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Comprehensive metabolic profiling of dioxin-like compounds exposure in laying hens:Implications for toxicity assessment
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作者 Xiaoxu Hu Tong Xu +12 位作者 Yangsheng Chen Qian zhang Lijuan Tang Liping Zheng Chu Wang Pu Wang Shujun Dong Ruiguo Wang su zhang Qinghua zhang Heidi Qunhui Xie Li Xu Bin Zhao 《Journal of Environmental Sciences》 2025年第2期107-115,共9页
The evaluation of toxicity related to polychlorinated dibenzo-p-dioxins and furans(PCDD/Fs)and dioxin-like polychlorinated biphenyls(DL-PCBs)is crucial for a comprehensive risk assessment in real-world exposure scenar... The evaluation of toxicity related to polychlorinated dibenzo-p-dioxins and furans(PCDD/Fs)and dioxin-like polychlorinated biphenyls(DL-PCBs)is crucial for a comprehensive risk assessment in real-world exposure scenarios.This study employed a controlled feeding experiment to investigate the metabolic effects of dioxin-like compounds(DLCs)on laying hens via feed exposure.Diets enriched with two concentrations(1.17 and 5.13 pg toxic equivalents(TEQ)/g dry weight(dw))were administered over 14 days,followed by 28 days of clean feed.Metabolomics analyses of blood samples revealed significant metabolic variations between PCDD/Fs and DL-PCBs exposed groups and controls,reflecting the induced metabolic disruption.Distinct changes were observed in sphingosine,palmitoleic acid,linoleate,linolenic acid,taurocholic acid,indole acrylic acid,and dibutyl phthalate levels,implying possible connections between PCDD/Fs and DL-PCBs toxic effects and energy-neuronal imbalances,along with lipid accumulation and anomalous amino acid metabolism,impacting taurine metabolism.Moreover,we identified three differential endogenous metabolites—L-tryptophan,indole-3-acetaldehyde,and indole acrylic acid—as potential ligands for the aryl hydrocarbon receptor(AhR),suggesting their role inmediating PCDD/Fs and DL-PCBs toxicity.This comprehensive investigation provides novel insights into the metabolic alterations induced by PCDD/Fs and DL-PCBs in laying hens,thereby enhancing our ability to assess risks associated with their exposure in human populations. 展开更多
关键词 Polychlorinated dibenzo-p-dioxins and furans Dioxin-like polychlorinated BIPHENYLS Laying hens METABOLOMIC
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Sandwiching Sulfur into the Dents Between N,O Co-Doped Graphene Layered Blocks with Strong Physicochemical Confinements for Stable and High-Rate Li-S Batteries 被引量:6
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作者 Mengjiao Shi su zhang +5 位作者 Yuting Jiang Zimu Jiang Longhai zhang Jin Chang Tong Wei Zhuangjun Fan 《Nano-Micro Letters》 SCIE EI CAS CSCD 2020年第11期13-24,共12页
