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A 1.55μm laser gain medium based on Yb^(3+)and Er^(3+)co-doped KBa_(0.94)Ca_(0.06)Y(MoO_(4))_(3) crystal with in-situ operating temperature self-monitoring capability
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作者 Yimin yang Rujia Chen +13 位作者 Zhipeng Zhang Huisheng Liu Zhuang Leng Xiliang Jiang Chunyu Zuo Lingbo Zhou Chun Li Fanming Zeng weiling yang Hai Lin Shasha Li Lina Liu Jianhua Hou Zhongmin Su 《Journal of Rare Earths》 2025年第9期1784-1795,共12页
The 1.55μm laser technology is widely applied in military,information communication,biomedicine and other fields.With the deepening development of these application areas,the demand for novel 1.55μm laser gain media... The 1.55μm laser technology is widely applied in military,information communication,biomedicine and other fields.With the deepening development of these application areas,the demand for novel 1.55μm laser gain media is becoming increasingly urgent.This study reports a novel Yb^(3+),Er^(3+)co-doped KBa_(0.94)Ca_(0.06)Y(MoO_(4))_(3) (KBCYM)crystal.In this crystal,Yb^(3+)serves as a sensitizer,significantly enhancing the emission intensity of Er^(3+)in both visible and near-infrared bands.Notably,when the concentration of Yb^(3+)reaches 6 mol%,the emission intensity peaks at 1.55μm.Optical cross-section calculations reveal that the crystal exhibits a low laser pumping threshold at this concentration,demonstrating its potential as a laser gain medium.However,the crystal inevitably generates thermal effects during operation,which may adversely affect its performance.Therefore,real-time monitoring of the operating temperature is crucial.The thermal stability of the crystal was evaluated by measuring the temperature dependence of its luminescence intensity in the near-infrared band.Remarkably,even when the temperature rises to 553 K,the emission intensity at 1.55μm only decreases by 10.9%.Additionally,the temperature sensing performance was evaluated using fluorescence intensity ratio techniques,yielding absolute and relative sensitivities of 0.00981 K^(-1)at 453 K and 1.32%/K at 303 K,respectively,highlighting its potential for optical temperature sensing.Finally,through leveraging the unique properties of Yb^(3+),Er^(3+):KBCYM crystals,we successfully developed 1.55μm luminescent optical devices with practical applications.These devices not only exhibit efficient luminescent performance,but also possess a self-temperature measu rement functio n,opening up new avenues for the further development of laser technology. 展开更多
关键词 Molybdate crystal Top-seeded solution growth(TSSG) Energy transfer Laser materials Non-contact temperature measurement Rare earths
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