As one of the most prevalent gastrointestinal malignancies in humans,gastric cancer(GC)is often detected at an advanced stage,resulting in a poor prognosis and ranking it the fifth leading cause of cancer-related deat...As one of the most prevalent gastrointestinal malignancies in humans,gastric cancer(GC)is often detected at an advanced stage,resulting in a poor prognosis and ranking it the fifth leading cause of cancer-related deaths.Due to their high genomic correlation with humans,mice are ideal in vivo models for investigating GC-related pathogenesis and therapeutic interventions.This review provides an overview of different GC models,including genetically engineered,transplantation-based models,and chemically or biologically induced models,and discusses the recent advancements for each type,highlighting their unique contributions to the field.In addition,it summarizes the strengths,limitations,and typical applications of these models and offers a critical assessment of their applicability in research while acknowledging their current limitations in fully mirroring human GC progression.Furthermore,we analyze how each model accurately recapitulates the complexities of human GC and evaluate their potential for clinical translation.This review provides a reference for model selection in future GC research.展开更多
Fuel tank inerting technologies are able to reduce the fire risk by injection of inert gas into the ullage or fuel, the former called ullage washing and the latter fuel scrubbing. The Green On-Board Inert Gas Generati...Fuel tank inerting technologies are able to reduce the fire risk by injection of inert gas into the ullage or fuel, the former called ullage washing and the latter fuel scrubbing. The Green On-Board Inert Gas Generation System（GOBIGGS） is a novel technology based on flameless catalytic combustion, and owning to its simple structure and high inerting efficiency, it has received a lot of attentions. The inert gas in the GOBIGGS is mainly comprised of CO2, N2, and O2（hereinafter, Mixed Inert Gas（MIG））, while that in the On-Board Inert Gas Generation System（OBIGGS）, which is one of the most widely used fuel tank inerting technologies, is NitrogenEnriched Air（NEA）. The solubility of CO2 is nearly 20 times higher than that of N2 in jet fuels,so the inerting capability and performance are definitely disparate if the inert gas is selected as NEA or MIG. An inerting test bench was constructed to compare the inerting capabilities between NEA and MIG. Experimental results reveal that, if ullage washing is adopted, the variations of oxygen concentrations on the ullage and in the fuel are nearly identical no matter the inert gas is NEA or MIG. However, the ullage and dissolved oxygen concentrations of MIG scrubbing are always higher than those of NEA scrubbing.展开更多
The experimental apparatus to measure the mass diffusion coefficients of O2 in aviation fuel was constructed based on the digital holographic interferometry method. The theory of mass diffusion coefficient and interfe...The experimental apparatus to measure the mass diffusion coefficients of O2 in aviation fuel was constructed based on the digital holographic interferometry method. The theory of mass diffusion coefficient and interference image processing were introduced in detail. The accuracy of the experiment was verified by measuring the mass diffusion coefficient of 0.33 mol/L KCl in aqueous solution at 298.15 K. The mass diffusion coefficients of O_2 in RP3 and RP5 aviation fuels were measured at temperature from 278.15 K to 333.15 K, and the Arrhenius equation was employed to fit the experimental data. In terms of the Stokes-Einstein equation, the viscosities of these two aviation fuels were tested to estimate the correlation among mass diffusion coefficient, viscosity and temperature. A uniform polynomial calculation correlation was proposed to predict the mass diffusion coefficients of O_2 in both RP3 and RP5 aviation fuels, and its accuracy is considerably higher than that of the Stokes-Einstein equation.展开更多
