A study has been made on elements organic constituents, TSP, SO2,NO2 of atmospheric pollutants in Beijing. 17 elements, and some PAHs, e. g. B(a)P, B(b, j, k)P, and B(g, h, i)P, in airborne particles by X-ray fluoresc...A study has been made on elements organic constituents, TSP, SO2,NO2 of atmospheric pollutants in Beijing. 17 elements, and some PAHs, e. g. B(a)P, B(b, j, k)P, and B(g, h, i)P, in airborne particles by X-ray fluorescence spectroscopy and HPLC, GC/MS, have been determined respectively. It has been shown that the elements Pb, Zn, S and Cu were more enriched in fine particles and different valence states of sulfur at various sites. It was found that the concentrations of S6+ and S2-were more than 85% and less than 15% of the total sulfur respectively. Concentrations of major PAHs and sulfur-containing compounds increased in winter and in urban area. High values for Pb and Zn in city, Fe and Mn at industrial area and Cu, Al rural sites were obtained respectively. This implies the functions of different elemental sources of various sites. Thus, elements can be from distingushed anthropogenic and natural sources.The main contribution of SO2 was found of to have same seasonal variation as the anthropogenic elements, while that of NO2 varied only with emission from vehicles.展开更多
CE (=%C+(1/3)x(%Si)) does not suit experiment results in many cases. In this work, the effect of alloy elements on primary crystal temperature was measured and the relationship between primary crystal temperatu...CE (=%C+(1/3)x(%Si)) does not suit experiment results in many cases. In this work, the effect of alloy elements on primary crystal temperature was measured and the relationship between primary crystal temperature (Tc) and carbon equivalent (CEL) was investigated. The results show that Tc (Celsius degree) = 1650-110 × (%C) -25 × (%Si)+3 × (%Mn) -35 × (%P) -71 × (%5)-2 × (%Ni) -7 × (%Cr); CEL=%C + 0.23×(%Si)-0.03× (%Mn)+0.32×(%P)+0.64×(%S) +0.02×(%Ni)+0.06×(%Cr). That is, in hypo eutectic composition, carbon equivalent should be calculated with CEL=%C+ 0.23×(%Si), not with CE=%C+(1/3) x(%Si).展开更多
Independent microstructures made of Ni metal were fabricated by fivesequential processes: porous anodic oxide film formation, pore sealing, laser irradiation, Nielectroplating, and removal of the aluminum substrate an...Independent microstructures made of Ni metal were fabricated by fivesequential processes: porous anodic oxide film formation, pore sealing, laser irradiation, Nielectroplating, and removal of the aluminum substrate and anodic oxide films. Aluminum plates androds were anodized in an oxalic acid solution to form porous type anodic oxide films, and thenimmersed in boiling distilled water for pore sealing. The anodized and pore-sealed specimens wereirradiated with a pulsed neodymium-doped yttrium aluminum garnet (Nd-YAG) laser beam in a Ni platingsolution to remove anodic oxide film locally by rotating and moving up I down with anXYZ(theta)-stage. Nickel was deposited at the area where film had been removed by cathodicpolarization in the solution before removing the aluminum substrate and anodic oxide films in NaOHsolutions. Cylindrical or plain network structures were fabricated successfully.展开更多
文摘A study has been made on elements organic constituents, TSP, SO2,NO2 of atmospheric pollutants in Beijing. 17 elements, and some PAHs, e. g. B(a)P, B(b, j, k)P, and B(g, h, i)P, in airborne particles by X-ray fluorescence spectroscopy and HPLC, GC/MS, have been determined respectively. It has been shown that the elements Pb, Zn, S and Cu were more enriched in fine particles and different valence states of sulfur at various sites. It was found that the concentrations of S6+ and S2-were more than 85% and less than 15% of the total sulfur respectively. Concentrations of major PAHs and sulfur-containing compounds increased in winter and in urban area. High values for Pb and Zn in city, Fe and Mn at industrial area and Cu, Al rural sites were obtained respectively. This implies the functions of different elemental sources of various sites. Thus, elements can be from distingushed anthropogenic and natural sources.The main contribution of SO2 was found of to have same seasonal variation as the anthropogenic elements, while that of NO2 varied only with emission from vehicles.
文摘CE (=%C+(1/3)x(%Si)) does not suit experiment results in many cases. In this work, the effect of alloy elements on primary crystal temperature was measured and the relationship between primary crystal temperature (Tc) and carbon equivalent (CEL) was investigated. The results show that Tc (Celsius degree) = 1650-110 × (%C) -25 × (%Si)+3 × (%Mn) -35 × (%P) -71 × (%5)-2 × (%Ni) -7 × (%Cr); CEL=%C + 0.23×(%Si)-0.03× (%Mn)+0.32×(%P)+0.64×(%S) +0.02×(%Ni)+0.06×(%Cr). That is, in hypo eutectic composition, carbon equivalent should be calculated with CEL=%C+ 0.23×(%Si), not with CE=%C+(1/3) x(%Si).
文摘Independent microstructures made of Ni metal were fabricated by fivesequential processes: porous anodic oxide film formation, pore sealing, laser irradiation, Nielectroplating, and removal of the aluminum substrate and anodic oxide films. Aluminum plates androds were anodized in an oxalic acid solution to form porous type anodic oxide films, and thenimmersed in boiling distilled water for pore sealing. The anodized and pore-sealed specimens wereirradiated with a pulsed neodymium-doped yttrium aluminum garnet (Nd-YAG) laser beam in a Ni platingsolution to remove anodic oxide film locally by rotating and moving up I down with anXYZ(theta)-stage. Nickel was deposited at the area where film had been removed by cathodicpolarization in the solution before removing the aluminum substrate and anodic oxide films in NaOHsolutions. Cylindrical or plain network structures were fabricated successfully.