Environmental cleaning is an important aspect of bacteria control.Ethyl cellulose microcapsules containing potassium monopersulfate(PMCM)were prepared by emulsified solvent diffusion method.The chemical structure and ...Environmental cleaning is an important aspect of bacteria control.Ethyl cellulose microcapsules containing potassium monopersulfate(PMCM)were prepared by emulsified solvent diffusion method.The chemical structure and microstructure of the obtained PMCM was characterized by methods of Fourier transform infrared spectroscopy(FT-IR),optical microscopy,scanning electron microscopy and X-ACT energy dispersive X-ray spectroscopy.The SEM micrographs of the PMCM containing 21.6%of C,46.8%of O,10.7%of S and 19.4%of K was relatively smooth.Thermal stability,sustained release performance,and antimicrobial activity of PMCM were investigated.The results showed that the drug loading and encapsulation efficiency of PMCM were 30.3%and 42.6%respectively.Potassium monopersulfate was fully released after 8 h,following a Fickian diffusion mechanism.Results showed that the microcapsules prepared with a high concentration of potassium monopersulfate solution showed a good antimicrobial effect.The microcapsule wall of the resulting PMCM increased with increasing ethyl cellulose content and had high thermal stability from the data of 69%residue rate.The excellent thermal stability and high sustained release performance of PMCM showed high application value.展开更多
Immediately following the Ms7.0 Lushan earthquake on April 20, 2013, using high-pass and low- pass filtering on the digital seismic stations in the Shanxi Province, located about 870-1,452 km from the earthquake epice...Immediately following the Ms7.0 Lushan earthquake on April 20, 2013, using high-pass and low- pass filtering on the digital seismic stations in the Shanxi Province, located about 870-1,452 km from the earthquake epicenter, we detected some earthquakes at a time corre- sponding to the first arrival of surface waves in high-pass filtering waveform. The earthquakes were especially noticed at stations in Youyu （YUY）, Shanzizao （SZZ）, Shanghuangzhuang （SHZ）, and Zhenchuan （ZCH）, which are located in a volcanic region in the Shanxi Province,but they were not listed in the Shanxi seismic observation report. These earthquakes occurred 4-50 rain after the passage of the maximum amplitude Rayleigh wave, and the periods of the surface waves were mainly between 15 and 20 s following. The Coulomb stresses caused by the Ray- leigh waves that acted on the four stations was about 0.001 MPa, which is a little lower than the threshold value of dynamic triggering, therefore, we may conclude that the Datong volcanic region is more sensitive to the Coulomb stress change. To verify, if the similar phenomena are widespread, we used the same filtering to observecontrastively continuous waveform data before, and 5 h after, the Ms7.0 Lushan earthquake and Ms9.0 Tohoku earthquake in 2011. The results show that the similar phenomena occur before the earthquakes, but the seis- micity rates after the earthquakes are remarkably increased. Since these weak earthquakes are quite small, it is hard to get clear phase arrival time from three or more stations to locate them. In addition, the travel time differences between P waves and S waves （S-P） are all less than 4 s, that means the events should occur in 34 km around the stations in the volcanic region. The stress of initial dynamic triggering of the Ms9.0 Tohoku earthquake was about 0.09 MPa, which is much higher than the threshold value of dynamic triggering stress. The earthquakes after the Ms9.0 Tohoku earthquake are related to dynamic triggering stress, but the events before the earthquake cannot be linked to seismic events, but may be related to the back- ground seismicity or from other kinds of local sources, such as anthropogenic sources （i.e., explosions）. Using two teleseismic filtering, the small background earthquakes in the Datong volcanic region occur frequently, thus we postulate that previous catalog does not apply bandpass filter to pick out the weak earthquakes, and some of the observed weak events were not triggered by changes in the dynamic stress field.展开更多
基金support From the Open Fund Project of Key Lab.of Biomass Energy and Material,Jiangsu Province(JSBEM201907)the Ordinary University Young Innovative Talents Project of Guangdong Province(2018KQNCX119).
文摘Environmental cleaning is an important aspect of bacteria control.Ethyl cellulose microcapsules containing potassium monopersulfate(PMCM)were prepared by emulsified solvent diffusion method.The chemical structure and microstructure of the obtained PMCM was characterized by methods of Fourier transform infrared spectroscopy(FT-IR),optical microscopy,scanning electron microscopy and X-ACT energy dispersive X-ray spectroscopy.The SEM micrographs of the PMCM containing 21.6%of C,46.8%of O,10.7%of S and 19.4%of K was relatively smooth.Thermal stability,sustained release performance,and antimicrobial activity of PMCM were investigated.The results showed that the drug loading and encapsulation efficiency of PMCM were 30.3%and 42.6%respectively.Potassium monopersulfate was fully released after 8 h,following a Fickian diffusion mechanism.Results showed that the microcapsules prepared with a high concentration of potassium monopersulfate solution showed a good antimicrobial effect.The microcapsule wall of the resulting PMCM increased with increasing ethyl cellulose content and had high thermal stability from the data of 69%residue rate.The excellent thermal stability and high sustained release performance of PMCM showed high application value.
基金supported by Office of Science and Technology in Shanxi province based on research Projects(2012011029)National Natural Science Foundation(41174086)+1 种基金Scientific and Technological Research Project in Shanxi province(20100311129-2,20090311084)the China Earthquake Administration Spark Project(XH1005,XH13004)
文摘Immediately following the Ms7.0 Lushan earthquake on April 20, 2013, using high-pass and low- pass filtering on the digital seismic stations in the Shanxi Province, located about 870-1,452 km from the earthquake epicenter, we detected some earthquakes at a time corre- sponding to the first arrival of surface waves in high-pass filtering waveform. The earthquakes were especially noticed at stations in Youyu （YUY）, Shanzizao （SZZ）, Shanghuangzhuang （SHZ）, and Zhenchuan （ZCH）, which are located in a volcanic region in the Shanxi Province,but they were not listed in the Shanxi seismic observation report. These earthquakes occurred 4-50 rain after the passage of the maximum amplitude Rayleigh wave, and the periods of the surface waves were mainly between 15 and 20 s following. The Coulomb stresses caused by the Ray- leigh waves that acted on the four stations was about 0.001 MPa, which is a little lower than the threshold value of dynamic triggering, therefore, we may conclude that the Datong volcanic region is more sensitive to the Coulomb stress change. To verify, if the similar phenomena are widespread, we used the same filtering to observecontrastively continuous waveform data before, and 5 h after, the Ms7.0 Lushan earthquake and Ms9.0 Tohoku earthquake in 2011. The results show that the similar phenomena occur before the earthquakes, but the seis- micity rates after the earthquakes are remarkably increased. Since these weak earthquakes are quite small, it is hard to get clear phase arrival time from three or more stations to locate them. In addition, the travel time differences between P waves and S waves （S-P） are all less than 4 s, that means the events should occur in 34 km around the stations in the volcanic region. The stress of initial dynamic triggering of the Ms9.0 Tohoku earthquake was about 0.09 MPa, which is much higher than the threshold value of dynamic triggering stress. The earthquakes after the Ms9.0 Tohoku earthquake are related to dynamic triggering stress, but the events before the earthquake cannot be linked to seismic events, but may be related to the back- ground seismicity or from other kinds of local sources, such as anthropogenic sources （i.e., explosions）. Using two teleseismic filtering, the small background earthquakes in the Datong volcanic region occur frequently, thus we postulate that previous catalog does not apply bandpass filter to pick out the weak earthquakes, and some of the observed weak events were not triggered by changes in the dynamic stress field.