The properties of aviation fuel have a great influence on the performance of oxygenconsuming inerting systems. Based on the establishment of the catalytic inerting process, the flow relationship of each gas component ...The properties of aviation fuel have a great influence on the performance of oxygenconsuming inerting systems. Based on the establishment of the catalytic inerting process, the flow relationship of each gas component flowing through the catalytic reactor was derived. The mathematical model of the gas concentration in the gas phase of the fuel tank was established based on the mass conservation equation, and the fuel tank model was verified by performing experiments.The results showed that the fuel type exerts a considerably higher influence on the performance of the oxygen-consuming inerting system compared to the corresponding influence on the hollow fiber membrane system, and the relative magnitude of the inerting rates of the four fuel types is RP5 > RP3 > RP6 > JP8. In addition, a higher catalytic efficiency or fuel load rate corresponds to a higher rate of decrease of the oxygen concentration in the gas phase, and the inerting time is inversely proportional to the suction flow rate of the fan. When different fuels are used, the amount of cooling gas and water released from the inerting system are different. Therefore, the influence of fuel type on the system performance should be extensively considered in the future.展开更多
To determine the oxygen concentration variation in ullage that results from dissolved oxygen evolution in an inert aircraft fuel tank,the CFD method with a mass transfer source is applied in the present study.An exper...To determine the oxygen concentration variation in ullage that results from dissolved oxygen evolution in an inert aircraft fuel tank,the CFD method with a mass transfer source is applied in the present study.An experimental system is also designed to evaluate the accuracy of the CFD simulations.The dissolved oxygen evolution is simulated under different conditions of fuel load and initial oxygen concentration in ullage of an inert fuel tank with stimulations of heating and pressure decrease.The increase in the oxygen concentration in ullage ranges from 0.82%to 5.92%upon stimulation of heating and from 0.735%to 12.36%upon stimulation of a pressure decrease for an inert ullage in the simulations.The heating accelerates the release of the dissolved oxygen from the fuel by increasing the mass transfer rate in the mass transfer source and decreasing the pressure,thereby accelerating the dissolved oxygen evolution by increasing the concentration difference between the gas and the fuel.The time constant that represents the oxygen evolution rate is independent of the initial oxygen concentration in ullage of an inert tank but depends closely on the fuel load,temperature and pressure.The time constant can be fitted using a polynomial equation relating the fuel load to temperature in the heating stimulation with an accuracy of 4.77%.Upon stimulation of a pressure decrease,the time constant can be expressed in terms of the fuel load and the pressure,with an accuracy of 5.02%.展开更多
The establishment of highly sensitive diagnostic methods is critical in the early diagnosis and control of Zika virus(ZIKV)and in preventing serious neurological complications of ZIKV infection. In this study, we esta...The establishment of highly sensitive diagnostic methods is critical in the early diagnosis and control of Zika virus(ZIKV)and in preventing serious neurological complications of ZIKV infection. In this study, we established micro-droplet digital polymerase chain reaction(ddPCR) and real-time quantitative PCR(RT-qPCR) protocols for the detection of ZIKV based on the amplification of the NS5 gene. For the ZIKV standard plasmid, the RT-qPCR results showed that the cycle threshold(Ct) value was linear from 10~1 to 10~8 copy/l L, with a standard curve R^2 of 0.999 and amplification efficiency of 92.203%;however, a concentration as low as 1 copy/l L could not be detected. In comparison with RT-qPCR, the dd PCR method resulted in a linear range of 10~1–10~4 copy/l L and was able to detect concentrations as low as 1 copy/l L. Thus, for detecting ZIKV from clinical samples, RT-qPCR is a better choice for high-concentration samples(above 10~1 copy/l L),while ddPCR has excellent accuracy and sensitivity for low-concentration samples. These results indicate that the ddPCR method should be of considerable use in the early diagnosis, laboratory study, and monitoring of ZIKV.展开更多