The development of lithium-sulfur batteries(LSBs)is restricted by their poor cycle stability and rate performance due to the low conductivity of sulfur and severe shuttle effect.Herein,an N,O co-doped graphene layered... The development of lithium-sulfur batteries(LSBs)is restricted by their poor cycle stability and rate performance due to the low conductivity of sulfur and severe shuttle effect.Herein,an N,O co-doped graphene layered block(NOGB)with many dents on the graphene sheets is designed as effective sulfur host for high-performance LSB s.The sulfur platelets are physically confined into the dents and closely contacted with the graphene scaffold,ensuring structural stability and high conductivity.The highly doped N and O atoms can prevent the shuttle effect of sulfur species by strong chemical adsorption.Moreover,the micropores on the graphene sheets enable fast Li^+transport through the blocks.As a result,the obtained NOGB/S composite with 76 wt%sulfur content shows a high capacity of 1413 mAh g^-1 at 0.1 C,good rate performance of 433 mAh g^-1 at 10 C,and remarkable stability with 526 mAh g^-1 at after 1000 cycles at 1 C(average decay rate:0.038%per cycle).Our design provides a comprehensive route for simultaneously improving the conductivity,ion transport kinetics,and preventing the shuttle effect in LSBs. 展开更多
关键词 GRAPHENE Physicochemical confinement Cycle stability Shuttle effect Li-S batteries
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Effect of radio-frequency substrate bias on ion properties and sputtering behavior of 2 MHz magnetron sputtering
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作者 Min ZHU Chao YE +2 位作者 Xiangying WANG Amin JIANG su zhang 《Plasma Science and Technology》 SCIE EI CAS CSCD 2019年第1期100-107,共8页
The effect of radio-frequency substrate bias on ion properties and sputtering behavior of 2 MHz magnetron discharge was investigated. The ion velocity distribution function(IVDF), the maximum ion energy and ion flux d... The effect of radio-frequency substrate bias on ion properties and sputtering behavior of 2 MHz magnetron discharge was investigated. The ion velocity distribution function(IVDF), the maximum ion energy and ion flux density were measured at the substrate by a retarding field energy analyzer. The sputtering behavior was investigated by the electric characteristics of target and bias discharges using voltage–current probe technique. It was found that the substrate bias led to the decrease of sputtering power, voltage and current with the amplitude <7.5%. The substrate bias also led to the broadening of IVDFs and the increase of ion flux density, made the energy divergent of ions impacting the substrate. This effect was further enhanced by increasing bias power and reducing discharge pressure. 展开更多
关键词 RF MAGNETRON SPUTTERING RF substrate BIAS ION property electric characteristic
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Ion property and electrical characteristics of 60MHz very-high-frequency magnetron discharge at low pressure
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作者 Amin JIANG Chao YE +2 位作者 Xiangying WANG Min ZHU su zhang 《Plasma Science and Technology》 SCIE EI CAS CSCD 2018年第10期84-89,共6页
