm^(−2) exhibited stable cycling for 500 cycles with 80% capacity retention at 70 mA g^(−1). Pairing with high-loading commercial LiNi0.6Co0.2Mn0.2O_(2) (NCM622, 18.4 mg cm^(−2)) cathode, a 3DIP-Sn||NCM622 full cell delivered a high reversible capacity of 3.2 mAh cm^(−2). These results demonstrated the important role of regulating the uniform alloying/dealloying reaction and circumventing the localized strain/stress in improving the electrochemical performance of Sn foil anodes for advanced LIBs.
文摘An optimization strategy is presented concerning the aerodynamic performance of an impeller at the design point with a constraint of efficiency at the stall point, on the basis of the combination of three-dimensional inverse design method and the response surface methodology (RSM). A specific inlet angular momentum is given in the prescribed blade loading to facilitate the change of the blade inlet angle at either the hub or shroud of the impeller. Three variables, the inlet angular momentums at both the hub and shroud as well as a coefficient relation with blade loading, were chosen as the optimization variables after a sensitivity analysis, which is conducted by means of the orthogonal design experiment. The candidate impellers were generated by different angular momentum distributions determined by the Box-Behnken design, and the performances of corresponding compressors were simulated. The response surface models of the performances of the compressors were obtained at the design and stall points. Thus the optimal impeller was obtained and the compressor’s performance at the design flow rate could be predicted under the constraint of a specified efficiency at the stall flow rate. A comparison between the computational results of the original and optimized impeller indicates that a considerable improvement of the efficiency of the compressor over the whole working range is obtained, which confirms the validity of the optimization strategy.
基金supported by the project of State Key Laboratory of Nuclear Power Safety Monitoring Technology and Equipment(No.KA2019.418)the Foundation of Science and Technology on Reactor System Design Technology Laboratory(HT-KFKT-14-2017003)+1 种基金the technical support project for Suzhou Nuclear Power Research Institute(SNPI)(No.029-GN-B-2018-C45-P.0.99-00003)the project of the Research Institute of Nuclear Power Operation(No.RIN180149-SCCG)
文摘Scheduled maintenance and condition-based online monitoring are among the focal points of recent research to enhance nuclear plant safety.One of the most effective ways to monitor plant conditions is by implementing a full-scope,plant-wide fault diagnostic system.However,most of the proposed diagnostic techniques are perceived as unreliable by operators because they lack an explanation module,their implementation is complex,and their decision/inference path is unclear.Graphical formalism has been considered for fault diagnosis because of its clear decision and inference modules,and its ability to display the complex causal relationships between plant variables and reveal the propagation path used for fault localization in complex systems.However,in a graphbased approach,decision-making is slow because of rule explosion.In this paper,we present an enhanced signed directed graph that utilizes qualitative trend evaluation and a granular computing algorithm to improve the decision speed and increase the resolution of the graphical method.We integrate the attribute reduction capability of granular computing with the causal/fault propagation reasoning capability of the signed directed graph and comprehensive rules in a decision table to diagnose faults in a nuclear power plant.Qualitative trend analysis is used to solve the problems of fault diagnostic threshold selection and signed directed graph node state determination.The similarity reasoning and detection ability of the granular computing algorithm ensure a compact decision table and improve the decision result.The performance of the proposed enhanced system was evaluated on selected faults of the Chinese Fuqing 2 nuclear reactor.The proposed method offers improved diagnostic speed and efficient data processing.In addition,the result shows a considerable reduction in false positives,indicating that the method provides a reliable diagnostic system to support further intervention by operators.
基金This work is financially supported by the Natural Science Foundation of China (Grant No.51802105,12172143,52002136)China Postdoctoral Science Foun-dation.
