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氧化物中存在O2p空穴的典型实验结果和磁性氧化物的O2p巡游电子模型
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作者 唐贵德 齐伟华 《河北师范大学学报(自然科学版)》 CAS 2024年第1期1-8,共8页
负二价氧离子具有满壳层价电子结构(2s^(2)2p^(6)).负一价氧离子的价电子结构为2s^(2)2p^(5),相当于存在1个O2p空穴.传统的凝聚态物理和材料化学研究中都假设氧化物中的氧离子全部为负二价离子,在迄今为止的绝大多数研究氧化物磁性和电... 负二价氧离子具有满壳层价电子结构(2s^(2)2p^(6)).负一价氧离子的价电子结构为2s^(2)2p^(5),相当于存在1个O2p空穴.传统的凝聚态物理和材料化学研究中都假设氧化物中的氧离子全部为负二价离子,在迄今为止的绝大多数研究氧化物磁性和电输运性质的报道中,采用关于磁有序的超交换和双交换作用模型,都没有考虑O2p空穴的影响.然而,许多价电子状态实验证明,在氧化物中存在不可忽略的O2p空穴,即存在不可忽略的负一价氧离子,其占比可达30%或更多.基于这些实验结果,对传统磁有序模型进行改进,英美学者首先进行了探讨,笔者所在课题组与中国科学院物理研究所磁学国家重点实验室合作进行了系统的研究.介绍了相关的典型实验结果和理论模型. 展开更多
关键词 磁性材料 磁有序模型 O2p空穴 电子能量损失谱 X-射线光电子谱
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Roles of Te and Mn in the two phases of manganite with nominal composition La_(0.6)Sr_(0.1)Te_xMnO_3 被引量:2
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作者 LI Yanfeng JI Denghui +6 位作者 ZHAO Zhiwei tang guide LIU Shaopeng ZHANG Yuge LI Zhuangzhi HOU Denglu ZHU Minggang 《Rare Metals》 SCIE EI CAS CSCD 2011年第3期232-240,共9页
Powder samples with nominal composition La0.6Sr0.1TexMnO3 (x = 0.00, 0.05, 0.10, 0.15, 0.20) were prepared using the sol-gel method with thermal treatment up to 1473 K. On the basis of powder X-ray diffraction (XRD... Powder samples with nominal composition La0.6Sr0.1TexMnO3 (x = 0.00, 0.05, 0.10, 0.15, 0.20) were prepared using the sol-gel method with thermal treatment up to 1473 K. On the basis of powder X-ray diffraction (XRD), thermogravimetric and magnetic measurements, it was found that almost all of the Te and a few of the Mn ions were lost from the samples when they were calcined at 1473 K. The reason for the Te loss and a quantitative phase analysis for the samples calcined at 1473 K are discussed in detail. 展开更多
关键词 condensed matter physics crystal defects X-ray diffraction perovskite manganite magnetic properties
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Reverse of Dumbbell Rotation in Garnet Bubble Films 被引量:1
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作者 SUN Huiyuan NIE Xiangfu +1 位作者 tang guide HAN Baoshan 《Chinese Physics Letters》 SCIE CAS CSCD 1993年第10期623-626,共4页
The bias field dependence of the rotation direction of the dumbbells,contracted from multi-branched domains,was experimentally studied.Moreover,it was found that the rotation direction of these dumbbells can be revers... The bias field dependence of the rotation direction of the dumbbells,contracted from multi-branched domains,was experimentally studied.Moreover,it was found that the rotation direction of these dumbbells can be reversed by increasing the amplitude of the testing bias pulses with quite narrow width. 展开更多
关键词 ROTATION reversed NARROW
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Self-collapse of Dumbbell Domains in Garnet Bubble Films 被引量:1
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作者 NIE Xiangfu tang guide HAN Baoshan 《Chinese Physics Letters》 SCIE CAS CSCD 1991年第8期420-423,共4页
The self-collapse phenomenon of dumbbell domains was studied experimentally.The coincidence of the bias field region of self-collapse with that of collapse for both the first and second kinds of dumbbells manifests th... The self-collapse phenomenon of dumbbell domains was studied experimentally.The coincidence of the bias field region of self-collapse with that of collapse for both the first and second kinds of dumbbells manifests that two necessary conditions for self-collapse are:(1)sufficiently high number of vertical Bloch lines(VBLs)in their walls and(2)these VBLs are in high compression,and there exists the similarity between self-collapse and collapse in mechanism. 展开更多
关键词 MECHANISM walls COINCIDENCE
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