The pre-ionized 60 MHz very-high-frequency (VHF) magnetron discharge at low pressure, assisted by inductively coupled plasma (ICP) discharge, was developed. The measurement of ion flux density and ion energy to th... The pre-ionized 60 MHz very-high-frequency (VHF) magnetron discharge at low pressure, assisted by inductively coupled plasma (ICP) discharge, was developed. The measurement of ion flux density and ion energy to the substrate was carried out by a retarding field energy analyzer. The electric characteristics of discharge were also investigated by voltage-current probe technique. It was found that by reducing the discharge pressure of VHF magnetron discharge from 5 to 1 Pa, the ion flux density increased about four times, meanwhile the ion energy also increased doubly. The electric characteristics of discharge also showed that a little improvement of sputtering effectiveness was achieved by reducing discharge pressure. Therefore, the deposition property of VHF (60 MHz) magnetron sputtering can be improved by reducing the discharge pressure using the ICP-assisted pre-ionized discharge. 展开更多
关键词 VHF magnetron sputtering low pressure discharge ion property electric characteristic
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Cultural Practices for Propagation of Spatholobus suberectus via Cutting into Polybags
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作者 Maojin YE Ribin HUANG +4 位作者 Chunyun CHEN Dachang NING su zhang Shufu CHEN Qingsong DONG 《Medicinal Plant》 CAS 2021年第5期17-19,24,共4页
In this paper,the propagation of Spatholobus suberectus Dunn.was optimized based on the research results conducted in propagation for many years and the actual need for the planting materials.According to the requirem... In this paper,the propagation of Spatholobus suberectus Dunn.was optimized based on the research results conducted in propagation for many years and the actual need for the planting materials.According to the requirements of Good Agricultural Practices for Chinese Medicinal Drugs,cultural practices for propagation of S.suberectus were summed up and standardized,including the environmental requirements,land preparation,bed preparation,cutting of scions,cuttings treatment,cutting,management of cuttings at the nursery,bagged cuttings ready for transplanting,packing and handling,transportation,and preparation of records for archives. 展开更多
关键词 Spatholobus suberectus Dunn. Bagged cuttings Cutting directly into bags Cultural practices Chinese traditional medicinal plants in southern China
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A novel flexible nerve guidance conduit promotes nerve regeneration while providing excellent mechanical properties 被引量:1
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作者 Tong Li Quhan Cheng +11 位作者 Jingai zhang Boxin Liu Yu Shi Haoxue Wang Lijie Huang su zhang Ruixin zhang Song Wang Guangxu Lu Peifu Tang Zhongyang Liu Kai Wang 《Neural Regeneration Research》 SCIE CAS 2025年第7期2084-2094,共11页
Autografting is the gold standard for surgical repair of nerve defects>5 mm in length;however,autografting is associated with potential complications at the nerve donor site.As an alternative,nerve guidance conduit... Autografting is the gold standard for surgical repair of nerve defects>5 mm in length;however,autografting is associated with potential complications at the nerve donor site.As an alternative,nerve guidance conduits may be used.The ideal conduit should be flexible,resistant to kinks and lumen collapse,and provide