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1,2-双硫环戊烷封端的硅烷偶联剂改性白炭黑及其橡胶复合材料的制备与性能
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作者 邓硕 徐林竹 +3 位作者 赵青云 曾碧榕 何凯斌 戴李宗 《高分子材料科学与工程》 北大核心 2025年第1期30-42,共13页
为了提升硅烷偶联剂对白炭黑的改性效果,文中提出新型含双硫环戊烷硅烷偶联剂的设计与应用研究。首先通过酰胺化反应使硫辛酸和氨丙基三乙氧基硅烷反应,合成了一种以1, 2-二硫环戊烷封端的新型硅烷偶联剂5-(1, 2-二硫代烷基-3-基)-N-(3-... 为了提升硅烷偶联剂对白炭黑的改性效果,文中提出新型含双硫环戊烷硅烷偶联剂的设计与应用研究。首先通过酰胺化反应使硫辛酸和氨丙基三乙氧基硅烷反应,合成了一种以1, 2-二硫环戊烷封端的新型硅烷偶联剂5-(1, 2-二硫代烷基-3-基)-N-(3-(三乙氧硅烷基丙基)丙基)戊酰胺(LATES);进而通过水解缩合反应对白炭黑A200的表面进行改性。最后使用不同添加量的LATES-A200为填料制备了LATES-A200/NR橡胶复合材料并表征其性能。结果表明,LATES有效提升了白炭黑A200在橡胶中的分散性,添加量45 phr的10%LATES-A20045/NR橡胶复合材料的综合性能最好。与未改性的A200/NR相比,10%LATES-A20045/NR橡胶拉伸强度从19.51 MPa提高到25.74 MPa,60℃时的tan δ从0.111降低到0.071,表明橡胶的滚动阻力降低,结合胶的含量和交联密度增加。在应用相同处理方法及添加量情况下,LATES改性的二氧化硅对NR性能的影响效果优于Si69改性的二氧化硅,可为“绿色轮胎”橡胶复合材料的发展提供新的助剂选择。 展开更多
关键词 硅烷偶联剂 双硫环戊烷 改性白炭黑 橡胶复合材料 分散性
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Emission characteristics of biogenic volatile organic compounds in a subtropical pristine forest of southern China 被引量:1
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作者 Xi Chen Daocheng Gong +9 位作者 Youjing Lin Qiao Xu Yujin Wang Shiwei Liu Qinqin Li Fangyuan Ma Jiangyong Li shuo deng Hao Wang Boguang Wang 《Journal of Environmental Sciences》 2025年第2期665-682,共18页
Emission characteristics of biogenic volatile organic compounds(BVOCs)from dominant tree species in the subtropical pristine forests of China are extremely limited.Here we conducted in situ field measurements of BVOCs... Emission characteristics of biogenic volatile organic compounds(BVOCs)from dominant tree species in the subtropical pristine forests of China are extremely limited.Here we conducted in situ field measurements of BVOCs emissions from representative mature evergreen trees by using dynamic branch enclosures at four altitude gradients(600-1690ma.s.l.)in the Nanling Mountains of southern China.Composition characteristics as well as seasonal and altitudinal variations were analyzed.Standardized emission rates and canopyscale emission factors were then calculated.Results showed that BVOCs emission intensities in the wet season were generally higher than those in the dry season.Monoterpenes were the dominant BVOCs emitted from most broad-leaved trees,accounting for over 70%of the total.Schima superba,Yushania basihirsuta and Altingia chinensis had relatively high emission intensities and secondary pollutant formation potentials.The localized emission factors of isoprene were comparable to the defaults in the Model of Emissions of Gases and Aerosols fromNature(MEGAN),while emission factors of monoterpenes and sesquiterpenes were 2 to 58 times of those in the model.Our results can be used to update the current BVOCs emission inventory in MEGAN,thereby reducing the uncertainties of BVOCs emission estimations in forested regions of southern China. 展开更多
关键词 Biogenic volatile organic compounds(BVOCs) Dynamic enclosure system Nanling Mountains Emission factors Emission rates Chemical reactivity
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常规和串联变温吸附碳捕集工艺的设计与评估
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作者 邓硕 丘东亮 +1 位作者 张留淦 陈龙祥 《过程工程学报》 北大核心 2025年第10期1039-1048,共10页