文摘Metallic tin(Sn)foil is a promising candidate anode for lithium-ion batteries(LIBs)due to its metallurgical processability and high capacity.However,it suffers low initial Coulombic efficiency and inferior cycling stability due to its uneven alloying/dealloying reactions,large volume change and stress,and fast electrode structural degradation.Herein,we report an undulating LiSn electrode fabricated by a scalable two-step procedure involving mechanical lithography and chemical prelithiation of Sn foil.With the combination of experimental measurements and chemo-mechanical simulations,it was revealed the obtained undulating LiSn/Sn electrode could ensure better mechanical stability due to the pre-swelling state from Sn to Li x Sn and undulating structure of lithography in comparison with plane Sn,homogenize the electrochemical alloying/dealloying reactions due to the activated surface materials,and compensate Li loss during cycling due to the introduction of excess Li from Li_(x)Sn,thus enabling enhanced electrochemical performance.Symmetric cells consisting of undulating LiSn/Sn electrode with an active thickness of∼5 um displayed stable cycling over 1000 h at 1 mA cm^(-2) and 1 mAh cm^(-2) with a low average overpotential of<15 mV.When paired with commercial LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)(NCM622)cathode with high mass loading of 15.8 mg cm^(-2),the full cell demonstrated a high capacity of 2.4 mAh cm^(-2) and outstanding cycling stability with 84.9% capacity retention at 0.5 C after 100 cycles.This work presents an advanced LiSn electrode with stress-regulation design toward high-performance LIBs,and sheds light on the rational electrode design and processing of other high-capacity lithium alloy anodes.
文摘The high flow-rate centrifugal fan needs a three-dimensional impeller to achieve a high efficiency. In this paper, the design procedure of a high-efficiency three-dimensional centrifugal fan is presented. First, the main dimensions of the fan were calculated by using the conventional one-dimensional method. Then, the blade loading or the angular momentum distribution along the meridional streamline on the blade surfaces is prescribed. After that, the three-dimensional blade is determined by using the streamline curvature method. With the aid of numerical simulations, the performance of the three-dimensional fan was improved and some of the key influence factors were investigated. The analyses indicate that, as to the high flow-rate centrifugal fan, the Stanitz modified formula is recommended to calculate the separation radius, rb. A proper increase in the separation radius is beneficial for the fan’s performance. It is also indicated that a decrease in the angular momentum on the hub leads to an increase in total pressure efficiency, under the condition of a given constant mean angular momentum at the outlet of the blade. In addition, the installation of a fairing on the hub plate can improve the fan’s efficiency evidently when the streamline curvature method is adopted to design the three-dimensional impeller.
基金funded by the Fundamental Research Funds for the Central Universities (No.2232020A-02)National Natural Science Foundation of China (Nos.51774096,51871053,51902333)+3 种基金Shanghai Committee of Science and Technology (No.18JC1411200)Program for Innovative Research Team in University of Ministry of Education of China (No.IRT16R13)financial support sponsored by Shanghai Sailing Program (No. 19YF1454000)Key Research Program of Frontier Sciences,CAS (No.ZDBS-LY-JSC037)。
文摘In this study,large-scale Te-doped polycrystalline SnSe nanopowders were synthesized by a facile hydrothermal approach and the effect of Te doping on the thermoelectric properties of SnSe was fully investigated.It is found that the carrier concentration increases due to the reduction of band gap by alloying with Te,which contributes to significant enhancement of electrical conductivity especially at room temperature.Combined with the moderated Seebeck coefficient,a high power factor of 4.59μW cm 1 K 2 is obtained at 773 K.Furthermore,the lattice the rmal conductivity is greatly reduced upon Te substitution owing to the atomic point defect scattering.Benefiting from the synergistically optimized both electrical-and thermal-transport properties by Te-doping,thermoelectric performance of polycrystalline SnSe is enhanced in the whole temperature range with a maximum ZT of-0.79 at a relatively low temperature(773 K) for SnSe0.85Te0.15.This study provides a low-cost and simple lowtemperature method to mass production of SnSe with high thermoelectric performance for practical applications.
