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Nature of Soil Acidity in Relation to Properties and Lime Requirement of Some Inceptisols 被引量:4
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作者 A.K.DOLUI s.bhattacharjee 《Pedosphere》 SCIE CAS CSCD 2003年第2期181-188,共8页
Some Inceptisols representing the Singla catchment area in Karimgaungedistrict of Assam, India, were studied for lime requirement as influenced by the nature of soilacidity. The electrostatically bonded (EB)-H^+ and E... Some Inceptisols representing the Singla catchment area in Karimgaungedistrict of Assam, India, were studied for lime requirement as influenced by the nature of soilacidity. The electrostatically bonded (EB)-H^+ and EB-Al^(3+) acidities constituted 33 and 67percent of exchangeable acidity while EB-H^+, EB-Al^(3+), exchangeable and pH-dependent aciditiescomprised 6, 14, 20 and 80 percent of total potential acidity. The pH-dependent acidity made a majorcontribution towards the total potential acidity (67%~84%). Grand mean of lime requirementdetermined by the laboratory incubation method and estimated by the methods of New Woodruff,Woodruff and Peech as expressed in MgCaCO_3 ha^(-1) was in the order: Woodruff (15.6) > New Woodruff(14.9) > Peech (5.1) > incubation (5.0). Correlations analysis among different forms of acidity andlime requirement methods with selected soil properties showed that pH in three media, namely water,1 mol L^(-1) KC1 and 0.01 mol L^(-1) CaCl_2, had a significant negative correlation with differentforms of acidity and lime requirement methods. Exchangeable Fe and Al showed significant positivecorrelations with EB-Al^(3+) acidity, exchangeable acidity, pH-dependent acidity and total potentialacidity, and also lime requirement methods. Extractable Al showed positive correlations withdifferent forms of acidity except EB-H^+ and EB-Al^(3+) acidities. The lime requirement by differentmethods depended upon the extractable aluminium. Significant positive correlations existed betweenlime requirements and different forms of acidity of the soils except EB-H^+ acidity and incubationmethod. The nature of soil acidity was mostly pH-dependent. Statistically, the Woodruff method didslightly better than the New Woodruff, incubation and Peech methods at estimating lime requirementand hence the Woodruff procedure may be recommended for routine soil testing because of its speedand simplicity. 展开更多
关键词 INCEPTISOLS lime requirement nature of acidity soil properties
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水介质中多金属海水矿瘤砷吸附的研究
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作者 S.Maity S.Chakravarty +2 位作者 s.bhattacharjee B.C. Roy 赵玉军(翻译) 《水文地质工程地质技术方法动态》 2006年第4期28-37,共10页
本文详细报告了水介质中多金属海水矿瘤吸附砷(Ⅲ)和砷(Ⅴ)的研究结果。海水矿瘤的元素成分主要由铁、锰、硅(含有微量铝)、铜、钴和镍。海水矿瘤对砷(Ⅴ)的吸附取决于水介质的pH值,而砷(Ⅲ)的吸附不受水介质pH值的影响。砷... 本文详细报告了水介质中多金属海水矿瘤吸附砷(Ⅲ)和砷(Ⅴ)的研究结果。海水矿瘤的元素成分主要由铁、锰、硅(含有微量铝)、铜、钴和镍。海水矿瘤对砷(Ⅴ)的吸附取决于水介质的pH值,而砷(Ⅲ)的吸附不受水介质pH值的影响。砷吸附数据大体上符合兰米尔(Langmuir)等温线。砷(Ⅲ)和砷(Ⅴ)的动力学数据满足一种假定的二级动力学模型。海水矿瘤去除砷的效果取决于砷的初始浓度。当水介质中砷(Ⅲ)的初始浓度为0.34mg/L或砷(Ⅴ)的初始浓度为0.78mg/L时,海水矿瘤的最佳剂量为0.74mg/g。砷(Ⅲ)的吸附一般取决于离子环境。除PO4^3-以外,砷(Ⅲ)的吸附不受阴离子的影响,但受阳离子的影响显著。另一方面,砷(Ⅴ)的吸附受阴离子的影响显著,但不受阳离子的影响。试验结果表明,海水矿瘤吸附的砷(Ⅲ)主要为内部结核复合物,而吸附的砷(Ⅴ)为部分内部结核和部分外部结核复合物。当水介质的pH值为2-10时,吸附的砷(Ⅲ)和砷(Ⅴ)的解吸附较小。当水介质的pH值为6或更高时,海水矿瘤能被用于吸附地下水中的砷(Ⅲ)和砷(Ⅴ)物种。海水矿瘤被成功地用于去除采于印度西孟加拉邦的6种受砷污染地下水样中的砷(6种地下水样中砷的浓度范围为0.04-0.18mg/L)。 展开更多
关键词 吸附 砷(Ⅲ) 砷(Ⅴ) 海水矿瘤 水介质
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