The Mixed Inert Gas(MIG)produced by the novel Green On Board Inerting Gas Generation System(GOBIGGS)mainly consists of carbon dioxide,nitrogen and oxygen.Because of the large solubility of carbon dioxide in jet fuel c...The Mixed Inert Gas(MIG)produced by the novel Green On Board Inerting Gas Generation System(GOBIGGS)mainly consists of carbon dioxide,nitrogen and oxygen.Because of the large solubility of carbon dioxide in jet fuel compared with nitrogen,the no gas release or equilibrium model could not be employed any more.In this paper,first,a mathematical model of the ullage washing was set up to predict the variation of the oxygen concentration on ullage and in the fuel,and the gas evolution and dissolution rate were calculated by Fick's second law.Then,an experimental apparatus was constructed to verify the accuracy of the model.Finally,the numerical comparisons of ullage washing using Nitrogen Enriched Air(NEA)and MIG are presented under various flow rates and fuel loads,and the result reveals that the variation of the oxygen concentration on ullage is nearly identical whatever the inert gas is NEA or MIG.However,the variation of the oxygen concentration in the fuel is disparate,and the oxygen concentration decreases rapidly if the inert gas is MIG,especially when the fuel load is low or the flow rate of the inert gas is high.Besides,MIG could suppress the rising trend of the oxygen concentration on ullage when the aircraft ascends if the fuel tank is fully washed into an equilibrium state on ground.展开更多
Traditional fluorescent probes typically display blueshifted emission in rigidifying media;however,a newly developed class of rigidochromic fluorophores derived from phenanthridine demonstrates remarkable redshifted e...Traditional fluorescent probes typically display blueshifted emission in rigidifying media;however,a newly developed class of rigidochromic fluorophores derived from phenanthridine demonstrates remarkable redshifted emission under similar conditions.Pyridine,with similar N-heterostructure to those of phenanthridine group,is considered a promising candidate for achieving comparable rigidity-induced redshift behavior.In this work,we synthesized eight organic fluorophores featuring diverse functional units and substitutes by systematically combining pyridine with carbazole,triazatruxene(TAT),and tetraphenylethylene(TPE),respectively.These molecules exhibit significant emission redshifts(up to 225 nm,a record high value ever reported)or notable emission intensity changes as the rigidity of the polymer matrix increases,along with unique acid responsiveness.The differences in polar-πinteractions between fluorophores and polymers diversify the emission behavior,advancing the development of secure printing and intelligent optical materials.By embedding these fluorophores into polymer films with helical phase structures,redshifted emission with tunable chirality was achieved.Notably,leveraging the acid-responsive properties of these fluorophores,a time-dependent light-controlled dynamic encryption system was constructed,successfully enabling multi-level information encryption.This research greatly expands the scope of rigidochromic fluorophores,and their applications in anti-counterfeiting and information storage.展开更多
Comprehensive Summary,Organic luminogens with persistent room temperature phosphorescence(RTP)have drawn tremendous attentions due to their promising potentials in optoelectronic devices,information storage,biological...Comprehensive Summary,Organic luminogens with persistent room temperature phosphorescence(RTP)have drawn tremendous attentions due to their promising potentials in optoelectronic devices,information storage,biological imaging,and anti-counterfeiting.In this work,six triazatruxene-based lumiogens with different peripheral substituents and configurations are synthesized and systematically studied.The results show that their fluorescence quantum yields in solid states range from 15.73%to 37.58%.Dispersing the luminogens as vip into the host(PPh_(3))could turn on the persistent RTP,where PPh_(3)acts as not only a rigid matrix to suppress the non-radiative transitions of the vip,but also provides energy transfer channels to the vip.The maximum phosphorescence efficiency and the longest lifetime could reach 29.35%and 0.99 s in co-crystal films of 6-TAT-CN/PPh_(3)and 5-TAT-H/PPh_(3),respectively.Moreover,these host-vip co-crystalline films exhibit great potentials in advanced dynamic data encryption and anti-counterfeiting.This work deepens the insight for low cost,halogen-free,and facile fabrication of all-organic persistent RTP materials.展开更多
