The small punch test technique facilitates the convenient acquisition of the mechanical properties of in-service equipment materials and the assessment of their remaining service life through sampling.However,the weld...The small punch test technique facilitates the convenient acquisition of the mechanical properties of in-service equipment materials and the assessment of their remaining service life through sampling.However,the weldability of components with thin walls after small punch sampling,such as ethylene cracking furnace tubes,requires further investigation.Therefore,the weldability of in-service ethylene cracking furnace tubes following small punch sampling was investigated through nondestructive testing,microstructural characterization,and mechanical testing.Additionally,the impact of small punch sampling size and residual stress on the creep performance of the specimens was studied using an improved ductility exhaustion model.The results indicate that both the surface and interior of the weld repair areas on new furnace tubes and service-exposed furnace tubes after small-punch sampling are defect-free,exhibiting good weld quality.The strength of the specimens after weld repair was higher than that before sampling,whereas toughness decreased.Weld repair following small punch sampling of furnace tubes is both feasible and necessary.Furthermore,a linear relationship was observed between specimen thickness,diameter,and creep fracture time.The residual stress of welding affects the creep performance of the specimen under different stresses.展开更多
The semi-hydrogenation of alkynes to alkenes is of great significance in the industrial production of pharmaceutical and fine chemicals.Electrochemical semi-hydrogenation(ECSH)has emerged as a promising alternative to...The semi-hydrogenation of alkynes to alkenes is of great significance in the industrial production of pharmaceutical and fine chemicals.Electrochemical semi-hydrogenation(ECSH)has emerged as a promising alternative to conventional thermochemical hydrogenation.However,its practical application is hindered by low reaction rate and competing hydrogen evolution reaction(HER).In this work,the controllable incorporation of sulfur into the lattice of Pd nanostructures is proposed to develop disordered and electron-deficient Pd-based nanosheets on Ni foam and enhance their ECSH performance of alkynes.Mechanistic investigations demonstrate that the electronic and geometric structures of Pd sites are optimized by lattice sulfur,which tunes the competitive adsorption of H*and alkynes,inherently inhibits the H*coupling and weakens alkene adsorption,thereby promotes the semi-hydrogenation of alkynes and prevents the over-hydrogenation of alkenes.The optimized Pd-based nanosheets exhibit efficient electrocatalytic semi-hydrogenation performance in an H-cell,achieving 97%alkene selectivity,94%Faradaic efficiency,and a reaction rate of 303.7μmol mgcatal.^(-1) h^(-1) using 4-methoxyphenylacetylene as the model substrate.Even in a membrane electrode assembly(MEA)configuration,the optimized Pd-based nanosheets achieves a single-cycle alkyne conversion of 96%and an alkene selectivity of 97%,with continuous production of alkene at a rate of 1901.1μmol mgcatal.^(-1) h^(-1).The potential-and time-independent selectivity,good substrate universality with excellent tolerance to active groups(C–Br/Cl/C]O,etc.)further highlight the potential of this strategy for advanced catalysts design and green chemistry.展开更多
In recent years,most studies of complex networks have focused on a single network and ignored the interaction of multiple networks,much less the coupling mechanisms between multiplex networks.In this paper we investig...In recent years,most studies of complex networks have focused on a single network and ignored the interaction of multiple networks,much less the coupling mechanisms between multiplex networks.In this paper we investigate synchronization phenomena in multilayer networks with nonidentical topological structures based on three specific coupling mechanisms:assortative,disassortative,and anti-assortative couplings.We find rich and complex synchronous dynamic phenomena in coupled networks.We also study the behavior of effective frequencies for layers I and II to understand the underlying microscopic dynamics occurring under the three different coupling mechanisms.In particular,the coupling mechanisms proposed here have strong robustness and effectiveness and can produce abundant synchronization phenomena in coupled networks.展开更多
