Highly efficient nonlinear optical（NLO） materials with well-defined architectures in the wavelength and subwavelength length scales are of particular importance for next generation of integrated photonic circuits. F...Highly efficient nonlinear optical（NLO） materials with well-defined architectures in the wavelength and subwavelength length scales are of particular importance for next generation of integrated photonic circuits. Fluorenone analogues have been demonstrated to be promising candidates as building blocks for assembly of organic NLO materials thanks to their synergistic supramolecular interactions and brilliant optical properties. Here we have studied the polymorphs of a phenylethynyl functionalized fluorenone derivative, and their controlled self-assembly for microstructures with different morphologies. These polymorphic microcrystals exhibit very distinctive NLO properties, highly related to their supramolecular and electronic structures.展开更多
Flat and crystalline materials with exceptional nonlinear optical(NLO) properties are highly desirable for their potential applications in integrated NLO photonic devices.Graphdiyne(GD),a new twodimensional(2 D) carbo...Flat and crystalline materials with exceptional nonlinear optical(NLO) properties are highly desirable for their potential applications in integrated NLO photonic devices.Graphdiyne(GD),a new twodimensional(2 D) carbon allotrope,has recently evoked burgeoning research attention by virtue of its tunable bandgap along with a high carrier mobility and extended π-conjugation compared with most conventional optical materials.Here,we experimentally probe the third-order nonlinear optical response of GD dispersed in several common solvents(alcohols) using a femtosecond Z-scan technique.The measured nonlinear optical refractive index is in the order of ~10^(-8) cm^(2)/W,which is approximately one order of magnitude higher than that of most 2 D materials.In particular,we find that different NLO responses can be observed from GD when dispersed in different solvents,with the strongest NLO response when dispersed in 1-propanol.It is proposed that some intrinsic properties of the solvents,such as the polarity and viscosity,could influence the NLO response of GD materials.Our experimental results confirm the assumptions on the NLO behavior in GD and demonstrate its great potential for future generations of Kerr-effect-based NLO materials and devices.展开更多
Magnetic skyrmions are particle-like topological magnetic textures that are potential information carriers in future spintronics.An enormous body of research confirms their existence in a broad range of magnetic mater...Magnetic skyrmions are particle-like topological magnetic textures that are potential information carriers in future spintronics.An enormous body of research confirms their existence in a broad range of magnetic materials since their first discovery in 2009.To date,magnetic skyrmions can not only be found in asymmetric systems but also in centrosymmetric ones.Notably,engineered magnetic multilayers are promising structures for skyrmion-based spintronics because they can stabilize small-sized skyrmions at room temperature and facilitate their electric manipulation.In this overview,we introduce the topological nature,their special properties,and nucleation methods of skyrmions,and show their potential for applications.Perspectives on skyrmionic devices and developments toward other,more three-dimensional particle-like magnetic nanostructures,are discussed at the end.展开更多
基金the financial supports from the National Natural Science Foundation of China(NSFC) (Nos.21773168, 51503143 and 21761132007)the Tianjin Natural Science Foundation(No. 16JCQNJC05000)+5 种基金the Innovation Foundation of Tianjin University (No. 2016XRX-0017)the China International Science and Technology Projects(No. S2016G3413)The Netherlands Organization for Scientific Research (NWO) with the Veni Grant (No. 680-47-437)The Royal Netherlands Academy of Arts and Sciences(KNAW) with the China-Exchange Program (No. 530-4CDPO2)the Tianjin 1000 Youth Talents Planthe Chinese Scholarship Council (CSC)
文摘Highly efficient nonlinear optical（NLO） materials with well-defined architectures in the wavelength and subwavelength length scales are of particular importance for next generation of integrated photonic circuits. Fluorenone analogues have been demonstrated to be promising candidates as building blocks for assembly of organic NLO materials thanks to their synergistic supramolecular interactions and brilliant optical properties. Here we have studied the polymorphs of a phenylethynyl functionalized fluorenone derivative, and their controlled self-assembly for microstructures with different morphologies. These polymorphic microcrystals exhibit very distinctive NLO properties, highly related to their supramolecular and electronic structures.
基金Financial support from the National Natural Science Foundation of China(Nos.21773168 and 21761132007)the Dutch Research Council(NWO)are gratefully acknowledgedthe supports from the China Scholarship Council(CSC)。
文摘Flat and crystalline materials with exceptional nonlinear optical(NLO) properties are highly desirable for their potential applications in integrated NLO photonic devices.Graphdiyne(GD),a new twodimensional(2 D) carbon allotrope,has recently evoked burgeoning research attention by virtue of its tunable bandgap along with a high carrier mobility and extended π-conjugation compared with most conventional optical materials.Here,we experimentally probe the third-order nonlinear optical response of GD dispersed in several common solvents(alcohols) using a femtosecond Z-scan technique.The measured nonlinear optical refractive index is in the order of ~10^(-8) cm^(2)/W,which is approximately one order of magnitude higher than that of most 2 D materials.In particular,we find that different NLO responses can be observed from GD when dispersed in different solvents,with the strongest NLO response when dispersed in 1-propanol.It is proposed that some intrinsic properties of the solvents,such as the polarity and viscosity,could influence the NLO response of GD materials.Our experimental results confirm the assumptions on the NLO behavior in GD and demonstrate its great potential for future generations of Kerr-effect-based NLO materials and devices.
基金Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory,Grant/Award Number:XHT2020-005The Guangdong Basic and Applied Basic Research Foundation,Grant/Award Numbers:2020A1515110250,2021B1515120041+1 种基金The National Key Research and Development Program of China,Grant/Award Number:2020YFA0715000The European Research Council ERC grant agreement,Grant/Award Number:no.856538(3D-MAGiC)。
文摘Magnetic skyrmions are particle-like topological magnetic textures that are potential information carriers in future spintronics.An enormous body of research confirms their existence in a broad range of magnetic materials since their first discovery in 2009.To date,magnetic skyrmions can not only be found in asymmetric systems but also in centrosymmetric ones.Notably,engineered magnetic multilayers are promising structures for skyrmion-based spintronics because they can stabilize small-sized skyrmions at room temperature and facilitate their electric manipulation.In this overview,we introduce the topological nature,their special properties,and nucleation methods of skyrmions,and show their potential for applications.Perspectives on skyrmionic devices and developments toward other,more three-dimensional particle-like magnetic nanostructures,are discussed at the end.
