The dielectric properties of binary mixtures of benzylamine-1,2,6-hexantriol mixtures at different volume fractions of 1,2,6-hexanetriol have been measured using Time Domain Reflectometry(TDR)technique in the frequenc...The dielectric properties of binary mixtures of benzylamine-1,2,6-hexantriol mixtures at different volume fractions of 1,2,6-hexanetriol have been measured using Time Domain Reflectometry(TDR)technique in the frequency range of 10 MHz to 30 GHz.Complex permittivity spectra were fitted using Havriliak-Negami equation.By using least square fit method the dielectric parameters such as static dielectric constant(ε_(0)),dielectric constant at high frequency(ε_(∞)),relaxation timeτ(ps)and relaxation distribution parameter(β)were extracted from complex permittivity spectra at 25℃.The intramolecular interaction of different molecules has been discussed using the Kirkwood correlation factor,Bruggeman factor.The Kirkwood correlation factor(gf)and effective Kirkwood correlation factor(g^(eff))indicate the dipole ordering of the binary mixtures.展开更多
基金New Delhi is gratefully acknowledged(project No.SR/S2/LOP-25/2007)for laboratory facility.
文摘The dielectric properties of binary mixtures of benzylamine-1,2,6-hexantriol mixtures at different volume fractions of 1,2,6-hexanetriol have been measured using Time Domain Reflectometry(TDR)technique in the frequency range of 10 MHz to 30 GHz.Complex permittivity spectra were fitted using Havriliak-Negami equation.By using least square fit method the dielectric parameters such as static dielectric constant(ε_(0)),dielectric constant at high frequency(ε_(∞)),relaxation timeτ(ps)and relaxation distribution parameter(β)were extracted from complex permittivity spectra at 25℃.The intramolecular interaction of different molecules has been discussed using the Kirkwood correlation factor,Bruggeman factor.The Kirkwood correlation factor(gf)and effective Kirkwood correlation factor(g^(eff))indicate the dipole ordering of the binary mixtures.