Two new fused ring electron acceptors(FREAs)IDT-IC-T and IDT-IC-B with thienyl or phenyl substituents at the terminal INCN unit are synthesized.Theoretical calculations indicate that the two acceptors dominantly favor...Two new fused ring electron acceptors(FREAs)IDT-IC-T and IDT-IC-B with thienyl or phenyl substituents at the terminal INCN unit are synthesized.Theoretical calculations indicate that the two acceptors dominantly favor an intermolecularπ-πstacking between the flanking terminal groups.The twist angle between the aryl substituent and INCN unit has a significant influence on theπ-πstacking distance of terminal unit.IDT-IC-T with a smaller twist angle has a shorterπ-πstacking distance than that of IDT-IC-B with a larger twist angle.In addition,extending the conjugation also affects the blend film morphology.IDT-IC-T and IDT-IC-B based photoactive films show appropriate nanoscale phase separations;whereas,blend films based on the parent compound IDT-IC show large-size acceptor domains.As expected,PBDB-T:IDT-IC-T blend films show higher and more balanced electron and hole mobilities.Moreover,these two acceptors present a good charge-transport connectivity arising from the extended conjugation and the increased intermolecular overlapping.Ultimately,IDT-IC-T demonstrates the highest electron mobility(1.47×10^(-4)cm^2V^(-1)s^(-1))and the best power conversion efficiency(PCE)of 9.43%.As for IDT-IC,which only shows an electron mobility of 7.33×10^(-5)cm^2V^(-1)s^(-1)and a PCE of 5.82%.These findings provide a facile and effective way to improve the photovoltaic performance.展开更多
基金the Wenzhou Municipal Science and Technology Bureau Program,Grant/Award Number:Y2023075the Key R&D Program of Zhejiang Province,Grant/Award Number:2020C03029+2 种基金the Natural Science Foundation of Zhejiang,Grant/Award Number:LQ22H160010the General Scientific Research Projects of the Zhejiang Provincial Education Department,Grant/Award Number:Y202147055Wenzhou Major Scientific and Technological Innovation Project,Grant/Award Number:ZY2022015。
文摘As one of the most prevalent gastrointestinal malignancies in humans,gastric cancer(GC)is often detected at an advanced stage,resulting in a poor prognosis and ranking it the fifth leading cause of cancer-related deaths.Due to their high genomic correlation with humans,mice are ideal in vivo models for investigating GC-related pathogenesis and therapeutic interventions.This review provides an overview of different GC models,including genetically engineered,transplantation-based models,and chemically or biologically induced models,and discusses the recent advancements for each type,highlighting their unique contributions to the field.In addition,it summarizes the strengths,limitations,and typical applications of these models and offers a critical assessment of their applicability in research while acknowledging their current limitations in fully mirroring human GC progression.Furthermore,we analyze how each model accurately recapitulates the complexities of human GC and evaluate their potential for clinical translation.This review provides a reference for model selection in future GC research.
基金supported by Funding of Jiangsu Innovation Program for Graduate Education of China (No.KYLX15_0231)Postgraduate Research & Practice Innovation Program of Jiangsu Province of China (No.KYCX17_0279)+1 种基金the Fundamental Research Funds for the Central Universities,Aviation Industry Corporation of China Technology Innovation Fund for Fundamental Research (No.2014D60931R)Funding of Ministry of Industry and Information Technology for Civil Aircraft
文摘Fuel tank inerting technologies are able to reduce the fire risk by injection of inert gas into the ullage or fuel, the former called ullage washing and the latter fuel scrubbing. The Green On-Board Inert Gas Generation System（GOBIGGS） is a novel technology based on flameless catalytic combustion, and owning to its simple structure and high inerting efficiency, it has received a lot of attentions. The inert gas in the GOBIGGS is mainly comprised of CO2, N2, and O2（hereinafter, Mixed Inert Gas（MIG））, while that in the On-Board Inert Gas Generation System（OBIGGS）, which is one of the most widely used fuel tank inerting technologies, is NitrogenEnriched Air（NEA）. The solubility of CO2 is nearly 20 times higher than that of N2 in jet fuels,so the inerting capability and performance are definitely disparate if the inert gas is selected as NEA or MIG. An inerting test bench was constructed to compare the inerting capabilities between NEA and MIG. Experimental results reveal that, if ullage washing is adopted, the variations of oxygen concentrations on the ullage and in the fuel are nearly identical no matter the inert gas is NEA or MIG. However, the ullage and dissolved oxygen concentrations of MIG scrubbing are always higher than those of NEA scrubbing.
