Au nanoparticles(AuNPs)were prepared by reducing HAuCl4 with NaBH4,and then adsorbed uniformly on the surface of carboxylated nanocrystalline cellulose(CNCC).The obtained AuNPs/CNCC particles were doped into a conduct...Au nanoparticles(AuNPs)were prepared by reducing HAuCl4 with NaBH4,and then adsorbed uniformly on the surface of carboxylated nanocrystalline cellulose(CNCC).The obtained AuNPs/CNCC particles were doped into a conductive polymer of poly(3,4-ethylenedioxythiophene)(PEDOT)to yield a highly conductive nanocomposite,which was deposited onto a glassy carbon electrode(GCE)by an electrochemical method.The PEDOT/AuNPs/CNCC nanocomposite showed low electrochemical impedance and good electrocatalytic activity toward ascorbic acid.Based on this novel nanocomposite material,an amperometric sensor was developed for the detection of ascorbic acid with a detection limit as low as 0.29μM.When operated at-0.15 V,the sensor detected ascorbic acid in the range of 0.88μM to 15000μM.展开更多
基金supported by the National Natural Science Foundation of China(21422504 and 21275087)the Natural Science Foundation of Shandong Province of China(JQ201406).
文摘Au nanoparticles(AuNPs)were prepared by reducing HAuCl4 with NaBH4,and then adsorbed uniformly on the surface of carboxylated nanocrystalline cellulose(CNCC).The obtained AuNPs/CNCC particles were doped into a conductive polymer of poly(3,4-ethylenedioxythiophene)(PEDOT)to yield a highly conductive nanocomposite,which was deposited onto a glassy carbon electrode(GCE)by an electrochemical method.The PEDOT/AuNPs/CNCC nanocomposite showed low electrochemical impedance and good electrocatalytic activity toward ascorbic acid.Based on this novel nanocomposite material,an amperometric sensor was developed for the detection of ascorbic acid with a detection limit as low as 0.29μM.When operated at-0.15 V,the sensor detected ascorbic acid in the range of 0.88μM to 15000μM.
