With the continuous advancement of social technology and the increasing awareness of health management,biomass-based triboelectric nanogenerator(TENG)displayed significant potential as flexible wearable electronics fo...With the continuous advancement of social technology and the increasing awareness of health management,biomass-based triboelectric nanogenerator(TENG)displayed significant potential as flexible wearable electronics for continuous foot gait monitoring.Nevertheless,existing biomass-based TENG often faces challenges of insufficient mechanical robustness and durability in practical applications,where they are prone to surface abrasion and structural fracture under continuous compression and friction,severely limiting their long-term performances.In order to address these challenges,this work proposed a multiscale crosslinking strategy,which strengthened the noncovalent interactions within the polymer by constructing multiple reinforcement networks,successfully fabricating a dual-network C-lignin-based triboelectric material(CLTM)with excellent durability and crack resistance.Among them,the optimal CLTM(PSGCL-0.2)exhibited high mechanical strength(strain 445%,tensile strength 41.56 MPa,Young's modulus 41.25 MPa,toughness 159.67 MJ/m^(3))and excellent cyclic stability(300 cycles)with versatile functionalities,including antibacterial,antioxidant,and UV-shielding properties,water stabilization(255.51 g/m^(2)/d),efficient photothermal conversion,and full recyclability.Furthermore,biomass-based TENG device assembled from PSGCL-0.2 achieved stable triboelectric output properties(102.5 V,2.9μA,and 61.3 nC),and sustainable for 2000 cycles,fast response time(68 ms),and excellent power density(325.9 mW/m^(2)),effectively converting mechanical energy into electrical energy.Especially,PSGCL 0.2 was also integrated into the wireless self-powered smart insole,successfully enabling real-time visual monitoring of plantar pressure distribution and dynamic gait.Meanwhile,combined with the machine learning algorithm,the self-powered smart insole achieved precise recognition and classification of eight different motion states with an accuracy of 98%.This study provides the feasible strategy for developing extremely stable and durable biomass-based TENG,aimed at advancing sustainable intelligent healthcare systems.展开更多
Layered oxides present compelling potential as cathode materials for sodium-ion batteries(SIBs).However,challenges including interfacial instability and sluggish reaction kinetics critically limit their rate capabilit...Layered oxides present compelling potential as cathode materials for sodium-ion batteries(SIBs).However,challenges including interfacial instability and sluggish reaction kinetics critically limit their rate capability and cycling performance.Herein,we introduce the water-soluble sodium polyacrylate(NaPAA)binder as a promising approach to mitigating these issues in P2-type layered oxides.The NaPAA binder facilitates the formation of a uniform Na^(+) conductive interfacial film,which protects the cathode against electrolyte-induced corrosion and effectively inhibits the dissolution of transition metals in P2-Na_(0.85)Li_(0.12)Ni_(0.22)Mn_(0.66)O_(2)(NLNMO).Furthermore,we elucidate the mechanism by which the NaPAA binder dynamically regulates the coordination of free anions at the electrode-electrolyte interface.This regulation reduces solvent decomposition and promotes the formation of a stable,ionically conductive layer.Consequently,the P2-NLNMO@NaPAA integrated electrode exhibits enhanced electrochemical performance,achieving an 89.2%capacity retention after 200 cycles at 0.2 C and delivering an initial capacity of 102.9 mA h g^(-1) even at 0℃.This study advances the fundamental understanding of binder-mediated interface engineering and demonstrates a scalable and eco-friendly manufacturing pathway for high-performance SIBs.展开更多
Asian rice comprises two major subspecies:Xian(X)and Geng(G),and the diverged resistance genes(R)have provided a foundation for breeding improved cultivars to control rice blast disease.After conducting two-phase alle...Asian rice comprises two major subspecies:Xian(X)and Geng(G),and the diverged resistance genes(R)have provided a foundation for breeding improved cultivars to control rice blast disease.After conducting two-phase allele mining using six updated FNP marker systems,the functional haplotypes at Pit,Pib,and Pi63 strictly diverged into the X-populations and were defined as X-R loci,while those at Pi54,Pi37,and Pi36 into the G-populations as G-R loci.The genic diversity at the three