The western Los Angeles(LA)wildfires of early January 2025 caused catastrophic social and environmental impacts,drawing widespread attention.This study investigates the characteristics of these wildfires and quantifie...The western Los Angeles(LA)wildfires of early January 2025 caused catastrophic social and environmental impacts,drawing widespread attention.This study investigates the characteristics of these wildfires and quantifies the influence of heat and drought on their likelihood using a copula-based Bayesian probability framework.The wildfires were characterized by burned area(BA)and intensity(fire radiative power,FRP).The criteria establishing the presence of“hot drought”conditions were identified using the 5-day Standardized Temperature Index(STI)and 75-day Standardized Precipitation Index(SPI),respectively.The wildfire outbreak began on 7 January 2025 and burned for more than six days,with the total burned area exceeding 245 km^(2) and the cumulative FRP exceeding 41060 MW.Based on satellite-derived active fire observations from 2001 to 2025,we estimate that such large and intense wildfires during LA’s rainy season represent a once-in-a-67-year event.The wildfires were largely driven by the combination of hot and dry conditions,which dried out soils and vegetation that had proliferated due to above-average precipitation in previous winter seasons,thereby providing abundant fuel.Our seasonal analysis reveals that extreme drought increased the probability of wildfires matching the 2025 intensity and BA by 54%and 75%,respectively.Hot drought further amplified these probabilities by 149%(intensity)and 210%(BA).These findings suggest an elevated risk of large wildfires under hot drought conditions,contributing to their expansion into the non-traditional fire season.展开更多
Perovskite oxides have been widely applied as an effective catalyst in heterogeneous catalysis.However,the rational design of active catalysts has been restricted by the lack of understanding of the electronic structu...Perovskite oxides have been widely applied as an effective catalyst in heterogeneous catalysis.However,the rational design of active catalysts has been restricted by the lack of understanding of the electronic structure.The correlations between surface properties and bulk electronic structure have been ignored.Herein,a simple handler of LaFeO_(3)with diluted HNO3 was employed to tune the electronic structure and catalytic properties.Experimental analysis and theoretical calculations elucidate that acid etching could raise the Fe valence and enhance Fe-O covalency in the octahedral structure,thereby lessening charge transfer energy.Enhanced Fe-O covalency could lower oxygen vacancy formation energy and enhance oxygen mobility.In-situ DRIFTS results indicated the inherent adsorption capability of Toluene and CO molecules has been greatly improved owing to higher Fe-O covalency.As compared,the catalysts after acid etching exhibited higher catalytic activity,and the T_(90)had a great reduction of 45 and 58℃ for toluene and CO oxidation,respectively.A deeper understanding of electronic structure in perovskite oxides may inspire the design of high-performance catalysts.展开更多
Elevation change monitoring of the Antarctic ice sheet has been a key issue in global change research.Satellite altimetry has been proven to be effective in detecting ice sheet variations. With the development of ICES...Elevation change monitoring of the Antarctic ice sheet has been a key issue in global change research.Satellite altimetry has been proven to be effective in detecting ice sheet variations. With the development of ICESat-2, many elevation observations can be used to derive elevation changes. However, the large amount of multitemporal data may include anomalous data points, increasing the uncertainty of the results. In this work, we improved the traditional repeat track method by introducing the Institute of Geodesy and Geophysics Ⅲ(IGGⅢ) method to obtain high-accuracy estimates of elevation change. The improved method was applied to analyze elevation changes along the transect from Zhongshan Station to Dome A in East Antarctica via ICESat-2 satellite altimetry data. The results show that the improved and traditional methods yield consistent numerical and spatial elevation change distributions. The elevation change calculated via the traditional method is 0.033 ± 0.131 m/yr, whereas the elevation change estimated via the IGGⅢ robust estimation method is 0.033 ± 0.109 m/yr from March 2019 to December 2021.In terms of spatial distribution, elevation changes in inland areas remain close to equilibrium, whereas regions with steeper ice sheet margins exhibit positive accumulation trends in elevation changes. The improved method reduces the standard error of the adjustment function from 0.975 to 0.691 m/yr. The improvement is particularly remarkable in the area between 72°S and 77°S. The results demonstrate that the IGGⅢ method effectively reduces errors caused by the inclusion of anomalous data and maintains the high data utilization rate of repeat-orbit methods.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.42471034,42330604)the Qing Lan Projectsupport from the National Key Scientific and Technological Infrastructure project“Earth System Numerical Simulation Facility”(EarthLab).
