Tight glutenite reservoirs are known for strong heterogeneity,complex wettability,and challenging development.Gas-Assisted Gravity Drainage(GAGD)technology has the potential to significantly improve recovery efficienc...Tight glutenite reservoirs are known for strong heterogeneity,complex wettability,and challenging development.Gas-Assisted Gravity Drainage(GAGD)technology has the potential to significantly improve recovery efficiency in glutenite reservoir.However,there is currently limited research on GAGD processes specifically designed for glutenite reservoirs,and there is a lack of relevant dimensionless numbers for predicting recovery efficiency.In this study,we developed a theoretical model based on the characteristics of glutenite reservoirs and used phase-field method to track the oil-gas interface for numerical simulations of dynamic GAGD processes.To explore the factors influencing gas-driven recovery,we simulated the effects of strong heterogeneity and dynamic wettability on the construction process under gravity assistance.Additionally,we introduced multiple dimensionless numbers(including capillary number,viscosity ratio,and Bond number)and conducted a series of numerical simulations.The results demonstrate that gravity enhances the stability of the oil-gas interface but causes unstable pressure fluctuations when passing through different-sized throat regions,particularly leading to front advancement in smaller throats.Although strong heterogeneity has negative impacts on GAGD,they can be mitigated by reducing injection velocity.Increasing oil-wettability promotes oil displacement by overcoming capillary forces,particularly in narrower pores,allowing residual oils to be expelled.Among the dimensionless numbers,the recovery efficiency is directly proportional to the Bond number and inversely proportional to the capillary number and viscosity ratio.Through sensitivity analysis of the dimensionless numbers’impact on the recovery efficiency,a new dimensionless N_(Glu) considering heterogeneity is proposed to accurately predict GAGD recovery of tight glutenite reservoirs.展开更多
The oil and gas industry is increasingly focusing on exploring and developing resources in deep earth layers.At high temperatures,confining pressures,and geostress differences,rock has the mechanical characteristics o...The oil and gas industry is increasingly focusing on exploring and developing resources in deep earth layers.At high temperatures,confining pressures,and geostress differences,rock has the mechanical characteristics of plastic enhancement,which leads to the unclear mechanism of hydraulic fracture expansion.The current fracturing model and construction design lack pertinence,and the fracturing reform is difficult to achieve the expected effect.This paper established a model of elastoplastic hydraulic fracture propagation in deep reservoirs.It considered the enhancement of plasticity by examining the elastoplastic deformation and nonlinear fracturing characteristics of the rock.The results confirmed that the hydraulic fractures in deep reservoirs propagated due to plastic energy dissipation after fracture tip passivation,while the stress concentration declined,which increased propagation resistance.The relationship between geology,engineering factors,degree of plasticity,and fracture propagation is discussed,while the conditions that promote fracture propagation are analyzed to provide theoretical support for deep reservoir fracturing design.展开更多
A calculation model of stress field in laser additive manufacturing of walnut shell composite powder(walnut shell/Co-PES powder)was established.The DFLUX subroutine was used to implement the moveable application of a ...A calculation model of stress field in laser additive manufacturing of walnut shell composite powder(walnut shell/Co-PES powder)was established.The DFLUX subroutine was used to implement the moveable application of a double ellipsoid heat source by considering the mechanical properties varying with temperature.The stress field was simulated by the sequential coupling method,and the experimental results were in good accordance with the simulation results.In addition,the distribution and variation of stress and strain field were obtained in the process of laser additive manufacturing of walnut shell composite powder.The displacement of laser additive manufacturing walnut shell composite parts gradually decreased with increasing preheating temperature,decreasing laser power and increasing scanning speed.During the cooling process,the displacement of laser additive manufacturing of walnut shell composite parts gradually increased with the increasing preheating temperature,decreasing scanning speed and increasing laser power.展开更多