X-R loci(16 alleles)was twofold higher than that at the three G-R loci(8 alleles),and the allelic diversity in the Southern region(21 alleles)was nearly double that in the Northeastern region(11 alleles).Both observations reflect a significant difference in genetic diversity between X-and G-populations,and indicate that the effective R-genes mainly originated from X-subspecies.Based on the allelic structures characterized by a set of 10 parameters,8 and 16 alleles were respectively recognized as favorable and promising ones for the regional breeding programs.The genotypic structures of the two regional populations were almost different,indicating that the diverged alleles have been further assembled into two series of regional genotypes through long-term breeding programs,despite the presence of one-third of region-common alleles.The genotypic diversity in the Southern region(55 genotypes)was nearly twice as high as that in the Northeastern region(28),which perfectly reflects the aforementioned differences in both genic and allelic diversities.After analyzing the genotypic structures using a set of 13 parameters,4 and 23 genotypes,respectively,can be recommended as the favorable and promising ones for the regional breeding programs.The case study serves as a concrete sample of how to identify the favorable and promising alleles and genotypes,and beneficial parents based their comprehensive population structures for gene-designed breeding.展开更多
As the most abundant renewable aromatic biopolymer resource on the Earth,lignin has become a cutting-edge research hotspot in clean photocatalysis,thanks to the distinct highest occupied molecular-orbital and lowest u...As the most abundant renewable aromatic biopolymer resource on the Earth,lignin has become a cutting-edge research hotspot in clean photocatalysis,thanks to the distinct highest occupied molecular-orbital and lowest unoccupied molecular-orbital energy levels driven by the major β-O-4 linked bonds.However,the complex spatial architecture of functional groups,represented by benzene rings in the 3D intertwined macromolecular chains of lignin,and the challenge of enhancing carrier separation efficiency remain persistent obstacles hindering the development of lignin-based photocatalysts.Herein,a strategy of constructing lignin nanosphere-graphene oxide heterointerfaces(EL-GO)is proposed to comprehensively enhance the efficacy of functional groups and facilitate photoelectron migration modes.The recombination time of lightexcited photoelectrons is effectively prolonged by the π-π interactions between the“Donor site”and“Acceptor site”functional regions,along with the directional migration of photoelectrons between EL and GO.The photocatalytic efficiency of H_(2)O_(2) production using EL-GO is significantly enhanced under the protective mechanism of GO.To assess its potential,a prospect estimation of EL-GO in a lake containing various pollutants and metal ions was conducted,simulating real water conditions.This pioneering engineering effort aims to curb excessive consumption of fossil fuels and explore the green applications of lignin,thereby constructing a“carbon-neutral”feedstock system.展开更多
In this study,we developed a single-beam optical trap-based surface-enhanced Raman scattering(SERS)optofluidic molecular fingerprint spectroscopy detection system.This system utilizes a single-beam optical trap to con...In this study,we developed a single-beam optical trap-based surface-enhanced Raman scattering(SERS)optofluidic molecular fingerprint spectroscopy detection system.This system utilizes a single-beam optical trap to concentrate free silver nanoparticles(AgNPs)within an optofluidic chip,significantly enhancing SERS performance.We investigated the optical field distribution characteristics within the tapered fiber using COMSOL simulation software and established a MATLAB simulation model to validate the single-beam optical trap's effectiveness in capturing AgNPs,demonstrating the theoretical feasibility of our approach.To verify the particle capture efficacy of the system,we experimentally controlled the optical trap's on-off state to manage the capture and release of particles precisely.The experimental results indicated that the Raman signal intensity in the capture state was significantly higher than in the non-capture state,confirming that the single-beam optical trap effectively enhances the SERS detection capability of the optofluidic detection system.Furthermore,we employed Raman mapping techniques to investigate the impact of the capture area on the SERS effect,revealing that the