In order to clarify the relationship between the microstructural changes and the rheological behaviors of four chemically treated woods (delignified wood, hemicellulose-removed wood, DMSO swollen and decrystallization...In order to clarify the relationship between the microstructural changes and the rheological behaviors of four chemically treated woods (delignified wood, hemicellulose-removed wood, DMSO swollen and decrystallization treated wood), the stress relaxation of wood with three different moisture contents was determined during periodic temperature changes. The experi- mental results show that after wood relaxation for 4 h at 25 °C, the stress decays sharply when the temperature increases and 2 h later the stress recovers again when the temperature drops back to the original point. The additional stress relaxation, produced after tem- perature begins to increase, is mainly caused by the thermal swelling, molecular thermal movement and the break of a part of residual hydrogen bonds. The number of hydrogen bonds and the size and amount of cavities in various treated woods greatly affect the magnitude of the additional relaxed stress and the recovery stress.展开更多
It is very important to clarify the relationship of changes of molecular combinations in wood cell walls and the chemical rheological behavior during various chemical reagent treatments, for it would be helpful to dev...It is very important to clarify the relationship of changes of molecular combinations in wood cell walls and the chemical rheological behavior during various chemical reagent treatments, for it would be helpful to develop new wood modification technologies and to enrich the theory of chemical rheology of wood. Based on previous investigations on the chemorheological properties of wood by chemical treatments and the applied methods in chemical rheology of wool fibers, this paper proposes the study of various additional reagents to wood saturated in water for long periods of time in order to investigate the chemical rheology of wood, which can provide information about the character of combinations between wood molecules and the structural changes of molecules and further put forward the idea of modifying wood in a decrystallized state.展开更多
基金the National Natural Science Foundation of China (Grant No.30070606) and Graduate Cultivation Foundation of Beijing Forestry University(Grant No.304)
文摘In order to clarify the relationship between the microstructural changes and the rheological behaviors of four chemically treated woods (delignified wood, hemicellulose-removed wood, DMSO swollen and decrystallization treated wood), the stress relaxation of wood with three different moisture contents was determined during periodic temperature changes. The experi- mental results show that after wood relaxation for 4 h at 25 °C, the stress decays sharply when the temperature increases and 2 h later the stress recovers again when the temperature drops back to the original point. The additional stress relaxation, produced after tem- perature begins to increase, is mainly caused by the thermal swelling, molecular thermal movement and the break of a part of residual hydrogen bonds. The number of hydrogen bonds and the size and amount of cavities in various treated woods greatly affect the magnitude of the additional relaxed stress and the recovery stress.
基金Supported by the National Natural Science Foundation of China (Grant No.30070606) and Graduate Cultivation Foundation of Beijing Forestry University (Grant No.304)
文摘It is very important to clarify the relationship of changes of molecular combinations in wood cell walls and the chemical rheological behavior during various chemical reagent treatments, for it would be helpful to develop new wood modification technologies and to enrich the theory of chemical rheology of wood. Based on previous investigations on the chemorheological properties of wood by chemical treatments and the applied methods in chemical rheology of wool fibers, this paper proposes the study of various additional reagents to wood saturated in water for long periods of time in order to investigate the chemical rheology of wood, which can provide information about the character of combinations between wood molecules and the structural changes of molecules and further put forward the idea of modifying wood in a decrystallized state.
