The effect of different Zn concentrations(0 wt.%,1 wt.%,3 wt.%,and 6 wt.%)on the microstructure,cor-rosion property,and mechanical property of Mg-0.3Sc-x Zn(x=0 wt.%,1 wt.%,3 wt.%,and 6 wt.%)alloys was investigated.He...The effect of different Zn concentrations(0 wt.%,1 wt.%,3 wt.%,and 6 wt.%)on the microstructure,cor-rosion property,and mechanical property of Mg-0.3Sc-x Zn(x=0 wt.%,1 wt.%,3 wt.%,and 6 wt.%)alloys was investigated.Here,MSZ1 alloy exhibits the highest corrosion resistance(0.194 mm/y)and appropriate mechanical properties with an ultimate tensile strength of 228 MPa and elongation of 19%.The superior corrosion resistance of Mg-0.3Sc-1Zn alloys is attributed to the homogeneous volta-potential distribution and the dense corrosion product film.With the increase in zinc content,the strength and plasticity of Mg-0.3Sc-x Zn alloys(x=0 wt.%,1 wt.%,3 wt.%,6 wt.%)improved to some extent.The precipitated ScZn phase plays the role of the second phase strengthening,which enables MSZ6 to obtain the maximum tensile strength.However,the ScZn phase with low volta potential intensifies the galvanic corrosion,re-sulting in the decline of the corrosion performance.展开更多
The weak corrosion resistance of magnesium and its alloys greatly limited the industrial application.Though functional self-healing coatings have been proposed as countermeasures,repeated damages on coatings under pra...The weak corrosion resistance of magnesium and its alloys greatly limited the industrial application.Though functional self-healing coatings have been proposed as countermeasures,repeated damages on coatings under practical installation and complex external environments could require self-adaptive cor-rosion protection against multiple abrasions.In this study,an ultra-high corrosion-resistant Mg-1Zn-1Sc(wt.%)alloy with a corrosion rate of 0.087 mm/y has been designed and prepared,which has fine grains and uniform structure of a nano-scale ScZn phase with low potential.A unique and dense corrosion prod-uct film with a three-layered structure was found and studied on Mg-1Zn-1Sc alloy,providing excellent corrosion protection.In addition,the formation and protection mechanisms of the three-layered corrosion product film on Mg-1Zn-1Sc alloy have been discussed and proposed.The growth behavior of protective corrosion product film could be driven by the synergy of Sc and Zn elements.Furthermore,with the in-crease of Sc content,the strength,plasticity,and corrosion resistance of Mg-1Zn-x Sc(x=0,0.2,0.6,1.0,in wt.%)alloys increased simultaneously.The high corrosion resistance and moderate mechanical perfor-mance qualify Mg-1Zn-1Sc alloy as a promising candidate for diverse industrial applications.展开更多
A thick composite anodic oxide film was fabricated in an environmentally friendly malic acid electrolyte containing Poly Tetra Fluoro Ethylene(PTFE)nanoparticles on Ti-10V-2Fe-3Al alloys.The influence of pulse frequen...A thick composite anodic oxide film was fabricated in an environmentally friendly malic acid electrolyte containing Poly Tetra Fluoro Ethylene(PTFE)nanoparticles on Ti-10V-2Fe-3Al alloys.The influence of pulse frequency on the morphology,microstructure and composition of composite anodic oxide films containing PTFE nanoparticles was investigated using Field Emission Scanning Electron Microscopy(FE-SEM)equipped with Energy Dispersive Spectroscopy(EDS),Atomic Force Microscopy(AFM)and Raman spectroscopy.The tribological properties in terms of the friction coefficient,wear loss and morphology of worn surfaces were measured by ball-ondisc tests.The electrochemical property was evaluated by potentiodynamic polarization.The results indicated that the titanium dioxide of composite anodic oxide films transformed from anatase to rutile with the change of pulse frequency,which could result from the electrochemical dynamic equilibrium.The combination of PTFE nanoparticles and malic acid electrolyte molecules can influence the energy fluctuation of electrochemical equilibrium and formation of composite anodic oxide films.Moreover,composite anodic oxide films fabricated under the condition of 1.0–2.0 Hz exhibited the best wear resistance and corrosion property.The schematic diagram of the film formation and PTFE nanoparticles spreading process under different frequencies was elucidated.展开更多
基金financial support from the fi-nancial supports from the National Key R&D Program of China(No.2021YFB3701100)National Natural Science Foundation of China(Nos.52225101 and 52171103)+1 种基金Guangdong Major Project of Basic and Applied Basic Research(No.2020B0301030006)Fundamental Research Funds for the Central Universities(No.2020CDJDPT001).
