NiTi shape memory alloys(SMAs) was developed using the spark-plasma sintering(SPS) process with different average particle size(45 μm and 10 μm) under various temperature. The influence of particle size and temperat...NiTi shape memory alloys(SMAs) was developed using the spark-plasma sintering(SPS) process with different average particle size(45 μm and 10 μm) under various temperature. The influence of particle size and temperature on the density, microstructure, and corrosion behavior of the NiTi in simulated body fluid was examined. The porosity decreased with increasing sintering temperature and decreasing particle size, which resulted in an increase in density of the alloy. Increasing the sintering temperature led to the formation of Ni-and Ti-rich intermetallic such as Ni3Ti and NiTi2. The formation of these secondary phases influenced the corrosion behavior of NiTi by changing its chemical composition. The planar structure of NiTi was transformed into a dendritic structure at 900℃, which resulted in the formation of uniform oxide and phosphate layers on the entire surface. A high corrosion potential and low corrosion current density were achieved with NiTi prepared with 10 μm particles at 900℃, which exhibited superior corrosion resistance.展开更多
Ni-Cr based nanostructured feedstock powder was prepared by mechanical milling technique involving repeated welding, fracturing, and re-welding of powder particles in a planetary ball mill. The milled nanocrystalline ...Ni-Cr based nanostructured feedstock powder was prepared by mechanical milling technique involving repeated welding, fracturing, and re-welding of powder particles in a planetary ball mill. The milled nanocrystalline powders were used to coat carbon steel tubes using high velocity oxygen fuel（HVOF） thermal spraying process. The characterization of the feedstock powder and HVOF coated substrates was performed using optical microscope, X-ray diffractometer（XRD）, scanning electron microscope（SEM）, high resolution transmission electron microscope（HR-TEM）, energy dispersive spectrometer（EDS） and microhardness tests. The coated and uncoated samples were subjected to different thermal cycles and characterized for their phase changes, metallurgical changes and microhardness variations. Ni-Cr nanostructured coated samples exhibited higher mechanical and metallurgical properties compared to their conventionally coated counter parts. The results showed that the nanostructured coating possessed a more uniform and denser microstructure than the conventional coating.展开更多
The hot deformation behaviour of extruded magnesium-zinc oxide nano composite has been studied using hot compression test.The test was conducted in the temperature range of 250-400℃ and in the strain rate range of 0....The hot deformation behaviour of extruded magnesium-zinc oxide nano composite has been studied using hot compression test.The test was conducted in the temperature range of 250-400℃ and in the strain rate range of 0.01 to 1.5 s^(−1).The processing map was obtained using the power dissipation efficiency with the functions of temperature and strain rate.The workability and instability domains were observed in the processing map for a nano composite.The optical microscopy(OM),scanning electron microscopy(SEM)and transmission electron microscopy(TEM)images were used to confirm the formation of dynamic recrystallization(DRX),dynamic recovery(DRY)and instability regions.The workability region of the composite was identified at a working temperature of 400℃ and the strain rate of 0.01 s^(−1) from the processing map.The instability regions were observed at higher strain rates(>0.1 s^(−1))and temperatures(250-400℃).展开更多
The formulation of nanocrystallinc NiTi shape memory alloys has potential effects in mechanical stimulation and medical im- plantology. The present work elucidates the effect of milling time on the product＇s structur...The formulation of nanocrystallinc NiTi shape memory alloys has potential effects in mechanical stimulation and medical im- plantology. The present work elucidates the effect of milling time on the product＇s structural characteristics, chemical composition, and mi- crohardness for NiTi synthesized by mechanical alloying for different milling durations. Increasing the milling duration led to the formation of a nanocrystalline NiTi intermetallic at a higher level. The formation of nanocrystalline materials was directed through cold fusion, fractur- ing, and the development of a steady state, which were influenced by the accumulation of strain energy. In the morphological study, uninter- rupted cold diffusion and fracturing were visualized using transmission electron microscopy. Particle size analysis revealed that the mean particle size was reduced to -93 μm after 20 h of milling. The mechanical strength was enhanced by the formation of a nanocrystalline in- termetallic phase at longer milling time, which was confirmed by the results of Vickers hardness analyses.展开更多
The effect of Dzyaloshinskii-Moriya （D-M） interaction on the bistable nano-scale soliton switching offers the possiblity of developing a new innovative approach for data storage technology. The dynamics of Heisenber...The effect of Dzyaloshinskii-Moriya （D-M） interaction on the bistable nano-scale soliton switching offers the possiblity of developing a new innovative approach for data storage technology. The dynamics of Heisenberg ferromagnetic spin system is expressed in terms of generalized inhomogeneous higher order nonlinear Schr6dinger （NLS） equation. The bistable soliton switching in the ferromagnetic medium is established by solving the associated coupled evolution equations for amplitude and velocity of the soliton using the fourth order Runge-Kutta method numerically.展开更多
文摘NiTi shape memory alloys(SMAs) was developed using the spark-plasma sintering(SPS) process with different average particle size(45 μm and 10 μm) under various temperature. The influence of particle size and temperature on the density, microstructure, and corrosion behavior of the NiTi in simulated body fluid was examined. The porosity decreased with increasing sintering temperature and decreasing particle size, which resulted in an increase in density of the alloy. Increasing the sintering temperature led to the formation of Ni-and Ti-rich intermetallic such as Ni3Ti and NiTi2. The formation of these secondary phases influenced the corrosion behavior of NiTi by changing its chemical composition. The planar structure of NiTi was transformed into a dendritic structure at 900℃, which resulted in the formation of uniform oxide and phosphate layers on the entire surface. A high corrosion potential and low corrosion current density were achieved with NiTi prepared with 10 μm particles at 900℃, which exhibited superior corrosion resistance.