spectral intensity of molecular fingerprints in the laser-trapping region is significantly improved.We successfully detected the Raman spectrum of crystal violet at a concentration of 10^(−9)mol/L and pesticide thiram at a concentration of 10^(−5)mol/L,further demonstrating the ability of the single-beam optical trap in enhancing the molecular fingerprint spectrum identification capability of the SERS optofluidic chips.The optical trapping SERS optofluidic detection system developed in this study,as a key component of an integrated optoelectronic sensing system,holds the potential for integration with portable high-power lasers and high-performance Raman spectrometers.This integration is expected to advance highly integrated technologies and significantly enhance the overall performance and portability of optoelectronic sensing systems.展开更多
Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based catalysts.By introducing a third metal int...Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based catalysts.By introducing a third metal into NiFe-based catalysts to construct asymmetrical M-NiFe units,the d-orbital and electronic structures can be adjusted,which is an important strategy to achieve sufficient oxygen evolution reaction(OER)performance in AEMWEs.Herein,the ternary NiFeM(M:La,Mo)catalysts featured with distinct M-NiFe units and varying d-orbitals are reported in this work.Experimental and theoretical calculation results reveal that the doping of La leads to optimized hybridization between d orbital in NiFeM and 2p in oxygen,resulting in enhanced adsorption strength of oxygen intermediates,and reduced rate-determining step energy barrier,which is responsible for the enhanced OER performance.More critically,the obtained NiFeLa catalyst only requires 1.58 V to reach 1 A cm^(−2) in an anion exchange membrane electrolyzer and demonstrates excellent long-term stability of up to 600 h.展开更多
基金supported by the grants from National Natural Science Foundation of China(Nos.22278091,22278046)Young Elite Sci-entists Sponsorship Program by CAST(No.2024QNRC0387)+2 种基金the Guangxi Natural Science Foundation of China(Nos.2025GXNSFBA069146,2023GXNSFGA026001,GKAD25069076)the Foundation(No.202403)of Tianjin Key Laboratory of Pulp&Paper(Tianjin University of Science&Technology)P.R.China,and the Foundation of Guangxi Key Laboratory of Clean Pulp&Papermaking and Pollution Control,College of Light Industry and Food Engineering,Guangxi University(No.2021KF01).
文摘With the continuous advancement of social technology and the increasing awareness of health management,biomass-based triboelectric nanogenerator(TENG)displayed significant potential as flexible wearable electronics for continuous foot gait monitoring.Nevertheless,existing biomass-based TENG often faces challenges of insufficient mechanical robustness and durability in practical applications,where they are prone to surface abrasion and structural fracture under continuous compression and friction,severely limiting their long-term performances.In order to address these challenges,this work proposed a multiscale crosslinking strategy,which strengthened the noncovalent interactions within the polymer by constructing multiple reinforcement networks,successfully fabricating a dual-network C-lignin-based triboelectric material(CLTM)with excellent durability and crack resistance.Among them,the optimal CLTM(PSGCL-0.2)exhibited high mechanical strength(strain 445%,tensile strength 41.56 MPa,Young's modulus 41.25 MPa,toughness 159.67 MJ/m^(3))and excellent cyclic stability(300 cycles)with versatile functionalities,including antibacterial,antioxidant,and UV-shielding properties,water stabilization(255.51 g/m^(2)/d),efficient photothermal conversion,and full recyclability.Furthermore,biomass-based TENG device assembled from PSGCL-0.2 achieved stable triboelectric output properties(102.5 V,2.9μA,and 61.3 nC),and sustainable for 2000 cycles,fast response time(68 ms),and excellent power density(325.9 mW/m^(2)),effectively converting mechanical energy into electrical energy.Especially,PSGCL 0.2 was also integrated into the wireless self-powered smart insole,successfully enabling real-time visual monitoring of plantar pressure distribution and dynamic gait.Meanwhile,combined with the machine learning algorithm,the self-powered smart insole achieved precise recognition and classification of eight different motion states with an accuracy of 98%.This study provides the feasible strategy for developing extremely stable and durable biomass-based TENG,aimed at advancing sustainable intelligent healthcare systems.