基金supported by the Aeronautical Science Foundation of China(No.20132852040)the Fundation of Graduate Innovation Center in NUAA(No.kfjj20170116)+1 种基金the Fundamental Research Funds for the Central Universitiesthe Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘The experimental apparatus to measure the mass diffusion coefficients of O2 in aviation fuel was constructed based on the digital holographic interferometry method. The theory of mass diffusion coefficient and interference image processing were introduced in detail. The accuracy of the experiment was verified by measuring the mass diffusion coefficient of 0.33 mol/L KCl in aqueous solution at 298.15 K. The mass diffusion coefficients of O_2 in RP3 and RP5 aviation fuels were measured at temperature from 278.15 K to 333.15 K, and the Arrhenius equation was employed to fit the experimental data. In terms of the Stokes-Einstein equation, the viscosities of these two aviation fuels were tested to estimate the correlation among mass diffusion coefficient, viscosity and temperature. A uniform polynomial calculation correlation was proposed to predict the mass diffusion coefficients of O_2 in both RP3 and RP5 aviation fuels, and its accuracy is considerably higher than that of the Stokes-Einstein equation.
基金supported by National Natural Science Foundation of China Civil Aviation Joint Fund (No.U1933121)Postgraduate Research & Practice Innovation Program of Jiangsu Province (No.KYCX19_0198)The Fundamental Research Funds for the Central Universities and Priority Academic Program Development of Jiangsu Higher Education Institutions。
文摘The properties of aviation fuel have a great influence on the performance of oxygenconsuming inerting systems. Based on the establishment of the catalytic inerting process, the flow relationship of each gas component flowing through the catalytic reactor was derived. The mathematical model of the gas concentration in the gas phase of the fuel tank was established based on the mass conservation equation, and the fuel tank model was verified by performing experiments.The results showed that the fuel type exerts a considerably higher influence on the performance of the oxygen-consuming inerting system compared to the corresponding influence on the hollow fiber membrane system, and the relative magnitude of the inerting rates of the four fuel types is RP5 > RP3 > RP6 > JP8. In addition, a higher catalytic efficiency or fuel load rate corresponds to a higher rate of decrease of the oxygen concentration in the gas phase, and the inerting time is inversely proportional to the suction flow rate of the fan. When different fuels are used, the amount of cooling gas and water released from the inerting system are different. Therefore, the influence of fuel type on the system performance should be extensively considered in the future.
基金financially supported by NSFC-Civil Aviation Joint Research Fund,China(No.U1933121)Scientific Research Program Funded by Shaanxi Provincial Education Department,China(No.19JK0374)+2 种基金the Postgraduate Research&Practice Innovation Program of Jiangsu Province,China(No.KYCX19_0198)the Fundamental Research Funds for the Central UniversitiesPriority Academic Program Development of Jiangsu Higher Education Institutions。
文摘To determine the oxygen concentration variation in ullage that results from dissolved oxygen evolution in an inert aircraft fuel tank,the CFD method with a mass transfer source is applied in the present study.An experimental system is also designed to evaluate the accuracy of the CFD simulations.The dissolved oxygen evolution is simulated under different conditions of fuel load and initial oxygen concentration in ullage of an inert fuel tank with stimulations of heating and pressure decrease.The increase in the oxygen concentration in ullage ranges from 0.82%to 5.92%upon stimulation of heating and from 0.735%to 12.36%upon stimulation of a pressure decrease for an inert ullage in the simulations.The heating accelerates the release of the dissolved oxygen from the fuel by increasing the mass transfer rate in the mass transfer source and decreasing the pressure,thereby accelerating the dissolved oxygen evolution by increasing the concentration difference between the gas and the fuel.The time constant that represents the oxygen evolution rate is independent of the initial oxygen concentration in ullage of an inert tank but depends closely on the fuel load,temperature and pressure.The time constant can be fitted using a polynomial equation relating the fuel load to temperature in the heating stimulation with an accuracy of 4.77%.Upon stimulation of a pressure decrease,the time constant can be expressed in terms of the fuel load and the pressure,with an accuracy of 5.02%.