OBJECTIVE:To evaluate the 10-year therapeutic efficacy of Traditional Chinese Medicine(TCM)using the Strengthening Spleen and Draining Dampness therapy in the management of idiopathic membranous nephropathy(IMN).METHO...OBJECTIVE:To evaluate the 10-year therapeutic efficacy of Traditional Chinese Medicine(TCM)using the Strengthening Spleen and Draining Dampness therapy in the management of idiopathic membranous nephropathy(IMN).METHODS:A single-center,retrospective analysis was conducted on patients diagnosed with IMN who met predefined inclusion and exclusion criteria.Data were collected from the Department of Nephrology at Longhua Hospital,affiliated with Shanghai University of Traditional Chinese Medicine,between January 2007 and December 2011.Clinical parameters including 24-h urinary protein,serum albumin,serum creatinine,and estimated glomerular filtration rate(e GFR,EPI)were assessed at baseline and at 1,3,5,and 10 years of follow-up.The efficacy of the Strengthening Spleen and Draining Dampness therapy was analyzed using repeated measures analysis of variance(ANOVA).Kaplan-Meier survival curves and multivariate proportional hazards model(Cox regression models)were employed to identify factors associated with treatment outcomes.RESULTS:A total of 265 patients were included,with a median follow-up duration of 96 months(36,122).TCM treatment significantly reduced 24-h urinary protein levels(P<0.001),and increased serum albumin levels(P<0.001),while serum creatinine remained stable(P=0.187).Remission rates at 1,3,5,and 10 years were 52.81%,69.71%,68.39%,and 72.36%,respectively,and the rates of avoiding composite outcome events at the same intervals were 98.27%,94.29%,94.19%,and 93.50%.In the subgroup receiving TCM only,remission rates were 56.67%,84.44%,76.32%,and 82.86%.For patients treated initially with Western Medicine followed by TCM,the rates were 52.83%,65.85%,67.47%and 67.75%.In the cohort of patients who received TCM as their first-line therapy,remission rates were 49.23%,62.50%,61.76%,and 69.23%.Multivariate Cox regression analysis revealed that the duration of TCM treatment[hazard ratio(HR)=0.826,95%confidence interval(CI)(0.779,0.876),P<0.001],presence of hypertension[HR=1.912,95%CI(1.181,3.094),P=0.008],baseline serum albumin level[HR=0.930,95%CI(0.894,0.969),P<0.001],and the rate of serum albumin increase within the first year of treatment[HR=0.930,95%CI(0.909,0.957),P<0.001]were significantly associated with clinical outcomes.CONCLUSION:The Strengthening Spleen and Draining Dampness therapy demonstrated robust short-and longterm efficacy in treating IMN,with high rates of remission and renal survival over 10 years.Key factors influencing clinical remission included the duration of TCM treatment,baseline serum albumin levels,the presence of hypertension,and the rate of increase in serum albumin within the first year.These findings suggest that this TCM approach provides a viable long-term treatment option for IMN.展开更多
直驱风电场并入弱交流电网次同步振荡(sub-synchronous oscillation,SSO)威胁电力系统安全运行,分析其次同步分量通路能够揭示系统内部次同步交互作用特性,并能够分别针对每条通路进行阻尼特性分析,目前尚无文献开展相关研究。针对上述...直驱风电场并入弱交流电网次同步振荡(sub-synchronous oscillation,SSO)威胁电力系统安全运行,分析其次同步分量通路能够揭示系统内部次同步交互作用特性,并能够分别针对每条通路进行阻尼特性分析,目前尚无文献开展相关研究。针对上述问题,该文首先建立直驱风电场并入弱交流电网系统闭环传递函数框图,并利用阻尼转矩法分析直驱风电机组直流电容主导的振荡模态。然后,基于传递函数框图,分析得到2条次同步分量通路:直驱风电场内部次同步分量通路以及直驱风电场和弱交流系统之间的次同步分量通路。最后,利用通路阻尼分析,结合时域仿真,分别分析直驱风电机组网侧控制器(grid side controller,GSC)参数对2条通路阻尼特性的影响。结果表明:GSC直流电压外环积分系数增大时,2条次同步分量通路的阻尼均减小;直流电压外环比例系数和电流内环比例、积分系数减小会导致直驱风电场内部次同步分量通路的阻尼减小。研究结果对阻尼控制器的设计有一定的指导意义。展开更多
基金supports provided by the National Natural Science Foundation of China(No.52372330).
