A series of non-rare earth Mn^(4+)-activated strontium aluminate phosphors Sr_(4)Al_(14)O_(25):Mn^(4+)co-doped with Sc^(3+)ions were successfully synthesized by a high-temperature solid-state reaction method.XRD resul...A series of non-rare earth Mn^(4+)-activated strontium aluminate phosphors Sr_(4)Al_(14)O_(25):Mn^(4+)co-doped with Sc^(3+)ions were successfully synthesized by a high-temperature solid-state reaction method.XRD result reveals that there is no introduction of additional phase but expansion of lattice with incorporation of Sc34 ions.Excitation and emission spectrum measurement shows that the synthesized phosphors can be efficiently excited by near-ultraviolet and blue light,and a deep red emission centered at 652 nm with a narrow full width at half maximum(FWHM)can be obtained,which is attributed to the transition^(2)E→^(4)A_(2)of Mn^(4+)ions.In addition,the crystal field strength parameter(Dq)and Racah parameters(B,C)and energies of states were calculated based on experimental data.Moreover,the luminous intensity of Sr_(4)Al_(14-x)SCxO_(25):Mn^(4+)is enhanced and increased by 60%compared with Mn^(4+)single incorporated sample at x=0.06.A phenomenon of redshift is observed in the excitation spectrum and discussed systematically.Finally,the mechanism of the positive effects with Sc^(3+)ions incorporated into lattice is discussed in detail.All the results suggest that the Sr_(4)Al_(13.94)Sc_(0.06)O_(25):Mn^(4+)phosphor will become one of the great candidates for backlight of LCD.展开更多
基金Project supported by the National Key Research and Development Program of China(2017YFB0404301)the Team of Excellent Talent Development Project of Xicheng District,Beijing.
文摘A series of non-rare earth Mn^(4+)-activated strontium aluminate phosphors Sr_(4)Al_(14)O_(25):Mn^(4+)co-doped with Sc^(3+)ions were successfully synthesized by a high-temperature solid-state reaction method.XRD result reveals that there is no introduction of additional phase but expansion of lattice with incorporation of Sc34 ions.Excitation and emission spectrum measurement shows that the synthesized phosphors can be efficiently excited by near-ultraviolet and blue light,and a deep red emission centered at 652 nm with a narrow full width at half maximum(FWHM)can be obtained,which is attributed to the transition^(2)E→^(4)A_(2)of Mn^(4+)ions.In addition,the crystal field strength parameter(Dq)and Racah parameters(B,C)and energies of states were calculated based on experimental data.Moreover,the luminous intensity of Sr_(4)Al_(14-x)SCxO_(25):Mn^(4+)is enhanced and increased by 60%compared with Mn^(4+)single incorporated sample at x=0.06.A phenomenon of redshift is observed in the excitation spectrum and discussed systematically.Finally,the mechanism of the positive effects with Sc^(3+)ions incorporated into lattice is discussed in detail.All the results suggest that the Sr_(4)Al_(13.94)Sc_(0.06)O_(25):Mn^(4+)phosphor will become one of the great candidates for backlight of LCD.