In order to enhance the strength of sustainable walnut shell/Co-PES(WSPC)sintered parts,wax-filtrated posttreatment was carried out.The effects of treating fluid temperature,preheating time and immersion time on the b...In order to enhance the strength of sustainable walnut shell/Co-PES(WSPC)sintered parts,wax-filtrated posttreatment was carried out.The effects of treating fluid temperature,preheating time and immersion time on the bending strength of WSPC wax-filtrated parts were analyzed by single factor analysis method.To obtain an accurate model for predicting the bending strength of the WSPC wax-filtrated part,the experiments were involved by using Box-Behnken design(BBD).Main parameters,such as treating fluid temperature,preheating time and immersion time,and their interactive effects were analyzed through analysis of variance(ANOVA)and graphical contours.The results demonstrated that all parameters’direct effects were significant to bending strength of the WSPC wax-filtrated part.Its optimum value was 5.0 MPa when the treating fluid temperature of 70°C,preheating time of 50 min,and immersion time of 20 s.The predicted models effectively validated had good predicting accuracy.The WSPC wax-filtrated part using optimal processing parameters was processed by investment casting,and then the metal casting of dimensional stability and smooth surface was obtained.Investment casting was done using WSPC wax-filtrated parts under optimal process parameters and then metal parts with stable structure size and smooth surface can be obtained,which indicates that WSPC material can be used for investment casting.展开更多
Ru has recently been regarded as a promising catalyst for hydrogen oxidation reaction(HOR)and hydrogen evolution reaction(HER)due to its similar binding energy towards*H but lower price compared to Pt.Nevertheless,the...Ru has recently been regarded as a promising catalyst for hydrogen oxidation reaction(HOR)and hydrogen evolution reaction(HER)due to its similar binding energy towards*H but lower price compared to Pt.Nevertheless,the quest of high-efficiency Ru-based catalysts for HOR and HER is driven by the current disadvantages including low activity and unsatisfactory stability.Herein,we have fabricated and engineered two-dimensional(2D)Ru-based snow-like nanosheets with Ru/Ru O2interface(Ru/Ru O2SNSs)via a post-annealing treatment.Detailed characterizations and theoretical calculations indicate that the interfacial synergy,which is dependent on the temperature for annealing,can alter the hydrogen binding energy(HBE)and hydroxide binding energy(OHBE),as a result of the enhanced HOR and HER performance.Impressively,the optimal Ru/RuO_(2)SNSs display a mass activity of 9.13 A mgRu^(–1)at an overpotential of 50 m V in 0.1 mol L^(–1)KOH for HOR,which is 65,304,and 21 times higher than those of Ru SNSs(0.14 A mg_(Ru)^(–1)),RuO_(2)SNSs(0.03 A mg_(Ru)^(–1)),and commercial Pt/C(0.43 A mg_(Ru)^(–1)),respectively.Moreover,Ru/RuO_(2)SNSs display improved HER activity with a low overpotential of 20.2 m V for achieving10 m A cm^(-2)in 1 mol L^(–1)KOH.This work not only provides an efficient catalyst for HOR and HER,but also promotes fundamental research on the fabrication and modification of catalysts in heterogeneous catalysis.展开更多
The hydrogen oxidation reaction(HOR)in alkaline conditions is of great importance for the application of anion exchange membrane fuel cells(AEMFCs).However,the electrocatalysts for alkaline HOR generally suffer from t...The hydrogen oxidation reaction(HOR)in alkaline conditions is of great importance for the application of anion exchange membrane fuel cells(AEMFCs).However,the electrocatalysts for alkaline HOR generally suffer from the disadvantage of sluggish kinetics.Herein,we have fabricated Ru2Ni multilayered nanosheets(Ru2Ni MLNSs)in the layer-by-layer manner and engineered the surface properties via postannealing for efficient alkaline HOR.Detailed investigations reveal that such annealing at different temperatures can alter the surface properties of Ru2Ni MLNSs and thus regulate their adsorption abilities toward*H and*OH.In particular,the optimal catalyst exhibits a mass activity of 4.34 A mgRu−1 at an overpotential of 50 mV,which is 18.1 and 13.2 times higher than those of Ru/C(0.24 A mgRu−1)and Pt/C(0.33 A mgPt−1),respectively.Theoretical calculations indicate that the presence of surface O atoms can facilitate the HOR activity while the excessive coverage of O atoms on Ru2Ni surface leads to the strengthened H binding and the decay of HOR activity.This work not only provides an efficient catalyst for alkaline HOR,but it also may shed new light on the design of high-performance catalysts for electrocatalysis and beyond.We have fabricated Ru2Ni multilayer nanosheets(Ru2Ni MLNSs)and realized the surface engineering via an annealing process.Detailed investigations show that such surface engineering can regulate the surface properties and thus promote the alkaline HOR activity.Consequently,the optimal catalyst exhibits a much higher activity than those of commercial Ru/C and Pt/C and is a promising catalyst for alkaline HOR.展开更多
基金supported by the National Natural Science Foundation of China(U22B2075)the Fundamental Research Funds for the Central Universities(2024ZKPYSB03)support from Beijing University of Science and Technology.