基金supported by National Natural Science Foundation of China(Nos.92271202 and 92371105)。
文摘The attack angle may greatly affect the hypersonic plasma sheaths around the re-entry vehicle,thereby affecting the transmission characteristics of electromagnetic(EM)waves in the sheaths.In this paper,we propose an integrated three-dimensional(3D)model with various attack angles and realistic flying conditions of radio attenuation measurement C-II(RAM C-II)re-entry tasks for analyzing the effect of the attack angle on the transmission characteristics of EM waves in the sheaths.It is shown that the electron density and collision frequency of the sheath on the windward side can be increased by an order of magnitude with the increase of the attack angle.Meanwhile,the thickness of the sheath on the leeward side is increased where the electron density and collision frequency are reduced.The EM waves are mainly reflected on the windward plasma sheath due to the cutoff effect,and the radio-frequency(RF)blackout is mitigated if the antenna is positioned on the leeward side.Thus,by planning the trajectory properly and installing the antenna accordingly during the re-entry,it is possible to provide an approach for mitigation of the RF blackout problem to an extent.
基金supported by CNPC Key Core Technology Research Projects (2022ZG06)project funded by China Postdoctoral Science Foundation (2021M693508)Basic research and strategic reserve technology research fund project of institutes directly under CNPC.
文摘The efficient development and exploitation of shale oil depends on long-distance horizontal wells. As the degreeof cleaning of the wellbore plays a key role in these processes, in this study, this problem is investigated experimentallyby focusing on the dimensionless cuttings bed height. A method is proposed to calculate the horizontalwellhydraulic extension taking into account the influence of the wellbore cleaning degree on the wellborepressure distribution and assess the effect of a variety of factors such as the bottom hole pressure, the circulatingpressure drop, the drilling pump performance and the formation properties. The analysis shows that the hydraulicextension of horizontal wells decreases with an increase in the cuttings bed height, and the higher the displacementof drilling fluid, the faster the hydraulic extension declines. The annular pressure drop of the horizontalsection increases with the increase of the cuttings bed height, resulting in a higher bottom-hole pressure. Severalarguments are provided to guide the safe drilling of shale oil horizontal wells and overcome the limits of currenttechnological approaches.
基金supported by the National Key Research and Development Program of China(2023YFB3608902)the National Natural Science Foundation of China(Nos.22105054,22265009,62422404,62475116,and 52103210)+2 种基金the Collaborative Innovation Center Foundation of Hainan University(No.XTCX2022XXC02)the South China Sea New Star Innovation Talent Platform Project(No.NHXXRCXM202307)the Hainan University Start-up Fund,and the Natural Science Foundation of Jilin Province(No.20230101363JC).
文摘Organic luminescent radicals are promising for optoelectronic applications,yet their practical implementation remains hindered by aggregation-caused quenching(ACQ)in aggregated states.In this study,we present a molecular design strategy that enables unprecedented intrinsic luminescence from pure radicals across multiple aggregated states,including crystalline states,powders,and amorphous films,through the incorporation of sterically demanding TPP(2,4,6-triisopropylphenyl)groups.Comprehensive photophysical characterization coupled with structural analysis reveals that the TPP moieties effectively suppress detrimental intermolecular interactions,particularly exchange coupling andπ–πstacking between radical centers.The luminescent properties were analyzed via systematic theoretical calculations.The universality of this design principle is further demonstrated through its successful application to diradical systems,including Chichibabin’s and Muller’s hydrocarbons,which exhibit significantly enhanced emission in aggregated states.This work establishes a generalizable strategy for designing stable and efficient luminescent radicals in aggregated states,opening new avenues for radical-based optoelectronic devices.
基金supported by National Key R&D Program of China(No.2017YFB0903300)National Science Foundation of China(No.51777065)Beijing Natural Science Foundation(No.3182037).
文摘With the gradual upgradation of global energy consumption and the associated development of multi-energy sources,the pace of unified energy planning and design has been accelerated and the concept of multi-energy system(MES)has been formed.The industrial structure of industrial park(IP)consists of production and marketing of multi-energy sources,which makes IP become an ideal application scenario for MES.The coupling between multi-sources raises the complexity level of IP,which requires the demand side analysis in IP as it enables customers to actively participate in energy planning and development.This paper presents the concept and operation strategies of integrated demand response(IDR),and its model classification is analyzed in detail.Optimization model and IDR with varying time period are studied in IP to determine their impacts on the system.A detailed survey of different techniques in both operation strategies and model classification is presented and the classification is based on pros and cons.Finally,key issues and outlooks are discussed.
