The electrochemical reduction reaction of carbon dioxide(CO_(2)-ERR)holds tremendous potential as a key approach for achieving carbon neutrality by harnessing renewable resources.However,the current state of CO_(2)-ER...The electrochemical reduction reaction of carbon dioxide(CO_(2)-ERR)holds tremendous potential as a key approach for achieving carbon neutrality by harnessing renewable resources.However,the current state of CO_(2)-ERR encounters challenges in terms of efficiency and selectivity.Overcoming these obstacles requires the development of a robust electrocatalyst capable of enhancing process efficiency and improving selectivity towards desired products.In recent years,2D materials have garnered significant attention as efficient catalysts.Among them,MXene stands out of high interest due to unique multilayered structure and presence of surface functional moieties.The MXene material offers high electrical conductivity,versatile surface chemistry,and tunable interface designs.This comprehensive review explores the utilization of MXene-based catalysts for CO_(2)-ERR into valuable products.It covers fundamental aspects of electrochemical conversion,including CO_(2)adsorption on MXene Ti_(3)C_(2)T_(x),the mechanism of CO_(2)-ERR on MXene(Mo_(2)CS_(2))single-atom catalysts,applications,synthesis methods of MXene production,and future prospects.Additionally,the review highlights the significance of modern artificial intelligence techniques,particularly machine learning,in screening and activating CO_(2),making it a pioneering scientific endeavor.展开更多
基金supported by the National Natural Science Foundation of China(Nos.62375200 and 61975148).
文摘The electrochemical reduction reaction of carbon dioxide(CO_(2)-ERR)holds tremendous potential as a key approach for achieving carbon neutrality by harnessing renewable resources.However,the current state of CO_(2)-ERR encounters challenges in terms of efficiency and selectivity.Overcoming these obstacles requires the development of a robust electrocatalyst capable of enhancing process efficiency and improving selectivity towards desired products.In recent years,2D materials have garnered significant attention as efficient catalysts.Among them,MXene stands out of high interest due to unique multilayered structure and presence of surface functional moieties.The MXene material offers high electrical conductivity,versatile surface chemistry,and tunable interface designs.This comprehensive review explores the utilization of MXene-based catalysts for CO_(2)-ERR into valuable products.It covers fundamental aspects of electrochemical conversion,including CO_(2)adsorption on MXene Ti_(3)C_(2)T_(x),the mechanism of CO_(2)-ERR on MXene(Mo_(2)CS_(2))single-atom catalysts,applications,synthesis methods of MXene production,and future prospects.Additionally,the review highlights the significance of modern artificial intelligence techniques,particularly machine learning,in screening and activating CO_(2),making it a pioneering scientific endeavor.