基金supported by the National Natural Science Foundation of China (Nos. 31470271 and 81730110)Guangzhou Science and Technology Program key projects (No. 201803040006)
文摘The establishment of highly sensitive diagnostic methods is critical in the early diagnosis and control of Zika virus(ZIKV)and in preventing serious neurological complications of ZIKV infection. In this study, we established micro-droplet digital polymerase chain reaction(ddPCR) and real-time quantitative PCR(RT-qPCR) protocols for the detection of ZIKV based on the amplification of the NS5 gene. For the ZIKV standard plasmid, the RT-qPCR results showed that the cycle threshold(Ct) value was linear from 10~1 to 10~8 copy/l L, with a standard curve R^2 of 0.999 and amplification efficiency of 92.203%;however, a concentration as low as 1 copy/l L could not be detected. In comparison with RT-qPCR, the dd PCR method resulted in a linear range of 10~1–10~4 copy/l L and was able to detect concentrations as low as 1 copy/l L. Thus, for detecting ZIKV from clinical samples, RT-qPCR is a better choice for high-concentration samples(above 10~1 copy/l L),while ddPCR has excellent accuracy and sensitivity for low-concentration samples. These results indicate that the ddPCR method should be of considerable use in the early diagnosis, laboratory study, and monitoring of ZIKV.
基金supported by National Natural Science Foundation of China Civil Aviation Joint Fund(No.U1933121)Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX19_0198)+1 种基金the Fundamental Research Funds for the Central UniversitiesPriority Academic Program Development of Jiangsu Higher Education Institutions。
文摘The Mixed Inert Gas(MIG)produced by the novel Green On Board Inerting Gas Generation System(GOBIGGS)mainly consists of carbon dioxide,nitrogen and oxygen.Because of the large solubility of carbon dioxide in jet fuel compared with nitrogen,the no gas release or equilibrium model could not be employed any more.In this paper,first,a mathematical model of the ullage washing was set up to predict the variation of the oxygen concentration on ullage and in the fuel,and the gas evolution and dissolution rate were calculated by Fick's second law.Then,an experimental apparatus was constructed to verify the accuracy of the model.Finally,the numerical comparisons of ullage washing using Nitrogen Enriched Air(NEA)and MIG are presented under various flow rates and fuel loads,and the result reveals that the variation of the oxygen concentration on ullage is nearly identical whatever the inert gas is NEA or MIG.However,the variation of the oxygen concentration in the fuel is disparate,and the oxygen concentration decreases rapidly if the inert gas is MIG,especially when the fuel load is low or the flow rate of the inert gas is high.Besides,MIG could suppress the rising trend of the oxygen concentration on ullage when the aircraft ascends if the fuel tank is fully washed into an equilibrium state on ground.
基金supported by National Natural Science Foundation of China(22275193,22275189,and 52473201)the Natural Science Foundation of Fujian Province(2024J09055)+3 种基金Fujian Provincial Department of Science and Technology(202310030)Self-deployment Project Research Program of Haixi Institutes,Chinese Academy of Science,CXZX-2022-GH09(E255KF0101)Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China(2021ZR115)Foundation for the Excellent Postdoctoral of Fujian Province,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences(E055AJ01,E355AJ01).