基金This work was supported by National High Technology Research and Development Program,“863 key technologies and development on large-scale grid-connected PV plants”(No.2011AA05A301).
文摘This paper describes the research on a largescale dispatchable grid-connected photovoltaic(PV)system for supplying power to the grid for dispatch instead of supplying the electricity to a local load.In order to maximise the value of the solar energy,a hybrid electricity storage consisting of batteries and supercapacitors is used with the PV system.This paper proposes a control strategy focusing on theDCpower at theDClink rather than at the grid-connected inverter.Two typical sets of real data,collected from existing sites,are used to demonstrate the practicality of the system.Finally,the simulation results are used to demonstrate the good performance and feasibility of the proposed system together with the proposed control strategy.
基金This work was funded by the Fundamental Research Funds for the Central Universities(No.2232020A-02)National Natural Science Foundation of China(Nos.51774096,51871053,51902333)+3 种基金Shanghai Committee of Science and Technology(18JC1411200)Program for Innovative Research Team in University of Ministry of Education of China(IRT_16R13)Q.Zhang acknowledges financial support sponsored by Shanghai Saiiling Program(19YF1454000)Key Research Program of Frontier Sciences,CAS(Grant No.ZDBS-LY-JSC037).
文摘N-type Se&Lu-codoped Bi2Te3 nanopowders were prepared by hydrothermal method and sintered by spark plasma sintering technology to form dense samples.By further doping Se element into Lu-doped Bi2Te3 samples,the thickness of the nanosheets has the tendency to become thinner.The electrical conductivity of Lu0.1Bi1.9Te3−xSex material is reduced with the increasing Se content due to the reduced carrier concentration,while the Seeback coefficient values are enhanced.The lattice thermal conductivity of the Lu0.1Bi1.9Te3−xSex is greatly reduced due to the introduced point defects and atomic mass fluctuation.Finally,the Lu0.1Bi1.9Te2.7Se0.3 sample obtained a maximum ZT value of 0.85 at 420 K.This study provides a low-cost and simple low-temperature method to mass production of Se&Lu-codoped Bi2Te3 with high thermoelectric performance for practical applications.
基金support from the National Natural Science Foundation of China(grant nos.51925303,91833304,and 51673080)the program“JLUSTIRT”(grant no.2019TD-33).
文摘Radical-based light-emitting diodes are an innovative type of organic light-emitting diodes(OLEDs),which adopt luminescent radicals as emitters,aiming at improving the external quantum efficiency(EQE)of OLEDs.Research on luminescent radicals and the corresponding devices is a multidisciplinary field involving organic chemistry,solid-state physics,photochemistry,electronics,and others.The relevant theories have been established step-by-step in recent years.
基金2016 national key R&D program of China to support low-carbon Winter Olympics of integrated smart grid demonstration project(2016YFB0900501).
文摘Solar cells convert sun light into electricity,but have the major drawbacks of high initial cost,low photo-conversion efficiency and intermittency.The current-voltage characteristics of the solar cells depend on solar insolation level and temperature,which lead to the variation of the maximum power point(MPP).Herein,to improve photovoltaic(PV)system efficiency,and increase the lifetime of the battery,a microcontroller-based battery charge controller with maximum power point tracker(MPPT)is designed for harvesting the maximum power available from the PV system under given insolation and temperature conditions.Among different MPPT techniques,perturb and observe(P&O)technique gives excellent results and thus is used.This work involves the design of MPPT charge controller using DC/DC buck converter and microcontroller.A prototype MPPT charge controller is tested with a 200 W PV panel and lead acid battery.The results show that the designed MPPT controller improves the efficiency of the PV panel when compared to conventional charge controllers.