文摘Tight glutenite reservoirs are known for strong heterogeneity,complex wettability,and challenging development.Gas-Assisted Gravity Drainage(GAGD)technology has the potential to significantly improve recovery efficiency in glutenite reservoir.However,there is currently limited research on GAGD processes specifically designed for glutenite reservoirs,and there is a lack of relevant dimensionless numbers for predicting recovery efficiency.In this study,we developed a theoretical model based on the characteristics of glutenite reservoirs and used phase-field method to track the oil-gas interface for numerical simulations of dynamic GAGD processes.To explore the factors influencing gas-driven recovery,we simulated the effects of strong heterogeneity and dynamic wettability on the construction process under gravity assistance.Additionally,we introduced multiple dimensionless numbers(including capillary number,viscosity ratio,and Bond number)and conducted a series of numerical simulations.The results demonstrate that gravity enhances the stability of the oil-gas interface but causes unstable pressure fluctuations when passing through different-sized throat regions,particularly leading to front advancement in smaller throats.Although strong heterogeneity has negative impacts on GAGD,they can be mitigated by reducing injection velocity.Increasing oil-wettability promotes oil displacement by overcoming capillary forces,particularly in narrower pores,allowing residual oils to be expelled.Among the dimensionless numbers,the recovery efficiency is directly proportional to the Bond number and inversely proportional to the capillary number and viscosity ratio.Through sensitivity analysis of the dimensionless numbers’impact on the recovery efficiency,a new dimensionless N_(Glu) considering heterogeneity is proposed to accurately predict GAGD recovery of tight glutenite reservoirs.
基金The Youth Science Fund Project of National Natural Science Foundation of China,52404027,Jinbo Lithe General Program of the National Natural Science Foundation of China,52274036,Suling Wang。
文摘The oil and gas industry is increasingly focusing on exploring and developing resources in deep earth layers.At high temperatures,confining pressures,and geostress differences,rock has the mechanical characteristics of plastic enhancement,which leads to the unclear mechanism of hydraulic fracture expansion.The current fracturing model and construction design lack pertinence,and the fracturing reform is difficult to achieve the expected effect.This paper established a model of elastoplastic hydraulic fracture propagation in deep reservoirs.It considered the enhancement of plasticity by examining the elastoplastic deformation and nonlinear fracturing characteristics of the rock.The results confirmed that the hydraulic fractures in deep reservoirs propagated due to plastic energy dissipation after fracture tip passivation,while the stress concentration declined,which increased propagation resistance.The relationship between geology,engineering factors,degree of plasticity,and fracture propagation is discussed,while the conditions that promote fracture propagation are analyzed to provide theoretical support for deep reservoir fracturing design.
基金Supported by the Scientific Research Start-Up Fund Project of Northeast Petroleum University(2019KQ67 and 2021KQ09)the Guiding Innovation Fund Project of Northeast Petroleum University(2021YDL-13)+1 种基金National Natural Science Foundation of China(52075090)Supported by the National Key R&D Program of China(2017YFD0601004).
文摘A calculation model of stress field in laser additive manufacturing of walnut shell composite powder(walnut shell/Co-PES powder)was established.The DFLUX subroutine was used to implement the moveable application of a double ellipsoid heat source by considering the mechanical properties varying with temperature.The stress field was simulated by the sequential coupling method,and the experimental results were in good accordance with the simulation results.In addition,the distribution and variation of stress and strain field were obtained in the process of laser additive manufacturing of walnut shell composite powder.The displacement of laser additive manufacturing walnut shell composite parts gradually decreased with increasing preheating temperature,decreasing laser power and increasing scanning speed.During the cooling process,the displacement of laser additive manufacturing of walnut shell composite parts gradually increased with the increasing preheating temperature,decreasing scanning speed and increasing laser power.
基金This study was supported by Scientific Research Staring Foundation of Northeast Petroleum University(1305021868)the National Natural Science Foundation of China(51475089)+3 种基金the National Key R&D Program of China(2017YFD0601004)the Natural Science Foundation of Heilongjiang Province(ZD2017009)Fundamental Research Funds for the Central Universities(2572017PZ06)the Special Project of Scientific and Technological Development of Central Guidance for Local(ZY16C03).
文摘In order to enhance the strength of sustainable walnut shell/Co-PES(WSPC)sintered parts,wax-filtrated posttreatment was carried out.The effects of treating fluid temperature,preheating time and immersion time on the bending strength of WSPC wax-filtrated parts were analyzed by single factor analysis method.To obtain an accurate model for predicting the bending strength of the WSPC wax-filtrated part,the experiments were involved by using Box-Behnken design(BBD).Main parameters,such as treating fluid temperature,preheating time and immersion time,and their interactive effects were analyzed through analysis of variance(ANOVA)and graphical contours.The results demonstrated that all parameters’direct effects were significant to bending strength of the WSPC wax-filtrated part.Its optimum value was 5.0 MPa when the treating fluid temperature of 70°C,preheating time of 50 min,and immersion time of 20 s.The predicted models effectively validated had good predicting accuracy.The WSPC wax-filtrated part using optimal processing parameters was processed by investment casting,and then the metal casting of dimensional stability and smooth surface was obtained.Investment casting was done using WSPC wax-filtrated parts under optimal process parameters and then metal parts with stable structure size and smooth surface can be obtained,which indicates that WSPC material can be used for investment casting.
