The effects of H_(2)SO_(4)concentration and current in electrochemical corrosion on surface layer softening or plasticizing of Q235 steel bar and their effects on subsequent electrochemical cold drawing(ECD)were inves...The effects of H_(2)SO_(4)concentration and current in electrochemical corrosion on surface layer softening or plasticizing of Q235 steel bar and their effects on subsequent electrochemical cold drawing(ECD)were investigated.The results indicate that the electrochemical corrosion can soften or plasticize the surface layer of Q235 steel bar and then make the subsequent ECD be conducted more easily.The softening degree and thickness of the surface layer are continuously enhanced with increasing corrosion rate,i.e.,increasing H_(2)SO_(4)concentration or current,due to the generation of more vacancy clusters in deeper regions of surface layer.These vacancy clusters then relax dislocations through being absorbed during ECD,and the formation and movement of additional dislocation flux are thereby enhanced,resulting in the further obvious decrease in the drawing force.It is also due to the enhanced formation and movement of additional dislocation flux that the dislocation density and thus the hardness of the surface layer are decreased,as well as that the texture structure is weakened.These behaviors are enhanced as the corrosion rate increases.展开更多
Due to the similarity in composition and crystal structure of some Ti Al Si ternary intermetallics,it is quite difficult to accurately confirm their physic characteristics,and thus,to tailor microstructure to improve ...Due to the similarity in composition and crystal structure of some Ti Al Si ternary intermetallics,it is quite difficult to accurately confirm their physic characteristics,and thus,to tailor microstructure to improve mechanical properties of metal materials related to the Ti Al Si intermetallics.Therefore,the formation process of Ti Al Si intermetallics was investigated during heating Ti-A356 mixed powder compact at a A356 alloy semisolid temperature of 595℃.The results indicated that two kinds of intermetallics ofτ1(tetragonal,I41/amd)andτ2(orthorhombic,Cmcm)generated,and both the concentration and supply direction of Ti atoms,which are related to local breakage of oxide films on neighboring Ti and A356 alloy powders,determined the phase and morphology of the intermetallics.τ1 andτ2 crystals all had an intrinsic plate morphology,butτ2 crystals were thinner due to more anisotropic growth resulted from their high density of stacking faults(SFs).τ1 lamellar domains generated during growth ofτ2 crystals,which were accompanied by decrease in density of SFs.The combined effect of size difference and internal energy difference betweenτ1 andτ2 crystals made largeτ1 crystals coarsen at the expense ofτ2 crystals in Ostwald ripening,leading them to finally evolve into an agglomerate of largeτ1 plates.展开更多
基金thanks for the National Natural Science Foundation of China(Grant No.51971105)for financial support,and P.Zhang and X.Z.Cao(the Positron Research Platform,Institute of High Energy Physics,CAS,Beijing 100049,China)for conducting the analysis of positron annihilation life spectroscopy.
文摘The effects of H_(2)SO_(4)concentration and current in electrochemical corrosion on surface layer softening or plasticizing of Q235 steel bar and their effects on subsequent electrochemical cold drawing(ECD)were investigated.The results indicate that the electrochemical corrosion can soften or plasticize the surface layer of Q235 steel bar and then make the subsequent ECD be conducted more easily.The softening degree and thickness of the surface layer are continuously enhanced with increasing corrosion rate,i.e.,increasing H_(2)SO_(4)concentration or current,due to the generation of more vacancy clusters in deeper regions of surface layer.These vacancy clusters then relax dislocations through being absorbed during ECD,and the formation and movement of additional dislocation flux are thereby enhanced,resulting in the further obvious decrease in the drawing force.It is also due to the enhanced formation and movement of additional dislocation flux that the dislocation density and thus the hardness of the surface layer are decreased,as well as that the texture structure is weakened.These behaviors are enhanced as the corrosion rate increases.
基金supported by the National Key Research and Development Program(grant No.2018YFB2001800)the National Natural Science Foundation of China(grant No.51564035)。
文摘Due to the similarity in composition and crystal structure of some Ti Al Si ternary intermetallics,it is quite difficult to accurately confirm their physic characteristics,and thus,to tailor microstructure to improve mechanical properties of metal materials related to the Ti Al Si intermetallics.Therefore,the formation process of Ti Al Si intermetallics was investigated during heating Ti-A356 mixed powder compact at a A356 alloy semisolid temperature of 595℃.The results indicated that two kinds of intermetallics ofτ1(tetragonal,I41/amd)andτ2(orthorhombic,Cmcm)generated,and both the concentration and supply direction of Ti atoms,which are related to local breakage of oxide films on neighboring Ti and A356 alloy powders,determined the phase and morphology of the intermetallics.τ1 andτ2 crystals all had an intrinsic plate morphology,butτ2 crystals were thinner due to more anisotropic growth resulted from their high density of stacking faults(SFs).τ1 lamellar domains generated during growth ofτ2 crystals,which were accompanied by decrease in density of SFs.The combined effect of size difference and internal energy difference betweenτ1 andτ2 crystals made largeτ1 crystals coarsen at the expense ofτ2 crystals in Ostwald ripening,leading them to finally evolve into an agglomerate of largeτ1 plates.
