研制了民航飞机机轮橡胶密封圈混炼胶料,物理机械性能满足GJB 5258—2003标准要求。与现用胶料相比,拉断伸长率提高约20%,150℃×22 h YH-10液压油中压缩永久变形率降低约60%;同一辊胶料历经10个月,先后4次重复热炼、挤出,胶料的物...研制了民航飞机机轮橡胶密封圈混炼胶料,物理机械性能满足GJB 5258—2003标准要求。与现用胶料相比,拉断伸长率提高约20%,150℃×22 h YH-10液压油中压缩永久变形率降低约60%;同一辊胶料历经10个月,先后4次重复热炼、挤出,胶料的物理机械性能几乎没有变化,且加工工艺性能良好;采用实验室加速老化方法,预测硫化制品寿命提高近50%。展开更多
A novel bovine serum albumin (BSA) imprinted Mn-doped ZnS quantum dots (Mn:ZnS QDs) is firstly reported. The molecular imprinted polymer (MIP) functionalized Mn:ZnS QDs (Mn:ZnS @SiO2@MIP) include the prepar...A novel bovine serum albumin (BSA) imprinted Mn-doped ZnS quantum dots (Mn:ZnS QDs) is firstly reported. The molecular imprinted polymer (MIP) functionalized Mn:ZnS QDs (Mn:ZnS @SiO2@MIP) include the preparation of Mn:ZnS QDs, the coating of silica on the surface of Mn:ZnS QDs, and the functional polymerization by sol-gel reaction using 3-aminophenylboronic acid as the functional and cross-linking monomer in the presence of BSA (Mn:ZnS@SiO2@MIP-BSA), and then the elution of the imprinted BSA on the surface of Mn:ZnS@SiO2 QDs. The results showed that the phosphorescence of Mn:ZnS@SiO2@MIP is stronger quenched by BSA than that of non-imprinted one (Mn:ZnS@SiO2@NIP), indicating that the selectivity of the imprinted Mn:ZnS quantum dots toward BSA is superior to that of non-imprinted one.展开更多
文摘研制了民航飞机机轮橡胶密封圈混炼胶料,物理机械性能满足GJB 5258—2003标准要求。与现用胶料相比,拉断伸长率提高约20%,150℃×22 h YH-10液压油中压缩永久变形率降低约60%;同一辊胶料历经10个月,先后4次重复热炼、挤出,胶料的物理机械性能几乎没有变化,且加工工艺性能良好;采用实验室加速老化方法,预测硫化制品寿命提高近50%。
基金financial support from the Hubei Science Foundation(No.2010CDA061)
文摘A novel bovine serum albumin (BSA) imprinted Mn-doped ZnS quantum dots (Mn:ZnS QDs) is firstly reported. The molecular imprinted polymer (MIP) functionalized Mn:ZnS QDs (Mn:ZnS @SiO2@MIP) include the preparation of Mn:ZnS QDs, the coating of silica on the surface of Mn:ZnS QDs, and the functional polymerization by sol-gel reaction using 3-aminophenylboronic acid as the functional and cross-linking monomer in the presence of BSA (Mn:ZnS@SiO2@MIP-BSA), and then the elution of the imprinted BSA on the surface of Mn:ZnS@SiO2 QDs. The results showed that the phosphorescence of Mn:ZnS@SiO2@MIP is stronger quenched by BSA than that of non-imprinted one (Mn:ZnS@SiO2@NIP), indicating that the selectivity of the imprinted Mn:ZnS quantum dots toward BSA is superior to that of non-imprinted one.