The high cost and poor durability of Pt nanoparticles(NPs)have always been great challenges to the commercialization of proton exchange membrane fuel cells(PEMFCs).Pt-based intermetallic NPs with a highly ordered stru...The high cost and poor durability of Pt nanoparticles(NPs)have always been great challenges to the commercialization of proton exchange membrane fuel cells(PEMFCs).Pt-based intermetallic NPs with a highly ordered structure are considered as promising catalysts for PEMFCs due to their high catalytic activity and stability.Here,we reported a facile method to synthesize N-doped carbon encapsulated PtZn intermetallic(PtZn@NC)NPs via the pyrolysis of Pt@Zn-based zeolitic imidazolate framework-8(Pt@ZIF-8)composites.The catalyst obtained at 800℃(10%-PtZn@NC-800)was found to exhibit a half-wave potential(Ev2)up to 0.912 V versus reversible hydrogen electrode(RHE)for the cathodic oxygen reduction reaction in an acidic medium,which shifted by 26 mV positively compared to the benchmark Pt/C catalyst.Besides,the mass activity and specific activity of 10%-PtZn@NC-800 at 0.9 V versus RHE were nearly 3 and 5 times as great as that of commercial Pt/C,respectively.It is worth noting that the PtZn@NC showed excel Ient stability in oxygen reducti on reacti on(ORR)with just 1 mV of the Ev2 loss after 5,000 cycles,which is superior to that of most reported PtM catalysts(especially those disordered solid solutions).Furthermore,such N-doped carb on shell encapsulated PtZn intermetallic NPs showed significa ntly enha need performances towards the anodic oxidation reaction of organic small molecules(such as methanol and formic acid).The synergistic effects of the N doped carbon encapsulation structure and intermetallic NPs are responsible for outstanding performances of the catalysts.This work provides us a new engineering strategy to acquire highly active and stable multifunctional catalysts for PEMFCs.展开更多
基金This work was supported by the National Key Research and Development Program of China(Nos.2017YFA0206500 and 2017YFA0206801)the National Basic Research Program of China(No.2015CB932301)the National Natural Science Foundation of China(Nos.21671163 and 21721001).
文摘The high cost and poor durability of Pt nanoparticles(NPs)have always been great challenges to the commercialization of proton exchange membrane fuel cells(PEMFCs).Pt-based intermetallic NPs with a highly ordered structure are considered as promising catalysts for PEMFCs due to their high catalytic activity and stability.Here,we reported a facile method to synthesize N-doped carbon encapsulated PtZn intermetallic(PtZn@NC)NPs via the pyrolysis of Pt@Zn-based zeolitic imidazolate framework-8(Pt@ZIF-8)composites.The catalyst obtained at 800℃(10%-PtZn@NC-800)was found to exhibit a half-wave potential(Ev2)up to 0.912 V versus reversible hydrogen electrode(RHE)for the cathodic oxygen reduction reaction in an acidic medium,which shifted by 26 mV positively compared to the benchmark Pt/C catalyst.Besides,the mass activity and specific activity of 10%-PtZn@NC-800 at 0.9 V versus RHE were nearly 3 and 5 times as great as that of commercial Pt/C,respectively.It is worth noting that the PtZn@NC showed excel Ient stability in oxygen reducti on reacti on(ORR)with just 1 mV of the Ev2 loss after 5,000 cycles,which is superior to that of most reported PtM catalysts(especially those disordered solid solutions).Furthermore,such N-doped carb on shell encapsulated PtZn intermetallic NPs showed significa ntly enha need performances towards the anodic oxidation reaction of organic small molecules(such as methanol and formic acid).The synergistic effects of the N doped carbon encapsulation structure and intermetallic NPs are responsible for outstanding performances of the catalysts.This work provides us a new engineering strategy to acquire highly active and stable multifunctional catalysts for PEMFCs.