文摘The effect of different Zn concentrations(0 wt.%,1 wt.%,3 wt.%,and 6 wt.%)on the microstructure,cor-rosion property,and mechanical property of Mg-0.3Sc-x Zn(x=0 wt.%,1 wt.%,3 wt.%,and 6 wt.%)alloys was investigated.Here,MSZ1 alloy exhibits the highest corrosion resistance(0.194 mm/y)and appropriate mechanical properties with an ultimate tensile strength of 228 MPa and elongation of 19%.The superior corrosion resistance of Mg-0.3Sc-1Zn alloys is attributed to the homogeneous volta-potential distribution and the dense corrosion product film.With the increase in zinc content,the strength and plasticity of Mg-0.3Sc-x Zn alloys(x=0 wt.%,1 wt.%,3 wt.%,6 wt.%)improved to some extent.The precipitated ScZn phase plays the role of the second phase strengthening,which enables MSZ6 to obtain the maximum tensile strength.However,the ScZn phase with low volta potential intensifies the galvanic corrosion,re-sulting in the decline of the corrosion performance.
基金supported by the National Natural Science Foundation of China(Nos.52225101 and 52171103)the National Key R&D Program of China(No.2021YFB3701100)+1 种基金the Guangdong Major Project of Basic and Applied Basic Research(No.2020B0301030006)the Fundamental Research Funds for the Central Universities(No.2020CDJDPT001).
文摘The weak corrosion resistance of magnesium and its alloys greatly limited the industrial application.Though functional self-healing coatings have been proposed as countermeasures,repeated damages on coatings under practical installation and complex external environments could require self-adaptive cor-rosion protection against multiple abrasions.In this study,an ultra-high corrosion-resistant Mg-1Zn-1Sc(wt.%)alloy with a corrosion rate of 0.087 mm/y has been designed and prepared,which has fine grains and uniform structure of a nano-scale ScZn phase with low potential.A unique and dense corrosion prod-uct film with a three-layered structure was found and studied on Mg-1Zn-1Sc alloy,providing excellent corrosion protection.In addition,the formation and protection mechanisms of the three-layered corrosion product film on Mg-1Zn-1Sc alloy have been discussed and proposed.The growth behavior of protective corrosion product film could be driven by the synergy of Sc and Zn elements.Furthermore,with the in-crease of Sc content,the strength,plasticity,and corrosion resistance of Mg-1Zn-x Sc(x=0,0.2,0.6,1.0,in wt.%)alloys increased simultaneously.The high corrosion resistance and moderate mechanical perfor-mance qualify Mg-1Zn-1Sc alloy as a promising candidate for diverse industrial applications.
基金co-supported by the National Natural Science Foundation of China(Nos.51971040 and 51971044)the Fundamental Research Funds for the Central Universities,China(2020CDJQY-A007)+1 种基金China Postdoctoral Science Foundation Funded Project(Nos.2017M620410 and 2018T110942)the Chongqing Postdoctoral Scientific Research Foundation(No.Xm2017010)。
文摘A thick composite anodic oxide film was fabricated in an environmentally friendly malic acid electrolyte containing Poly Tetra Fluoro Ethylene(PTFE)nanoparticles on Ti-10V-2Fe-3Al alloys.The influence of pulse frequency on the morphology,microstructure and composition of composite anodic oxide films containing PTFE nanoparticles was investigated using Field Emission Scanning Electron Microscopy(FE-SEM)equipped with Energy Dispersive Spectroscopy(EDS),Atomic Force Microscopy(AFM)and Raman spectroscopy.The tribological properties in terms of the friction coefficient,wear loss and morphology of worn surfaces were measured by ball-ondisc tests.The electrochemical property was evaluated by potentiodynamic polarization.The results indicated that the titanium dioxide of composite anodic oxide films transformed from anatase to rutile with the change of pulse frequency,which could result from the electrochemical dynamic equilibrium.The combination of PTFE nanoparticles and malic acid electrolyte molecules can influence the energy fluctuation of electrochemical equilibrium and formation of composite anodic oxide films.Moreover,composite anodic oxide films fabricated under the condition of 1.0–2.0 Hz exhibited the best wear resistance and corrosion property.The schematic diagram of the film formation and PTFE nanoparticles spreading process under different frequencies was elucidated.