文摘The small punch test technique facilitates the convenient acquisition of the mechanical properties of in-service equipment materials and the assessment of their remaining service life through sampling.However,the weldability of components with thin walls after small punch sampling,such as ethylene cracking furnace tubes,requires further investigation.Therefore,the weldability of in-service ethylene cracking furnace tubes following small punch sampling was investigated through nondestructive testing,microstructural characterization,and mechanical testing.Additionally,the impact of small punch sampling size and residual stress on the creep performance of the specimens was studied using an improved ductility exhaustion model.The results indicate that both the surface and interior of the weld repair areas on new furnace tubes and service-exposed furnace tubes after small-punch sampling are defect-free,exhibiting good weld quality.The strength of the specimens after weld repair was higher than that before sampling,whereas toughness decreased.Weld repair following small punch sampling of furnace tubes is both feasible and necessary.Furthermore,a linear relationship was observed between specimen thickness,diameter,and creep fracture time.The residual stress of welding affects the creep performance of the specimen under different stresses.
基金financially supported by the National Natural Science Foundation of China(51701127,92163209,12264053)Shenzhen Fundamental Research Program(JCYJ20220811170904003,JCYJ20210324094000001)+6 种基金Shenzhen Peacock Plan(20180703896C)Shenzhen Key Laboratory of 2D Metamaterials for Information Technology(ZDSYS201707271014468)the research projects of Guangdong Provincial Education Office(2024KCXTD064)ZJUHIC start-up fund(02090200-K02013002)Beijing Natural Science Foundation(JQ22004)the Natural Science Foundation of Hangzhou(2024SZRYBB020001)the Scientific Research and Innovation Project of Postgraduate Students in the Academic Degree of Yunnan University(KC-23234366).
文摘The semi-hydrogenation of alkynes to alkenes is of great significance in the industrial production of pharmaceutical and fine chemicals.Electrochemical semi-hydrogenation(ECSH)has emerged as a promising alternative to conventional thermochemical hydrogenation.However,its practical application is hindered by low reaction rate and competing hydrogen evolution reaction(HER).In this work,the controllable incorporation of sulfur into the lattice of Pd nanostructures is proposed to develop disordered and electron-deficient Pd-based nanosheets on Ni foam and enhance their ECSH performance of alkynes.Mechanistic investigations demonstrate that the electronic and geometric structures of Pd sites are optimized by lattice sulfur,which tunes the competitive adsorption of H*and alkynes,inherently inhibits the H*coupling and weakens alkene adsorption,thereby promotes the semi-hydrogenation of alkynes and prevents the over-hydrogenation of alkenes.The optimized Pd-based nanosheets exhibit efficient electrocatalytic semi-hydrogenation performance in an H-cell,achieving 97%alkene selectivity,94%Faradaic efficiency,and a reaction rate of 303.7μmol mgcatal.^(-1) h^(-1) using 4-methoxyphenylacetylene as the model substrate.Even in a membrane electrode assembly(MEA)configuration,the optimized Pd-based nanosheets achieves a single-cycle alkyne conversion of 96%and an alkene selectivity of 97%,with continuous production of alkene at a rate of 1901.1μmol mgcatal.^(-1) h^(-1).The potential-and time-independent selectivity,good substrate universality with excellent tolerance to active groups(C–Br/Cl/C]O,etc.)further highlight the potential of this strategy for advanced catalysts design and green chemistry.
基金Project supported by the National Natural Science Foundation of China(Grants Nos.71801066 and 71704046)the Natural Science Foundation of Anhui Province,China(Grant Nos.1808085QG225 and 1908085MA22)+1 种基金the FundamentalResearch Funds for the Central Universities,China(Grant Nos.JZ2020HGTB0021 and JZ2021HGTB0065)the Outstanding Young Talent Support Program in Universities of Anhui Province in 2020 year。
文摘In recent years,most studies of complex networks have focused on a single network and ignored the interaction of multiple networks,much less the coupling mechanisms between multiplex networks.In this paper we investigate synchronization phenomena in multilayer networks with nonidentical topological structures based on three specific coupling mechanisms:assortative,disassortative,and anti-assortative couplings.We find rich and complex synchronous dynamic phenomena in coupled networks.We also study the behavior of effective frequencies for layers I and II to understand the underlying microscopic dynamics occurring under the three different coupling mechanisms.In particular,the coupling mechanisms proposed here have strong robustness and effectiveness and can produce abundant synchronization phenomena in coupled networks.