基金supported and funded from consultancy project of Bharath Heavy Electricals Limited, Tiruchirappalli,India
文摘Ni-Cr based nanostructured feedstock powder was prepared by mechanical milling technique involving repeated welding, fracturing, and re-welding of powder particles in a planetary ball mill. The milled nanocrystalline powders were used to coat carbon steel tubes using high velocity oxygen fuel（HVOF） thermal spraying process. The characterization of the feedstock powder and HVOF coated substrates was performed using optical microscope, X-ray diffractometer（XRD）, scanning electron microscope（SEM）, high resolution transmission electron microscope（HR-TEM）, energy dispersive spectrometer（EDS） and microhardness tests. The coated and uncoated samples were subjected to different thermal cycles and characterized for their phase changes, metallurgical changes and microhardness variations. Ni-Cr nanostructured coated samples exhibited higher mechanical and metallurgical properties compared to their conventionally coated counter parts. The results showed that the nanostructured coating possessed a more uniform and denser microstructure than the conventional coating.
文摘The hot deformation behaviour of extruded magnesium-zinc oxide nano composite has been studied using hot compression test.The test was conducted in the temperature range of 250-400℃ and in the strain rate range of 0.01 to 1.5 s^(−1).The processing map was obtained using the power dissipation efficiency with the functions of temperature and strain rate.The workability and instability domains were observed in the processing map for a nano composite.The optical microscopy(OM),scanning electron microscopy(SEM)and transmission electron microscopy(TEM)images were used to confirm the formation of dynamic recrystallization(DRX),dynamic recovery(DRY)and instability regions.The workability region of the composite was identified at a working temperature of 400℃ and the strain rate of 0.01 s^(−1) from the processing map.The instability regions were observed at higher strain rates(>0.1 s^(−1))and temperatures(250-400℃).
文摘The formulation of nanocrystallinc NiTi shape memory alloys has potential effects in mechanical stimulation and medical im- plantology. The present work elucidates the effect of milling time on the product＇s structural characteristics, chemical composition, and mi- crohardness for NiTi synthesized by mechanical alloying for different milling durations. Increasing the milling duration led to the formation of a nanocrystalline NiTi intermetallic at a higher level. The formation of nanocrystalline materials was directed through cold fusion, fractur- ing, and the development of a steady state, which were influenced by the accumulation of strain energy. In the morphological study, uninter- rupted cold diffusion and fracturing were visualized using transmission electron microscopy. Particle size analysis revealed that the mean particle size was reduced to -93 μm after 20 h of milling. The mechanical strength was enhanced by the formation of a nanocrystalline in- termetallic phase at longer milling time, which was confirmed by the results of Vickers hardness analyses.
基金support by NBHM in the form of major research project, BRNS in the form of Young Scientist Research Award, India and ICTP, Italy in the form of Junior Associateshipfinancial support from CSIR, India in the form of Senior Research Fellowship
文摘The effect of Dzyaloshinskii-Moriya （D-M） interaction on the bistable nano-scale soliton switching offers the possiblity of developing a new innovative approach for data storage technology. The dynamics of Heisenberg ferromagnetic spin system is expressed in terms of generalized inhomogeneous higher order nonlinear Schr6dinger （NLS） equation. The bistable soliton switching in the ferromagnetic medium is established by solving the associated coupled evolution equations for amplitude and velocity of the soliton using the fourth order Runge-Kutta method numerically.