physical cues to guide nerve regeneration.We designed a novel flexible conduit using electrospinning technology to create fibers on the innermost surface of the nerve guidance conduit and employed melt spinning to align them.Subsequently,we prepared disordered electrospun fibers outside the aligned fibers and helical melt-spun fibers on the outer wall of the electrospun fiber lumen.The presence of aligned fibers on the inner surface can promote the extension of nerve cells along the fibers.The helical melt-spun fibers on the outer surface can enhance resistance to kinking and compression and provide stability.Our novel conduit promoted nerve regeneration and functional recovery in a rat sciatic nerve defect model,suggesting that it has potential for clinical use in human nerve injuries. 展开更多
关键词 aligned fibers anti-kinking helical fibers nerve guidance conduit nerve regeneration peripheral nerve injury topological guidance
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基于选择性化学刻蚀的低缺陷炭导电网络原位构筑及其对活性炭比 表面积与导电性的协同增强
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作者 张晶 张苏 +8 位作者 李齐齐 纪麟肯 李禹彤 任宇康 臧小蓓 曹宁 胡涵 梁鹏 范壮军 《物理化学学报》 北大核心 2025年第10期82-92,共11页
导电性是影响活性炭的电化学性能的重要因素,但活性炭发达的孔隙结构通常会破坏连续导电网络。本研究以沥青/聚丙烯腈(PAN)混合前驱体为原料,提出一种简单的选择性化学蚀刻策略制备兼具高比表面积与高导电性的活性炭。研究发现,PAN衍生... 导电性是影响活性炭的电化学性能的重要因素,但活性炭发达的孔隙结构通常会破坏连续导电网络。本研究以沥青/聚丙烯腈(PAN)混合前驱体为原料,提出一种简单的选择性化学蚀刻策略制备兼具高比表面积与高导电性的活性炭。研究发现,PAN衍生炭包含无定形与结晶炭;在活化过程中,高反应活性的无定形炭被优先刻蚀,促使低缺陷炭骨架原位重构为连续导电网络。优化样品的比表面积达2773 m^(2)·g^(-1),电导率提升了2.6倍(912 S·m^(-1)),性能优于大多数活性炭。此外,沥青和PAN分子之间通过预氧化产生的强交联效应使制备的活性炭的产率(58%)显著高于纯沥青基活性炭(34%)。组装的对称超级电容器在10 mg·cm^(-2)高负载量下仍表现出优异的面电容(1 A·g^(-1)时为2.8 F·cm^(-2))、良好的倍率性能(50 A·g^(-1)时电容保持率为41%)、高的能量密度(10.9 Wh·kg^(-1))及卓越的循环稳定性(50000次循环后容量无衰减),本工作显示了高导电活性炭在实际应用中的巨大潜力,为先进储能器件用导电活性炭的制备提供了新思路。 展开更多
关键词 活性炭 导电性 比表面积 超级电容器 化学刻蚀
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基于BIM的结构正向设计应用研究 被引量:1
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作者 梁锦皓 苏章 +2 位作者 李文建 程哲 程亮 《中国高新科技》 2025年第5期86-88,共3页
文章立足于大型公共建筑项目的正向设计过程,深入探索在当前技术环境下,结构专业正向设计流程的实践与挑战。文章聚焦于BIM技术在结构设计方向的应用,包括三维设计、出图与深化等方面,并针对当前技术条件下所面临的挑战进行深入探讨。
关键词 正向设计 结构设计 BIM协同
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前驱体机械压实制备高密度活性炭及其致密电容储能性能
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作者 李齐齐 张苏 +6 位作者 江娱婷 朱琳娜 郭楠楠 张晶 李禹彤 魏彤 范壮军 《物理化学学报》 北大核心 2025年第3期113-126,共14页
大比表面积活性炭的密度普遍较低、体积储能性能不佳,难以满足超级电容器的小型化发展需求。针对此,本工作提出在活化前对炭前驱体进行机械压实以提高活性炭密度的普适性方法,并研究了机械压实对由外而内活化(炭粉/KOH混合物)和均匀离... 大比表面积活性炭的密度普遍较低、体积储能性能不佳,难以满足超级电容器的小型化发展需求。针对此,本工作提出在活化前对炭前驱体进行机械压实以提高活性炭密度的普适性方法,并研究了机械压实对由外而内活化(炭粉/KOH混合物)和均匀离子活化(热解含钾盐类)所制备活性炭的比表面积、孔结构和电容储能性能的影响规律。结果表明,对前驱体进行机械压实能够提高活化反应效率、活性炭密度和体积电容储能性能。随着机械压力升高,由外而内活化所得活性炭的比表面积和孔隙率先升高后降低,原因在于机械压实能够消除颗粒间的空隙以增加前驱体与活化剂之间的接触,进而显著提高了活化效率。对于均匀离子活化,活性炭的比表面积和孔隙率呈现先降低后升高的趋势,这可能是由于致密前驱体抑制了热解过程中产生的活性气体分子(H_(2)O、CO_(2)等)快速散逸,使之继续参与活化反应,提高了活化刻蚀效率。本工作为大比表面积和高密度活性炭的设计制备提供了简单思路。 展开更多
关键词 活性炭 机械压实 活化 超级电容器 体积比容量
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577nm微脉冲激光联合康柏西普治疗玻璃体切除术后糖尿病性黄斑水肿 被引量:10
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作者 孙光丽 张苏 +2 位作者 覃雪 刘写写 姚进 《国际眼科杂志》 CAS 北大核心 2023年第6期996-1000,共5页