基金supported by the National Natural Science Foundation of China(52374311)National Key R&D Program of China(2023YFE0203000)+3 种基金the National Natural Science Foundation of Shaanxi(2023KXJ-262,2025SYS-SYSZD-035)the Fund of the State Key Laboratory of Solidification Processing in NPU(2025-TS-10)the Fundamental Research Funds for the Central Universities(D5000250277)the Youth Innovation Team of Shaanxi Universities。
文摘Layered oxides present compelling potential as cathode materials for sodium-ion batteries(SIBs).However,challenges including interfacial instability and sluggish reaction kinetics critically limit their rate capability and cycling performance.Herein,we introduce the water-soluble sodium polyacrylate(NaPAA)binder as a promising approach to mitigating these issues in P2-type layered oxides.The NaPAA binder facilitates the formation of a uniform Na^(+) conductive interfacial film,which protects the cathode against electrolyte-induced corrosion and effectively inhibits the dissolution of transition metals in P2-Na_(0.85)Li_(0.12)Ni_(0.22)Mn_(0.66)O_(2)(NLNMO).Furthermore,we elucidate the mechanism by which the NaPAA binder dynamically regulates the coordination of free anions at the electrode-electrolyte interface.This regulation reduces solvent decomposition and promotes the formation of a stable,ionically conductive layer.Consequently,the P2-NLNMO@NaPAA integrated electrode exhibits enhanced electrochemical performance,achieving an 89.2%capacity retention after 200 cycles at 0.2 C and delivering an initial capacity of 102.9 mA h g^(-1) even at 0℃.This study advances the fundamental understanding of binder-mediated interface engineering and demonstrates a scalable and eco-friendly manufacturing pathway for high-performance SIBs.
基金funded by grants from the National Key R&D Project(2023YFD1400201-02,2023YFD1400203-02)the National Natural Science Foundation of China(31870137)+1 种基金the National Transgenic Research Project(2015ZX08001-002)the Key R&D Project of Guangdong Province(2022B0202060005).
文摘Asian rice comprises two major subspecies:Xian(X)and Geng(G),and the diverged resistance genes(R)have provided a foundation for breeding improved cultivars to control rice blast disease.After conducting two-phase allele mining using six updated FNP marker systems,the functional haplotypes at Pit,Pib,and Pi63 strictly diverged into the X-populations and were defined as X-R loci,while those at Pi54,Pi37,and Pi36 into the G-populations as G-R loci.The genic diversity at the three X-R loci(16 alleles)was twofold higher than that at the three G-R loci(8 alleles),and the allelic diversity in the Southern region(21 alleles)was nearly double that in the Northeastern region(11 alleles).Both observations reflect a significant difference in genetic diversity between X-and G-populations,and indicate that the effective R-genes mainly originated from X-subspecies.Based on the allelic structures characterized by a set of 10 parameters,8 and 16 alleles were respectively recognized as favorable and promising ones for the regional breeding programs.The genotypic structures of the two regional populations were almost different,indicating that the diverged alleles have been further assembled into two series of regional genotypes through long-term breeding programs,despite the presence of one-third of region-common alleles.The genotypic diversity in the Southern region(55 genotypes)was nearly twice as high as that in the Northeastern region(28),which perfectly reflects the aforementioned differences in both genic and allelic diversities.After analyzing the genotypic structures using a set of 13 parameters,4 and 23 genotypes,respectively,can be recommended as the favorable and promising ones for the regional breeding programs.The case study serves as a concrete sample of how to identify the favorable and promising alleles and genotypes,and beneficial parents based their comprehensive population structures for gene-designed breeding.
