Furfurylation,a renowned chemical modification technique,uses furfuryl alcohol to enhance the properties of wood.This technology can be further refined by incorporating renewable tannins,which promote cross-linking wi...Furfurylation,a renowned chemical modification technique,uses furfuryl alcohol to enhance the properties of wood.This technology can be further refined by incorporating renewable tannins,which promote cross-linking with furfuryl alcohol.This study investigates the effects of furfurylation and tannin-modified furfurylation on the physical and mechanical properties of tropical Gmelina wood(Gmelina arborea Roxb.).Experiments involved impregnating Gmelina wood with aqueous solutions of furfuryl alcohol(FA)at 40%and 70%concentrations,as well as FA-tannin combinations(FA 40%-TA and FA 70%-TA),followed by polymerization at 103℃.The results demonstrated that both FA and FA-tannin treatments significantly improved the wood’s physical and mechanical properties.Notably,FA-tannin treatments achieved anti-swelling efficiency comparable to FA alone.However,the addition of tannins(FA 70%-TA)enhanced leaching resistance by up to 47%,contributing to a more environmentally sustainable modification process.Mechanically,the inclusion of tannins in FA 70%-TA slightly increased the modulus of elasticity(14%~8732 kg/cm^(2))and the modulus of rupture(9%~40.9 kg/cm^(2)).Furthermore,the tannin addition imparted a darker color to the modified wood,enhancing its aesthetic appeal.This study highlights the potential of tannin-modified furfurylation to advance wood modification technology,combining improved performance with environmental benefits.展开更多
基金funded by the Directorate General of Higher Education,Research,and Technology,Ministry of Education,Culture,Research,and Technology,Indonesia,which sponsored the research grant via the National Competitive Basic Research Scheme,No.027/E5/PG.02.00.PL/2024facilitated by IPB University(Bogor Agricultural University)through Research Contract No.22055/IT3.D10/PT.01.03/P/B/2024+1 种基金funded by Research Organization for Nanotechnology and Materials No.3/III.10/HK/2023National Research and Innovation Agency(BRIN),Indonesia.
文摘Furfurylation,a renowned chemical modification technique,uses furfuryl alcohol to enhance the properties of wood.This technology can be further refined by incorporating renewable tannins,which promote cross-linking with furfuryl alcohol.This study investigates the effects of furfurylation and tannin-modified furfurylation on the physical and mechanical properties of tropical Gmelina wood(Gmelina arborea Roxb.).Experiments involved impregnating Gmelina wood with aqueous solutions of furfuryl alcohol(FA)at 40%and 70%concentrations,as well as FA-tannin combinations(FA 40%-TA and FA 70%-TA),followed by polymerization at 103℃.The results demonstrated that both FA and FA-tannin treatments significantly improved the wood’s physical and mechanical properties.Notably,FA-tannin treatments achieved anti-swelling efficiency comparable to FA alone.However,the addition of tannins(FA 70%-TA)enhanced leaching resistance by up to 47%,contributing to a more environmentally sustainable modification process.Mechanically,the inclusion of tannins in FA 70%-TA slightly increased the modulus of elasticity(14%~8732 kg/cm^(2))and the modulus of rupture(9%~40.9 kg/cm^(2)).Furthermore,the tannin addition imparted a darker color to the modified wood,enhancing its aesthetic appeal.This study highlights the potential of tannin-modified furfurylation to advance wood modification technology,combining improved performance with environmental benefits.