目的:分析577nm微脉冲激光(SML)光凝联合玻璃体腔注射康柏西普治疗增殖性糖尿病视网膜病变(PDR)患者玻璃体切除术后发生糖尿病性黄斑水肿(DME)的临床效果。方法:回顾性分析2019-01/2021-06就诊于我院经玻璃体切除治疗的PDR患者,术后发生... 目的:分析577nm微脉冲激光(SML)光凝联合玻璃体腔注射康柏西普治疗增殖性糖尿病视网膜病变(PDR)患者玻璃体切除术后发生糖尿病性黄斑水肿(DME)的临床效果。方法:回顾性分析2019-01/2021-06就诊于我院经玻璃体切除治疗的PDR患者,术后发生DME患者29例30眼。根据治疗方式不同分为两组,单纯注射组患者14例14眼行玻璃体腔注射康柏西普,联合治疗组患者15例16眼行黄斑区577nm微脉冲激光光凝联合玻璃体腔注射康柏西普。比较两组患者治疗前及治疗6、12mo最佳矫正视力(BCVA)、黄斑中心凹视网膜厚度(CMT)的变化,以及治疗前、治疗12mo多焦视网膜电流图(mfERG)的变化。结果:两组患者治疗6、12mo BCVA(LogMAR)均较术前改善,CMT均较术前下降(均P<0.001)。单纯注射组治疗前及治疗6、12mo BCVA(LogMAR)、CMT与联合治疗组比较均无差异(均P>0.05)。治疗12mo单纯注射组较联合治疗组振幅略低(23.02±3.13 vs 26.50±3.33μV/deg2),潜伏期延长(38.75±1.62 vs 34.21±3.06ms)(均P≤0.001)。随访12mo,单纯注射组注射康柏西普8.14±1.46次,联合治疗组5.05±1.51次(P<0.05)。结论:577nm微脉冲激光光凝联合玻璃体腔注射康柏西普可有效缓解玻璃体切除术后DME患者的黄斑水肿、提高BCVA,并能改善黄斑区视功能,有效减少康柏西普注射次数。 展开更多
关键词 577nm微脉冲激光 康柏西普 黄斑水肿 玻璃体切除
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Effect of heat treatment on microstructure and mechanical properties of a novel Al-Zn-Mg-Cu alloy
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作者 Yan-mei Yang Xin-chen Tang +13 位作者 Ye-fei Li Xue-wei Fang Da-wei Yi Zhi-yun zhang Qiao-ling Zheng Zhi-xi Wang Guo-yu zhang su zhang Hao Cheng Yang He Yi-bo Liu Zi-han Wu Ya-nan Chen Yi-min Gao 《China Foundry》 2025年第3期292-300,共9页
Effects of solution and aging treatment on the microstructure and mechanical properties of a novel Al-Zn-Mg-Cu alloy by microalloying rare elements Sc and Er were studied.The results show that solution time has a visi... Effects of solution and aging treatment on the microstructure and mechanical properties of a novel Al-Zn-Mg-Cu alloy by microalloying rare elements Sc and Er were studied.The results show that solution time has a visible influence on the microstructure and mechanical properties of the alloy.Specifically,as the solution time increases,the area fraction of the residual phase in the alloy decreases,and the shape of the grain becomes more spheroidal and coarser,leading to a decrease in hardness.This is attributed to the dissolution of strengthening phases during the solution treatment,which weakens the solid solution strengthening effect.The single-stage aging treatment shows an initial increase in strength and hardness of the alloy,followed by a decrease as the aging time is extended,until a steady state is achieved.The optimal single-aging conditions are found to be at 120℃ for 24 h,where the alloy exhibits an excellent combination of high strength and good ductility,with an ultimate tensile strength(UTS)of 523 MPa,yield strength(YS)of 482 MPa,and elongation(El)of 1.75%,respectively.Compared to single-stage aging,double-stage aging(120℃ for 24 h and then 150℃ for 52 h)significantly increases the elongation of the alloy(4.17%),but the UTS reduces to 465.29 MPa,and YS reduces to 410.64 MPa.Transmission electron microscopy(TEM)observations disclose that the grain size,the distribution spacing of precipitates along the grain boundary,and the width of the precipitation-free zone(PFZ)all undergo augmentation as the duration of the second stage aging process elongates. 展开更多
关键词 Al-Zn-Mg-Cu alloy aging treatment STRENGTH precipitate free zone
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阈值下导航激光治疗慢性中心性浆液性脉络膜视网膜病变疗效分析 被引量:4