文摘The western Los Angeles(LA)wildfires of early January 2025 caused catastrophic social and environmental impacts,drawing widespread attention.This study investigates the characteristics of these wildfires and quantifies the influence of heat and drought on their likelihood using a copula-based Bayesian probability framework.The wildfires were characterized by burned area(BA)and intensity(fire radiative power,FRP).The criteria establishing the presence of“hot drought”conditions were identified using the 5-day Standardized Temperature Index(STI)and 75-day Standardized Precipitation Index(SPI),respectively.The wildfire outbreak began on 7 January 2025 and burned for more than six days,with the total burned area exceeding 245 km^(2) and the cumulative FRP exceeding 41060 MW.Based on satellite-derived active fire observations from 2001 to 2025,we estimate that such large and intense wildfires during LA’s rainy season represent a once-in-a-67-year event.The wildfires were largely driven by the combination of hot and dry conditions,which dried out soils and vegetation that had proliferated due to above-average precipitation in previous winter seasons,thereby providing abundant fuel.Our seasonal analysis reveals that extreme drought increased the probability of wildfires matching the 2025 intensity and BA by 54%and 75%,respectively.Hot drought further amplified these probabilities by 149%(intensity)and 210%(BA).These findings suggest an elevated risk of large wildfires under hot drought conditions,contributing to their expansion into the non-traditional fire season.
基金the National Natural Science Foundation of China(Nos.22376178,22322606,22276105)the National Key Research and Development Program of China(No.2022YFC3704300)the Beijing Natural Science Foundation(No.8222054).
文摘Perovskite oxides have been widely applied as an effective catalyst in heterogeneous catalysis.However,the rational design of active catalysts has been restricted by the lack of understanding of the electronic structure.The correlations between surface properties and bulk electronic structure have been ignored.Herein,a simple handler of LaFeO_(3)with diluted HNO3 was employed to tune the electronic structure and catalytic properties.Experimental analysis and theoretical calculations elucidate that acid etching could raise the Fe valence and enhance Fe-O covalency in the octahedral structure,thereby lessening charge transfer energy.Enhanced Fe-O covalency could lower oxygen vacancy formation energy and enhance oxygen mobility.In-situ DRIFTS results indicated the inherent adsorption capability of Toluene and CO molecules has been greatly improved owing to higher Fe-O covalency.As compared,the catalysts after acid etching exhibited higher catalytic activity,and the T_(90)had a great reduction of 45 and 58℃ for toluene and CO oxidation,respectively.A deeper understanding of electronic structure in perovskite oxides may inspire the design of high-performance catalysts.
基金supported by the National Key Research and Development Program of China under grant number 2023YFC2809103the Fundamental Research Funds for the Central Universities under grant numbers 2042022kf1204, 2042022kf1069, 2042023gf0012, 2042022dx0001+1 种基金the Hubei Provincial Natural Science Foundation of China under grant number 2022CFB081the State Key Laboratory of Geodesy and Earth's Dynamics, Innovation Academy for Precision Measurement Science and Technology under grant number SKLGED2023-2-6
文摘Elevation change monitoring of the Antarctic ice sheet has been a key issue in global change research.Satellite altimetry has been proven to be effective in detecting ice sheet variations. With the development of ICESat-2, many elevation observations can be used to derive elevation changes. However, the large amount of multitemporal data may include anomalous data points, increasing the uncertainty of the results. In this work, we improved the traditional repeat track method by introducing the Institute of Geodesy and Geophysics Ⅲ(IGGⅢ) method to obtain high-accuracy estimates of elevation change. The improved method was applied to analyze elevation changes along the transect from Zhongshan Station to Dome A in East Antarctica via ICESat-2 satellite altimetry data. The results show that the improved and traditional methods yield consistent numerical and spatial elevation change distributions. The elevation change calculated via the traditional method is 0.033 ± 0.131 m/yr, whereas the elevation change estimated via the IGGⅢ robust estimation method is 0.033 ± 0.109 m/yr from March 2019 to December 2021.In terms of spatial distribution, elevation changes in inland areas remain close to equilibrium, whereas regions with steeper ice sheet margins exhibit positive accumulation trends in elevation changes. The improved method reduces the standard error of the adjustment function from 0.975 to 0.691 m/yr. The improvement is particularly remarkable in the area between 72°S and 77°S. The results demonstrate that the IGGⅢ method effectively reduces errors caused by the inclusion of anomalous data and maintains the high data utilization rate of repeat-orbit methods.