近年来,新型吸附剂的饱和吸附量不断增加,但其在循环过程中的实际吸附量因工艺流程设计局限而显著低于饱和值。为构建精准的吸附床模型,深入探究吸附工艺中复杂的传热与传质机理,本研究选用13X分子筛对CO_(2)/N_(2)进行吸附实验。通过... 近年来,新型吸附剂的饱和吸附量不断增加,但其在循环过程中的实际吸附量因工艺流程设计局限而显著低于饱和值。为构建精准的吸附床模型,深入探究吸附工艺中复杂的传热与传质机理,本研究选用13X分子筛对CO_(2)/N_(2)进行吸附实验。通过静态吸附与动态穿透实验,确定了竞争吸附等温线及吸附过程的传质传热系数,并基于该数据完成了变温吸附(Temperature Swing Adsorption,TSA)系统模型的搭建。对吸附床负载情况分析表明,常规TSA工艺的吸附剂利用率(AUR)仅为58.13%,大量吸附剂未实现充分利用,存在明显优化空间。为此,本研究设计了多床串联式新型TSA吸附工艺,通过使不同吸附床在上游床和下游床之间切换,使吸附剂利用率提升至85.50%,产品纯度从常规TSA工艺的90.74%提升至94.21%,能耗从6.48 MJ/kg CO_(2)降至4.79 MJ/kg CO_(2)。然而,串联工艺在吸附阶段存在少量CO_(2)泄露问题,导致气体回收率降至87.92%。此外,常规TSA工艺虽可通过延长吸附时间达到与串联工艺相近的AUR,但此时气体回收率仅为71.80%,较串联工艺低16.12个百分点。 展开更多
关键词 串联吸附 变温吸附 分子筛 碳捕集 数值模拟
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Reconfigurable and polarization-dependent optical filtering for transflective full-color generation utilizing low-loss phase-change materials 被引量:1
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作者 shuo deng Mengxi Cui +7 位作者 Jingru Jiang Chuang Wang Zengguang Cheng Huajun Sun Ming Xu Hao Tong Qiang He Xiangshui Miao 《Journal of Semiconductors》 EI CAS CSCD 2024年第7期46-53,共8页
All-dielectric metasurface, which features low optical absorptance and high resolution, is becoming a promising candidate for full-color generation. However, the optical response of current metamaterials is fixed and ... All-dielectric metasurface, which features low optical absorptance and high resolution, is becoming a promising candidate for full-color generation. However, the optical response of current metamaterials is fixed and lacks active tuning. In this work, we demonstrate a reconfigurable and polarization-dependent active color generation technique by incorporating low-loss phase change materials(PCMs) and CaF_2 all-dielectric substrate. Based on the strong Mie resonance effect and low optical absorption structure, a transflective, full-color with high color purity and gamut value is achieved. The spectrum can be dynamically manipulated by changing either the polarization of incident light or the PCM state. High transmittance and reflectance can be simultaneously achieved by using low-loss PCMs and substrate. The novel active metasurfaces can bring new inspiration in the areas of optical encryption, anti-counterfeiting, and display technologies. 展开更多
关键词 structural color RECONFIGURABLE all-dielectric metasurfaces phase change material
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Minimum distances of three families of low-density parity-check codes based on finite geometries 被引量:1
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作者 Yanan FENG shuo deng +1 位作者 Lu WANG Changli MA 《Frontiers of Mathematics in China》 SCIE CSCD 2016年第2期279-289,共11页
Three families of low-density parity-check (LDPC) codes are constructed based on the totally isotropic subspaces of symplectic, unitary, and orthogonal spaces over finite fields, respectively. The minimum distances ... Three families of low-density parity-check (LDPC) codes are constructed based on the totally isotropic subspaces of symplectic, unitary, and orthogonal spaces over finite fields, respectively. The minimum distances of the three families of LDPC codes in some special cases are settled. 展开更多
关键词 low-density parity-check (LDPC) code minimum distance symplectic UNITARY ORTHOGONAL
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