Saline soils are significantly affected by water-salt phase changes,evaporation,and groundwater during seasonal freezing and thawing.For the study of physical and mechanical properties of saline soils,solubility is an...Saline soils are significantly affected by water-salt phase changes,evaporation,and groundwater during seasonal freezing and thawing.For the study of physical and mechanical properties of saline soils,solubility is an important indicator that varies with temperature.However,there have been very limited computational studies on solubility at low temperatures.The model for calculating the solubility of Na_(2)SO_(4)-NaCl-H_(2)O ternary system under low temperature conditions was constructed in this paper,based on the Pitzer and BET models.Improvements were made to the parametersФandγin the Pitzer model,while improvements were made to the parameters c,r,and aw in the BET model.The solubility changes within the range of 273.15 K–373.15 K were calculated and validated by combining them with indoor experiments.It was found that both the improved Pitzer model and BET model accurately predicted relative equilibrium solubility data of the Na_(2)SO_(4)-NaCl-H_(2)O ternary system at temperatures ranging from 273.15 K to 373.15 K.Additionally,compared with the Pitzer model,the BET model had advantages such as easy parameter acquisition and wider application range.The findings from this research hold great significance for understanding the process and patterns of salt analysis during soil freeze-thaw cycles as well as providing a scientific foundation for further comprehension of phase change laws and physical properties related to saline soils.展开更多
[Objectives]To study the impact of heavy metal pollution of soil and plants during the process of reclaimed water for irrigation of green land in arid areas and the potential health risks to humans during use.[Methods...[Objectives]To study the impact of heavy metal pollution of soil and plants during the process of reclaimed water for irrigation of green land in arid areas and the potential health risks to humans during use.[Methods]Taking Zhongwei City in Ningxia,a typical arid area,as the research area,the irrigation water,soil and green grass in the reclaimed water irrigation region and the original green water irrigation region were sampled,the heavy elements Hg,As,Zn,Pb,Cd,Cr were detected,and the Nemerow method,biological absorption coefficient,and health risk assessment were employed to evaluate the degree of soil pollution,plant absorption capacity,and human health risks.[Results]Compared with the original green water,the Hg,Cd,and Cr pollution of the reclaimed water irrigated green land was higher,the As,Zn,Pb pollution was lower,and the content of Hg and Cd was higher than the environmental background values of soil in Ningxia;the Cr content exceeded the risk intervention values of the first type of land in the Soil Environmental Quality—Risk Control Standard for Soil Contamination of Development Land(GB 36600-2018).Compared with the original green water irrigation region,it is found that the reclaimed water irrigation reduced the heavy metal pollution of the soil to a certain extent.The heavy metal content of tall fescue grass(Festuca arundinacea)in the reclaimed water irrigation region was Zn,Cr,Pb,As,Cd,and Hg from high to low;the order of the biological absorption coefficient was Cd>As>Zn>Pb>Hg>Cr;irrigation water exerted a certain effect on the content of heavy metals in plants and the biological absorption coefficient through the soil.Using the health risk assessment method recommended by Environmental Protection Agency of the United States of America(USEPA),it was found that the reclaimed water has the highest risk through the inhalation route,and the occupational population has a higher risk of skin contact with soil and plants.[Conclusions]This study is intended to provide data support and theoretical basis for the environmental safety risk research of the application of reclaimed water in arid areas to urban greening.展开更多
基金supported by the National key research&development program of China(Grant no.2021YFD1900600)the National Natural Science Foundation of Ningxia(2023AAC05014)+1 种基金the Ningxia Key Research and Development Program(Special Talents)(2023BSB03021)the Scientific Research Program of University of Ningxia Education Department(NYG2024049)。
文摘Saline soils are significantly affected by water-salt phase changes,evaporation,and groundwater during seasonal freezing and thawing.For the study of physical and mechanical properties of saline soils,solubility is an important indicator that varies with temperature.However,there have been very limited computational studies on solubility at low temperatures.The model for calculating the solubility of Na_(2)SO_(4)-NaCl-H_(2)O ternary system under low temperature conditions was constructed in this paper,based on the Pitzer and BET models.Improvements were made to the parametersФandγin the Pitzer model,while improvements were made to the parameters c,r,and aw in the BET model.The solubility changes within the range of 273.15 K–373.15 K were calculated and validated by combining them with indoor experiments.It was found that both the improved Pitzer model and BET model accurately predicted relative equilibrium solubility data of the Na_(2)SO_(4)-NaCl-H_(2)O ternary system at temperatures ranging from 273.15 K to 373.15 K.Additionally,compared with the Pitzer model,the BET model had advantages such as easy parameter acquisition and wider application range.The findings from this research hold great significance for understanding the process and patterns of salt analysis during soil freeze-thaw cycles as well as providing a scientific foundation for further comprehension of phase change laws and physical properties related to saline soils.
基金Supported by Research and Development and Demonstration Project of Domestic Reclaimed Water Reuse Technology(2018YFC0408104)First-rate Discipline Project of Colleges and Universities in Ningxia(NXYLXK2017A03)Key Research and Development Plan Project of Ningxia Hui Autonomous Region(2018BEG03008).
文摘[Objectives]To study the impact of heavy metal pollution of soil and plants during the process of reclaimed water for irrigation of green land in arid areas and the potential health risks to humans during use.[Methods]Taking Zhongwei City in Ningxia,a typical arid area,as the research area,the irrigation water,soil and green grass in the reclaimed water irrigation region and the original green water irrigation region were sampled,the heavy elements Hg,As,Zn,Pb,Cd,Cr were detected,and the Nemerow method,biological absorption coefficient,and health risk assessment were employed to evaluate the degree of soil pollution,plant absorption capacity,and human health risks.[Results]Compared with the original green water,the Hg,Cd,and Cr pollution of the reclaimed water irrigated green land was higher,the As,Zn,Pb pollution was lower,and the content of Hg and Cd was higher than the environmental background values of soil in Ningxia;the Cr content exceeded the risk intervention values of the first type of land in the Soil Environmental Quality—Risk Control Standard for Soil Contamination of Development Land(GB 36600-2018).Compared with the original green water irrigation region,it is found that the reclaimed water irrigation reduced the heavy metal pollution of the soil to a certain extent.The heavy metal content of tall fescue grass(Festuca arundinacea)in the reclaimed water irrigation region was Zn,Cr,Pb,As,Cd,and Hg from high to low;the order of the biological absorption coefficient was Cd>As>Zn>Pb>Hg>Cr;irrigation water exerted a certain effect on the content of heavy metals in plants and the biological absorption coefficient through the soil.Using the health risk assessment method recommended by Environmental Protection Agency of the United States of America(USEPA),it was found that the reclaimed water has the highest risk through the inhalation route,and the occupational population has a higher risk of skin contact with soil and plants.[Conclusions]This study is intended to provide data support and theoretical basis for the environmental safety risk research of the application of reclaimed water in arid areas to urban greening.