基金Supported by the National Key Research and Development Project,Clinical Study on the Treatment of Refractory Membranous Nephropathy with the Treatment of Strengthening Spleen and Draining Dampness in Method using Single Group Target Value Method(No.2019YFC1709403)Systematic Study on the Diagnosis and Treatment Rules of Membranous Nephropathy in Traditional Chinese Medicine(No.2023YFC35033501,No.2023YFC35033503)。
文摘OBJECTIVE:To evaluate the 10-year therapeutic efficacy of Traditional Chinese Medicine(TCM)using the Strengthening Spleen and Draining Dampness therapy in the management of idiopathic membranous nephropathy(IMN).METHODS:A single-center,retrospective analysis was conducted on patients diagnosed with IMN who met predefined inclusion and exclusion criteria.Data were collected from the Department of Nephrology at Longhua Hospital,affiliated with Shanghai University of Traditional Chinese Medicine,between January 2007 and December 2011.Clinical parameters including 24-h urinary protein,serum albumin,serum creatinine,and estimated glomerular filtration rate(e GFR,EPI)were assessed at baseline and at 1,3,5,and 10 years of follow-up.The efficacy of the Strengthening Spleen and Draining Dampness therapy was analyzed using repeated measures analysis of variance(ANOVA).Kaplan-Meier survival curves and multivariate proportional hazards model(Cox regression models)were employed to identify factors associated with treatment outcomes.RESULTS:A total of 265 patients were included,with a median follow-up duration of 96 months(36,122).TCM treatment significantly reduced 24-h urinary protein levels(P<0.001),and increased serum albumin levels(P<0.001),while serum creatinine remained stable(P=0.187).Remission rates at 1,3,5,and 10 years were 52.81%,69.71%,68.39%,and 72.36%,respectively,and the rates of avoiding composite outcome events at the same intervals were 98.27%,94.29%,94.19%,and 93.50%.In the subgroup receiving TCM only,remission rates were 56.67%,84.44%,76.32%,and 82.86%.For patients treated initially with Western Medicine followed by TCM,the rates were 52.83%,65.85%,67.47%and 67.75%.In the cohort of patients who received TCM as their first-line therapy,remission rates were 49.23%,62.50%,61.76%,and 69.23%.Multivariate Cox regression analysis revealed that the duration of TCM treatment[hazard ratio(HR)=0.826,95%confidence interval(CI)(0.779,0.876),P<0.001],presence of hypertension[HR=1.912,95%CI(1.181,3.094),P=0.008],baseline serum albumin level[HR=0.930,95%CI(0.894,0.969),P<0.001],and the rate of serum albumin increase within the first year of treatment[HR=0.930,95%CI(0.909,0.957),P<0.001]were significantly associated with clinical outcomes.CONCLUSION:The Strengthening Spleen and Draining Dampness therapy demonstrated robust short-and longterm efficacy in treating IMN,with high rates of remission and renal survival over 10 years.Key factors influencing clinical remission included the duration of TCM treatment,baseline serum albumin levels,the presence of hypertension,and the rate of increase in serum albumin within the first year.These findings suggest that this TCM approach provides a viable long-term treatment option for IMN.
文摘直驱风电场并入弱交流电网次同步振荡(sub-synchronous oscillation,SSO)威胁电力系统安全运行,分析其次同步分量通路能够揭示系统内部次同步交互作用特性,并能够分别针对每条通路进行阻尼特性分析,目前尚无文献开展相关研究。针对上述问题,该文首先建立直驱风电场并入弱交流电网系统闭环传递函数框图,并利用阻尼转矩法分析直驱风电机组直流电容主导的振荡模态。然后,基于传递函数框图,分析得到2条次同步分量通路:直驱风电场内部次同步分量通路以及直驱风电场和弱交流系统之间的次同步分量通路。最后,利用通路阻尼分析,结合时域仿真,分别分析直驱风电机组网侧控制器(grid side controller,GSC)参数对2条通路阻尼特性的影响。结果表明:GSC直流电压外环积分系数增大时,2条次同步分量通路的阻尼均减小;直流电压外环比例系数和电流内环比例、积分系数减小会导致直驱风电场内部次同步分量通路的阻尼减小。研究结果对阻尼控制器的设计有一定的指导意义。