文摘Traditional fluorescent probes typically display blueshifted emission in rigidifying media;however,a newly developed class of rigidochromic fluorophores derived from phenanthridine demonstrates remarkable redshifted emission under similar conditions.Pyridine,with similar N-heterostructure to those of phenanthridine group,is considered a promising candidate for achieving comparable rigidity-induced redshift behavior.In this work,we synthesized eight organic fluorophores featuring diverse functional units and substitutes by systematically combining pyridine with carbazole,triazatruxene(TAT),and tetraphenylethylene(TPE),respectively.These molecules exhibit significant emission redshifts(up to 225 nm,a record high value ever reported)or notable emission intensity changes as the rigidity of the polymer matrix increases,along with unique acid responsiveness.The differences in polar-πinteractions between fluorophores and polymers diversify the emission behavior,advancing the development of secure printing and intelligent optical materials.By embedding these fluorophores into polymer films with helical phase structures,redshifted emission with tunable chirality was achieved.Notably,leveraging the acid-responsive properties of these fluorophores,a time-dependent light-controlled dynamic encryption system was constructed,successfully enabling multi-level information encryption.This research greatly expands the scope of rigidochromic fluorophores,and their applications in anti-counterfeiting and information storage.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.:22275189,22275193,and 22005307)the Natural Science Foundation of Fujian Province(E131AJ0101)+1 种基金Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China(2021ZR115)Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences(E055AJ01).
文摘Comprehensive Summary,Organic luminogens with persistent room temperature phosphorescence(RTP)have drawn tremendous attentions due to their promising potentials in optoelectronic devices,information storage,biological imaging,and anti-counterfeiting.In this work,six triazatruxene-based lumiogens with different peripheral substituents and configurations are synthesized and systematically studied.The results show that their fluorescence quantum yields in solid states range from 15.73%to 37.58%.Dispersing the luminogens as vip into the host(PPh_(3))could turn on the persistent RTP,where PPh_(3)acts as not only a rigid matrix to suppress the non-radiative transitions of the vip,but also provides energy transfer channels to the vip.The maximum phosphorescence efficiency and the longest lifetime could reach 29.35%and 0.99 s in co-crystal films of 6-TAT-CN/PPh_(3)and 5-TAT-H/PPh_(3),respectively.Moreover,these host-vip co-crystalline films exhibit great potentials in advanced dynamic data encryption and anti-counterfeiting.This work deepens the insight for low cost,halogen-free,and facile fabrication of all-organic persistent RTP materials.
基金supported by the National Natural Science Fundation of China (21574013, 51673028)the Fundamental Research Funds for the Central Universities
文摘Two new fused ring electron acceptors(FREAs)IDT-IC-T and IDT-IC-B with thienyl or phenyl substituents at the terminal INCN unit are synthesized.Theoretical calculations indicate that the two acceptors dominantly favor an intermolecularπ-πstacking between the flanking terminal groups.The twist angle between the aryl substituent and INCN unit has a significant influence on theπ-πstacking distance of terminal unit.IDT-IC-T with a smaller twist angle has a shorterπ-πstacking distance than that of IDT-IC-B with a larger twist angle.In addition,extending the conjugation also affects the blend film morphology.IDT-IC-T and IDT-IC-B based photoactive films show appropriate nanoscale phase separations;whereas,blend films based on the parent compound IDT-IC show large-size acceptor domains.As expected,PBDB-T:IDT-IC-T blend films show higher and more balanced electron and hole mobilities.Moreover,these two acceptors present a good charge-transport connectivity arising from the extended conjugation and the increased intermolecular overlapping.Ultimately,IDT-IC-T demonstrates the highest electron mobility(1.47×10^(-4)cm^2V^(-1)s^(-1))and the best power conversion efficiency(PCE)of 9.43%.As for IDT-IC,which only shows an electron mobility of 7.33×10^(-5)cm^2V^(-1)s^(-1)and a PCE of 5.82%.These findings provide a facile and effective way to improve the photovoltaic performance.