基金supported by the National Key R&D Program of China(2020YFB1505802)the Ministry of Science and Technology of China(2017YFA0208200,2016YFA0204100)+4 种基金the National Natural Science Foundation of China(22025108,U21A20327,and22121001)China Postdoctoral Science Foundation(2020M682083)Guangdong Provincial Natural Science Fund for Distinguished Young Scholars(2021B1515020081)Start-up Support from Xiamen University and the Guangzhou Key Laboratory of Low Dimensional Materials and Energy Storage Devices(20195010002)。
文摘Ru has recently been regarded as a promising catalyst for hydrogen oxidation reaction(HOR)and hydrogen evolution reaction(HER)due to its similar binding energy towards*H but lower price compared to Pt.Nevertheless,the quest of high-efficiency Ru-based catalysts for HOR and HER is driven by the current disadvantages including low activity and unsatisfactory stability.Herein,we have fabricated and engineered two-dimensional(2D)Ru-based snow-like nanosheets with Ru/Ru O2interface(Ru/Ru O2SNSs)via a post-annealing treatment.Detailed characterizations and theoretical calculations indicate that the interfacial synergy,which is dependent on the temperature for annealing,can alter the hydrogen binding energy(HBE)and hydroxide binding energy(OHBE),as a result of the enhanced HOR and HER performance.Impressively,the optimal Ru/RuO_(2)SNSs display a mass activity of 9.13 A mgRu^(–1)at an overpotential of 50 m V in 0.1 mol L^(–1)KOH for HOR,which is 65,304,and 21 times higher than those of Ru SNSs(0.14 A mg_(Ru)^(–1)),RuO_(2)SNSs(0.03 A mg_(Ru)^(–1)),and commercial Pt/C(0.43 A mg_(Ru)^(–1)),respectively.Moreover,Ru/RuO_(2)SNSs display improved HER activity with a low overpotential of 20.2 m V for achieving10 m A cm^(-2)in 1 mol L^(–1)KOH.This work not only provides an efficient catalyst for HOR and HER,but also promotes fundamental research on the fabrication and modification of catalysts in heterogeneous catalysis.
基金gratefully acknowledge the financial support of the National Key R&D Program of China(grant no.2020YFB1505802)the Ministry of Science and Technology of China(grant no.2017YFA0208200)+3 种基金the National Natural Science Foundation of China(grant nos.22025108,U21A20327,and 22121001)the China Postdoctoral Science Foundation(grant no.2020M682083)Guangdong Provincial Natural Science Fund for Distinguished Young Scholars(grant no.2021B1515020081)start-up support from Xiamen University.
文摘The hydrogen oxidation reaction(HOR)in alkaline conditions is of great importance for the application of anion exchange membrane fuel cells(AEMFCs).However,the electrocatalysts for alkaline HOR generally suffer from the disadvantage of sluggish kinetics.Herein,we have fabricated Ru2Ni multilayered nanosheets(Ru2Ni MLNSs)in the layer-by-layer manner and engineered the surface properties via postannealing for efficient alkaline HOR.Detailed investigations reveal that such annealing at different temperatures can alter the surface properties of Ru2Ni MLNSs and thus regulate their adsorption abilities toward*H and*OH.In particular,the optimal catalyst exhibits a mass activity of 4.34 A mgRu−1 at an overpotential of 50 mV,which is 18.1 and 13.2 times higher than those of Ru/C(0.24 A mgRu−1)and Pt/C(0.33 A mgPt−1),respectively.Theoretical calculations indicate that the presence of surface O atoms can facilitate the HOR activity while the excessive coverage of O atoms on Ru2Ni surface leads to the strengthened H binding and the decay of HOR activity.This work not only provides an efficient catalyst for alkaline HOR,but it also may shed new light on the design of high-performance catalysts for electrocatalysis and beyond.We have fabricated Ru2Ni multilayer nanosheets(Ru2Ni MLNSs)and realized the surface engineering via an annealing process.Detailed investigations show that such surface engineering can regulate the surface properties and thus promote the alkaline HOR activity.Consequently,the optimal catalyst exhibits a much higher activity than those of commercial Ru/C and Pt/C and is a promising catalyst for alkaline HOR.