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作者 张苏 姚进 《国际眼科杂志》 CAS 北大核心 2022年第10期1687-1692,共6页
目的:对比分析智能精准靶向导航阈值下能量和微脉冲激光治疗慢性中心性浆液性脉络膜视网膜病变(cCSC)的疗效。方法:回顾性临床研究。2020-01/2021-01于南京医科大学附属眼科医院就诊的cCSC患者36例40眼纳入研究,其中19例23眼接受智能精... 目的:对比分析智能精准靶向导航阈值下能量和微脉冲激光治疗慢性中心性浆液性脉络膜视网膜病变(cCSC)的疗效。方法:回顾性临床研究。2020-01/2021-01于南京医科大学附属眼科医院就诊的cCSC患者36例40眼纳入研究,其中19例23眼接受智能精准靶向导航阈值下能量激光治疗(靶向导航组),17例17眼接受微脉冲激光(SML)治疗(SML组)。两组患者基线资料比较,差异无统计学意义(P>0.05)。对比两组治疗前和治疗后2wk, 1、3、6mo最佳矫正视力(BCVA,LogMAR)、黄斑中心视网膜厚度(CMT)、黄斑中心凹视网膜下积液(SRF)、视网膜浅层毛细血管丛(SCP)、视网膜深层毛细血管丛(DCP)的血流密度和黄斑中心凹无血管区(FAZ)面积。结果:治疗后3、6mo,两组BCVA均较治疗前明显提高(P<0.05)。靶向导航组CMT在治疗后2wk较治疗前明显降低,SML组在治疗后1mo出现降低(P<0.05),治疗后3、6mo较治疗前明显降低(P<0.05),而两组间无明显差异(P>0.05)。两组患者SRF吸收情况有差异(P<0.05),靶向导航组患者SRF完全吸收率高于SML组患者。两组患者治疗后各时间点SCP、DCP、FAZ较治疗前均无改变(P>0.05)。结论:智能精准靶向导航阈值下能量激光治疗可迅速改善视网膜形态,缩短cCSC病程以促进视功能恢复,具有显效时间快、费用低、无创、可重复等优点,可成为临床治疗cCSC新方法。 展开更多
关键词 智能精准靶向导航激光 阈值下能量 慢性中心性浆液性脉络膜视网膜病变 微脉冲激光
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视网膜内界膜移植在大孔径黄斑裂孔手术的应用 被引量:1
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作者 张苏 姚进 《国际眼科杂志》 CAS 北大核心 2019年第11期1974-1977,共4页
目的:探讨视网膜内界膜移植治疗大孔径黄斑裂孔的疗效。方法:对2016-03/2018-03在我院进行玻璃体切割手术治疗的大孔径(>700μm)特发性黄斑裂孔患者35例资料进行回顾性分析,其中A组(17例)患者行常规玻璃体切割联合内界膜剥除,B组(18... 目的:探讨视网膜内界膜移植治疗大孔径黄斑裂孔的疗效。方法:对2016-03/2018-03在我院进行玻璃体切割手术治疗的大孔径(>700μm)特发性黄斑裂孔患者35例资料进行回顾性分析,其中A组(17例)患者行常规玻璃体切割联合内界膜剥除,B组(18例)患者行玻璃体切割联合内界膜移植术,术后随诊3~6mo,对术前、术后3mo的裂孔闭合率、BCVA进行比较。结果:术后3mo A组裂孔闭合率为65%,B组裂孔闭合率为100%(P<0.05);术后3mo A组BCVA较术前显著提高(提高2行及以上)者占35%,B组较术前显著提高者占78%(P<0.05)。结论:内界膜移植可提高大孔径特发性黄斑裂孔的术后裂孔闭合率,在一定程度上改善术后视功能,是一种安全有效的手术方式。 展开更多
关键词 黄斑裂孔 内界膜移植 内界膜剥除 玻璃体切割 裂孔闭合率
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超声波辅助低共熔溶剂提取对咖啡蛋白结构和功能特性的影响 被引量:4
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作者 苏璋 胡发广 +4 位作者 于鑫欣 李贵平 付兴飞 夏光华 董文江 《热带作物学报》 CSCD 北大核心 2024年第8期1714-1726,共13页
为探索咖啡蛋白在食品加工中的应用,以脱脂生咖啡粉为原料,探究不同超声波功率(0、200、400、600、800 W)与低共熔溶剂法、碱法协同作用对咖啡蛋白组成成分(聚丙烯酰胺凝胶电泳,SDS-PAGE)、结构特性(粒径分布、傅里叶红外光谱、圆二色... 为探索咖啡蛋白在食品加工中的应用,以脱脂生咖啡粉为原料,探究不同超声波功率(0、200、400、600、800 W)与低共熔溶剂法、碱法协同作用对咖啡蛋白组成成分(聚丙烯酰胺凝胶电泳,SDS-PAGE)、结构特性(粒径分布、傅里叶红外光谱、圆二色光谱、荧光光谱和扫描电镜)和功能特性(溶解度、吸水性、吸油性和乳化特性)的影响。结果表明:由低共熔溶剂提取的咖啡蛋白(DES)平均粒径(12.30μm)显著小于由碱法提取的咖啡蛋白(AEP)平均粒径(113.67μm);DES在酸性条件下溶解度更高,AEP在碱性条件下溶解度更高;DES比AEP有更好的吸水性和吸油性。经超声预处理后,咖啡蛋白电泳图谱、傅里叶红外光谱、圆二色光谱和荧光光谱结果分析表明,不同超声波功率预处理未引起蛋白质分子量分布的重大变化,但是对蛋白质的二级结构和三级结构产生影响。表面微观结构表明,DES表面结构较疏松多孔,AEP表面紧密平坦,超声预处理后AEP微观结构变得疏松多孔,纹理变得分散,并呈现出更多的不规则碎片;DES表面发生略微变化,在400 W和600 W处理15 min时表现出更多小颗粒多孔无序结构,微观结构变化可影响蛋白质的化学和物理性质及其功能特性。在超声功率为400 W时,DES粒径显著减小,粒径参数D[3,2]和D[4,3]分别从10.50、30.43μm减小到7.89、11.27μm;溶解度显著提高,在酸性、碱性条件下溶解度分别由47%、71%上升到75%、81%。此外,超声预处理可提高咖啡蛋白的吸水性和乳化活性,这些均为蛋白质在食品应用中的重要功能特性。研究表明采用超声波技术对咖啡蛋白进行改性有效果,研究结果可为咖啡蛋白在食品加工中的应用提供理论依据。 展开更多
关键词 咖啡蛋白 超声波功率 低共熔溶剂 结构特征 功能特性
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炭-/石墨烯量子点在超级电容器中的应用 被引量:14
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作者 朱家瑶 董玥 +1 位作者 张苏 范壮军 《物理化学学报》 SCIE CAS CSCD 北大核心 2020年第2期30-45,共16页
炭-/石墨烯量子点作为新兴的炭纳米材料,因具有独特的小尺寸效应和丰富的边缘活性位点而在高性能超级电容器电极材料的研发方面展现出巨大潜力。针对目前炭-/石墨烯量子点在超级电容器电极材料方面的应用优势和存在的关键问题,本文以炭-... 炭-/石墨烯量子点作为新兴的炭纳米材料,因具有独特的小尺寸效应和丰富的边缘活性位点而在高性能超级电容器电极材料的研发方面展现出巨大潜力。针对目前炭-/石墨烯量子点在超级电容器电极材料方面的应用优势和存在的关键问题,本文以炭-/石墨烯量子点、量子点/导电炭复合材料、量子点/金属氧化物复合材料、量子点/导电聚合物复合材料以及量子点衍生炭这些电极材料为脉络,梳理了近年来该领域的发展状况,尝试阐释炭-/石墨烯量子点在电极材料、复合材料和衍生炭电极材料中所起到的关键作用,最后对炭-/石墨烯量子点电极材料的发展进行了展望。本综述以期为炭-/石墨烯量子点基电极材料的研究提供一定参考和依据。 展开更多
