Over the past decades,considerable efforts have been made in the commercial application of bulk metallic glasses(BMGs).Despite great challenges faced by the industrial players,significant progress has been achieved,an...Over the past decades,considerable efforts have been made in the commercial application of bulk metallic glasses(BMGs).Despite great challenges faced by the industrial players,significant progress has been achieved,and millions of commercial products for various kinds of applications have been shipped around the world.Here in this paper,we shall present the alloys suitable for the actual products in the application and discuss the merits of the processing technique of BMGs over the existing processing techniques and materials.Most importantly we demonstrate the typical examples of products over the past few years.Finally,future directions of the industrialization of BMGs are also discussed.展开更多
As one of the most important forming technologies for industrial bulk metallic glass (BMG) parts withcomplex shapes, high-pressure die casting (HPDC) can fill a die cavity with a glass-forming metallic liquidin millis...As one of the most important forming technologies for industrial bulk metallic glass (BMG) parts withcomplex shapes, high-pressure die casting (HPDC) can fill a die cavity with a glass-forming metallic liquidin milliseconds. However, to our knowledge, the correlation between flow and crystallization behavior inthe HPDC process has never been established. In this study, we report on the solidification behavior ofZr_(55)Cu_(30)Ni_(5)Al_(10) glass forming liquid under various flow rates. Surprisingly, the resulting alloys display adecreasing content of amorphous phase with increase of flow rate, i.e. increase of cooling rate, suggestingthat crystallization kinetics of glass-forming metallic liquids in the HPDC process is strongly dependenton the flow field. Analysis reveals that the accelerated crystallization behavior is mainly ascribed to therapid increase in viscosity with a decreasing temperature as well as to the huge shear effect in the glassforming liquid at the end stage of the filling process when the temperature is close to the glass-transitionpoint;this results in a transition from diffusion- to advection-dominated transport. The current investigation suggests that flow-related crystallization must be considered to assess the intrinsic glass-formingability of BMGs produced via HPDC. The obtained results will not only improve the understanding ofcrystallization dynamics but also promote the high-quality production and large-scale application of BMGparts.展开更多
基金financial support from the Shenyang National Laboratory for Materials Science,Institute of Metal Research。
文摘Over the past decades,considerable efforts have been made in the commercial application of bulk metallic glasses(BMGs).Despite great challenges faced by the industrial players,significant progress has been achieved,and millions of commercial products for various kinds of applications have been shipped around the world.Here in this paper,we shall present the alloys suitable for the actual products in the application and discuss the merits of the processing technique of BMGs over the existing processing techniques and materials.Most importantly we demonstrate the typical examples of products over the past few years.Finally,future directions of the industrialization of BMGs are also discussed.
基金L.H.Liu would like to thank the financial support from the National Natural Science Foundation of China(No.52001123)the China Postdoctoral Science Foundation(Nos.2019TQ0099 and 2019M662908)+5 种基金Guangdong Basic and the Applied Basic Research Foundation(No.2019A1515110215)the Foundation for Distinguished Young Talents in Higher Education of Guangdong(No.2019KQNCX003)the Fundamental Research Funds for the Central Universities(No.2020ZYGXZR030)the Open Fund of National Engineering Research Center of Near-net-shape Forming for Metallic Materials(No.2019003)C.Yang would like to thank the financial support from the Key Basic and Applied Research Program of Guangdong Province(No.2019B030302010)the National Natural Science Foundation of China(No.51971149).
文摘As one of the most important forming technologies for industrial bulk metallic glass (BMG) parts withcomplex shapes, high-pressure die casting (HPDC) can fill a die cavity with a glass-forming metallic liquidin milliseconds. However, to our knowledge, the correlation between flow and crystallization behavior inthe HPDC process has never been established. In this study, we report on the solidification behavior ofZr_(55)Cu_(30)Ni_(5)Al_(10) glass forming liquid under various flow rates. Surprisingly, the resulting alloys display adecreasing content of amorphous phase with increase of flow rate, i.e. increase of cooling rate, suggestingthat crystallization kinetics of glass-forming metallic liquids in the HPDC process is strongly dependenton the flow field. Analysis reveals that the accelerated crystallization behavior is mainly ascribed to therapid increase in viscosity with a decreasing temperature as well as to the huge shear effect in the glassforming liquid at the end stage of the filling process when the temperature is close to the glass-transitionpoint;this results in a transition from diffusion- to advection-dominated transport. The current investigation suggests that flow-related crystallization must be considered to assess the intrinsic glass-formingability of BMGs produced via HPDC. The obtained results will not only improve the understanding ofcrystallization dynamics but also promote the high-quality production and large-scale application of BMGparts.