基金National Natural Science Foundation of China,Grant/Award Numbers:22178037,22278046,U22A20424Liaoning Education Department Project,Grant/Award Number:JYTMS20230396。
文摘As the most abundant renewable aromatic biopolymer resource on the Earth,lignin has become a cutting-edge research hotspot in clean photocatalysis,thanks to the distinct highest occupied molecular-orbital and lowest unoccupied molecular-orbital energy levels driven by the major β-O-4 linked bonds.However,the complex spatial architecture of functional groups,represented by benzene rings in the 3D intertwined macromolecular chains of lignin,and the challenge of enhancing carrier separation efficiency remain persistent obstacles hindering the development of lignin-based photocatalysts.Herein,a strategy of constructing lignin nanosphere-graphene oxide heterointerfaces(EL-GO)is proposed to comprehensively enhance the efficacy of functional groups and facilitate photoelectron migration modes.The recombination time of lightexcited photoelectrons is effectively prolonged by the π-π interactions between the“Donor site”and“Acceptor site”functional regions,along with the directional migration of photoelectrons between EL and GO.The photocatalytic efficiency of H_(2)O_(2) production using EL-GO is significantly enhanced under the protective mechanism of GO.To assess its potential,a prospect estimation of EL-GO in a lake containing various pollutants and metal ions was conducted,simulating real water conditions.This pioneering engineering effort aims to curb excessive consumption of fossil fuels and explore the green applications of lignin,thereby constructing a“carbon-neutral”feedstock system.
基金financial supports from National Natural Science Foundation of China(62175023).
文摘In this study,we developed a single-beam optical trap-based surface-enhanced Raman scattering(SERS)optofluidic molecular fingerprint spectroscopy detection system.This system utilizes a single-beam optical trap to concentrate free silver nanoparticles(AgNPs)within an optofluidic chip,significantly enhancing SERS performance.We investigated the optical field distribution characteristics within the tapered fiber using COMSOL simulation software and established a MATLAB simulation model to validate the single-beam optical trap's effectiveness in capturing AgNPs,demonstrating the theoretical feasibility of our approach.To verify the particle capture efficacy of the system,we experimentally controlled the optical trap's on-off state to manage the capture and release of particles precisely.The experimental results indicated that the Raman signal intensity in the capture state was significantly higher than in the non-capture state,confirming that the single-beam optical trap effectively enhances the SERS detection capability of the optofluidic detection system.Furthermore,we employed Raman mapping techniques to investigate the impact of the capture area on the SERS effect,revealing that the spectral intensity of molecular fingerprints in the laser-trapping region is significantly improved.We successfully detected the Raman spectrum of crystal violet at a concentration of 10^(−9)mol/L and pesticide thiram at a concentration of 10^(−5)mol/L,further demonstrating the ability of the single-beam optical trap in enhancing the molecular fingerprint spectrum identification capability of the SERS optofluidic chips.The optical trapping SERS optofluidic detection system developed in this study,as a key component of an integrated optoelectronic sensing system,holds the potential for integration with portable high-power lasers and high-performance Raman spectrometers.This integration is expected to advance highly integrated technologies and significantly enhance the overall performance and portability of optoelectronic sensing systems.
基金financially supported by the National Natural Science Foundation of China(22309137,22279095)Open subject project State Key Laboratory of New Textile Materials and Advanced Processing Technologies(FZ2023001).
文摘Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based catalysts.By introducing a third metal into NiFe-based catalysts to construct asymmetrical M-NiFe units,the d-orbital and electronic structures can be adjusted,which is an important strategy to achieve sufficient oxygen evolution reaction(OER)performance in AEMWEs.Herein,the ternary NiFeM(M:La,Mo)catalysts featured with distinct M-NiFe units and varying d-orbitals are reported in this work.Experimental and theoretical calculation results reveal that the doping of La leads to optimized hybridization between d orbital in NiFeM and 2p in oxygen,resulting in enhanced adsorption strength of oxygen intermediates,and reduced rate-determining step energy barrier,which is responsible for the enhanced OER performance.More critically,the obtained NiFeLa catalyst only requires 1.58 V to reach 1 A cm^(−2) in an anion exchange membrane electrolyzer and demonstrates excellent long-term stability of up to 600 h.