关键词 炭量子点 石墨烯量子点 超级电容器 复合材料 炭材料
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受教育水平与退休后再就业:基于CHARLS数据的实证研究 被引量:8
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作者 杨筠 张苏 宁向东 《经济学报》 2018年第3期169-196,共28页
随着预期寿命增加和教育水平的提升,老年劳动者成为劳动力市场的重要组成部分,再就业被越来越多的国家重视和研究。再就业反映了劳动者的主观决策,研究再就业对于设计更优的退休制度具有重要意义。CHARLS数据显示,现阶段我国退休者的再... 随着预期寿命增加和教育水平的提升,老年劳动者成为劳动力市场的重要组成部分,再就业被越来越多的国家重视和研究。再就业反映了劳动者的主观决策,研究再就业对于设计更优的退休制度具有重要意义。CHARLS数据显示,现阶段我国退休者的再就业率为32.18%,并且个体受教育水平和再就业率呈正"U"型,低等学历者和高等学历者的再就业率最高,分别为36.33%和33.33%,而中等学历的再就业率最低,不到30%。在考虑了个体因素、家庭因素等控制变量后,上述关系更为显著。在经过稳健性检验后这一结果依然成立。其背后的机制是,教育水平较低的退休者由于收入水平较低,需要延长劳动时间获得收入,我们称之为"收入补偿"型再就业;教育水平较高的退休者收入水平更高但工作年限较短,需要延长劳动时间以弥补教育投资,我们称之为"教育补偿"型再就业。前者具有"被动性",后者具有"主动性"并在一定程度上有马斯洛的"自我实现"的意义。我们的研究对于退休制度改革有一定的启发意义。 展开更多
关键词 受教育水平 再就业 收入补偿 教育补偿
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植物基多孔炭材料在超级电容器中的应用 被引量:24
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作者 郭楠楠 张苏 +1 位作者 王鲁香 贾殿赠 《物理化学学报》 SCIE CAS CSCD 北大核心 2020年第2期87-107,共21页
植物基多孔炭具有发达的孔结构、大的表面积、较为成熟的制备工艺、丰富的来源、低廉的价格,是目前商业应用范围最广的超级电容器电极材料。然而在实际应用中仍然存在着质量/体积比容量较低、倍率性能差等问题。本文针对先进电容器件的... 植物基多孔炭具有发达的孔结构、大的表面积、较为成熟的制备工艺、丰富的来源、低廉的价格,是目前商业应用范围最广的超级电容器电极材料。然而在实际应用中仍然存在着质量/体积比容量较低、倍率性能差等问题。本文针对先进电容器件的高能量密度、优异功率性能的要求,首先介绍了近年来发展的植物基多孔炭的制备方法,讨论了植物前驱体的组成和结构对其产物结构的影响以及与其电化学性能之间的构效关系,特别总结了近年来植物基超大比表面积多孔炭、中孔炭、层次化多孔炭的制备方法和电容储能性能。针对大比表面积多孔炭用于超级电容器时的体积性能不佳这一关键问题,本文还总结了提高植物基多孔炭体积电化学性能的方法。最后,对植物基多孔电极材料存在的问题进行了分析与总结,并展望了其研究前景。 展开更多
关键词 超级电容器 电极材料 植物 多孔炭材料 电化学性能
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Activation of autophagy in the retina after optic nerve crush injury in rats 被引量:7
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作者 Li-Hua Kang su zhang +1 位作者 Sheng Jiang Nan Hu 《International Journal of Ophthalmology(English edition)》 SCIE CAS 2019年第9期1395-1401,共7页
AIM: To investigate the activation of autophagy in rat retina after optic nerve crush(ONC) and evaluate its relationship with apoptosis of retinal ganglion cells(RGCs).METHODS: The ONC model was established. Western b... AIM: To investigate the activation of autophagy in rat retina after optic nerve crush(ONC) and evaluate its relationship with apoptosis of retinal ganglion cells(RGCs).METHODS: The ONC model was established. Western blots were performed to investigate expression of p62, LC3 and Beclin-1. Transmission electron microscopy was performed to discover the autophagosomes in the retina after ONC. Immunohistochemistry was used to confirm the distribution of LC3. TUNEL was performed to confirm the relationship between autophagy and RGC apoptosis. RESULTS: p62/Beclin-1 ratio was declined shortly after ONC until to day 7 after ONC and then restored to a normal level at day 21. There was an opposite change in the LC3-II/LC3 I ratio in the retina compared to the p62/Beclin-1 ratio. Increased autophagosomes were found after ONC using transmission electron microscopy, and most of the LC3-stained cells were colocalized with RGCs and Müller cells. More LC3-immunoreactive cells and apoptotic RGCs were found on day 7 following ONC. CONCLUSION: Possible activation of autophagy in RGCs after ONC;autophagy mainly occurred in RGCs and Müller cells, and the apoptosis of RGCs after ONC may be partly associated with autophagic activation. 展开更多
关键词 AUTOPHAGY optic NERVE CRUSH apoptosis retinal GANGLION cells rat
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术毕注射康柏西普联合25G玻璃体切割术治疗早期PDR合并玻璃体积血 被引量:9
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作者 张苏 孙光丽 +1 位作者 徐向忠 姚进 《国际眼科杂志》 CAS 北大核心 2023年第3期483-487,共5页
目的:分析探讨手术结束时玻璃体腔注射康柏西普联合25G微创玻璃体切割手术(PPV)在治疗早期增殖性糖尿病视网膜病变(PDR)合并玻璃体积血的有效性和安全性。方法:回顾性研究分析就诊于南京医科大学眼科医院患有PDR合并有玻璃体积血需要行... 目的:分析探讨手术结束时玻璃体腔注射康柏西普联合25G微创玻璃体切割手术(PPV)在治疗早期增殖性糖尿病视网膜病变(PDR)合并玻璃体积血的有效性和安全性。方法:回顾性研究分析就诊于南京医科大学眼科医院患有PDR合并有玻璃体积血需要行平坦部PPV患者60例60眼。依据患者注药时间分为术毕联合康柏西普注射组(A组)20例20眼、术前康柏西普注射组(B组)20例20眼和无注射(C组)20例20眼三组进行观察分析,分析三组患者的手术前后视力、眼压、术中情况、术后预后及并发症的差异。结果:三组患者的手术前基本情况及手术时间均无差异,三组术中均未出现医源性裂孔、硅油填充,术后均未出现复发性视网膜脱离。三组术后1、3、6mo最佳矫正视力(BCVA)均较术前改善(P<0.05),注射组(A组和B组)术眼术后BCVA改善程度均优于无注射组(C组),均有差异(P<0.05)。A组术后晚期玻璃体积血(术后1mo之后)发生率明显低于B组和C组(均P<0.05)。注射组(A组和B组)术眼中央视网膜厚度在术后1、3、6mo均低于无注射组(C组),均有差异(P<0.05)。结论:术毕注射康柏西普同术前注射康柏西普均可安全有效治疗早期PDR,显著提高患者术后视力,而手术结束时注射康柏西普能够减少晚期玻璃体积血复发的概率,使得PPV治疗取得更好的效果,有助于改善患者的视网膜和视功能,提高患者生活质量。 展开更多
关键词 微创玻璃体切割术 康柏西普 增殖性糖尿病视网膜病变 玻璃体积血
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Preparation and luminescence properties of orange-red Ba3Y4O9:Sm3+phosphors 被引量:8
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作者 Jiayu Li Ran Pang +7 位作者 Zhan Yu Liyan Liu Haiyan Wu Huimin Li Lihong Jiang su zhang Jing Feng Chengyu Li 《Journal of Rare Earths》 SCIE EI CAS CSCD 2018年第7期680-684,共5页
A novel orange-red emitting Ba3 Y4 O9:Sm^(3+) phosphors were prepared by a high temperature solidstate reaction in air. X-ray diffraction(XRD), photoluminescence spectra, fluorescence decay and temperature-depen... A novel orange-red emitting Ba3 Y4 O9:Sm^(3+) phosphors were prepared by a high temperature solidstate reaction in air. X-ray diffraction(XRD), photoluminescence spectra, fluorescence decay and temperature-dependent emission spectra were utilized to characterize the structure and luminescence properties. The results show that the excitation spectrum includes a series of linear peaks at350, 367, 382, 410, 424, 445, 470 and 495 nm, respectively. Under 410 nm excitation, the emission peaks were located at 574 nm(~4 G(5/2)-~6 H(5/2)), 608 nm(~4 G(5/2)-~6 H(7/2)),659 nm(~4 G(5/2)-~6 H(9/2)) and722 nm(~4 G(5/2)-~6 H(11/2)), respectively. The concentration quenching occurs when x equals 0.08 for Ba3 Y(4-x)O9:xSm^(3+) phosphor and its mechanism is ascribed to the dipole-dipole interaction. The chromaticity coordinates of Ba3 Y(3.92)O9:0.08 Sm^(3+) phosphor are in the orange-red region. The temperature-dependent study shows that this phosphor has excellent luminescence thermal-stability.And the luminescence intensity of Ba3 Y(3.92)O9:0.08 Sm^(3+) phosphor at 473 K only declines by about25.75% of its initial intensity. The experimental data indicate that Ba3 Y4 O9:Sm^(3+) phosphor may be promising as an orange-red emitting phosphor for white light emitting diodes. 展开更多
关键词 Orange-red phosphors Rare earths Ba3Y4O9 PHOTOLUMINESCENCE
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