Aqueous zinc-based energy storage devices(ZESDs)have garnered considerable interest because of their high specific capacity,abundant zinc reserves,excellent safety,and environmental friendliness.In recent years,variou...Aqueous zinc-based energy storage devices(ZESDs)have garnered considerable interest because of their high specific capacity,abundant zinc reserves,excellent safety,and environmental friendliness.In recent years,various types of boron,nitrogen co-doped carbon(BNC)materials have been developed to improve electrochemical performance of ZESDs.To promote the advancement of these technologies,we herein give a comprehensive review of the progress in BNC materials for ZESDs.The different synthetic methods employed in the preparation of BNC materials,including direct carbonization,template method,chemical vapor deposition,hydrothermal method,etc.,are summarized.These methods play a vital role in tailoring the structure,composition,and properties of BNC materials to optimize their performance in energy storage applications.Furthermore,some key achievements of BNC materials in zinc-air batteries and zinc-ion hybrid supercapacitors are elaborated.Lastly,future challenges and development directions of BNC materials in ZESDs are prospected.This comprehensive review could serve as a valuable resource in the energy storage field,providing insights into the potential of BNC materials in zinc-based energy storage technologies.展开更多
Aqueous Zn-I_(2)-Mn hybrid batteries demonstrate enhanced capacity,superior redox reaction kinetics,and prolonged cycle life compared to their Zn-I_(2)and Zn-Mn counterparts,making them promising candidates for grid-s...Aqueous Zn-I_(2)-Mn hybrid batteries demonstrate enhanced capacity,superior redox reaction kinetics,and prolonged cycle life compared to their Zn-I_(2)and Zn-Mn counterparts,making them promising candidates for grid-scale energy storage.Nevertheless,challenges remain in developing multifunctional positive electrode materials and elucidating the mechanistic synergy governing iodine and manganese redox reactions.Herein,we present a high-performance free-standing electrode composed of birnessite(KMnO)nanosheet arrays in situ grown on carbon cloth(CC@KMnO)for constructing a Zn-I_(2)-Mn hybrid battery.Combined theoretical studies and in situ characterizations reveal that CC@KMnO enhances iodine species adsorption,lowers the Gibbs free energy change for iodine reduction,and significantly accelerates I^(-)/I_(3)^(-)/I_(5)^(-)redox kinetics while suppressing polyiodide shuttling and corrosion effects.Synchronously,the Zn I_(2)electrolyte facilitates the dissolution of residual and exfoliated KMnO,thereby improving manganese redox reaction kinetics,reversibility,and enhancing cycling stability.Leveraging this mutually reinforcing effect,the Zn-I_(2)-Mn hybrid battery achieves an impressive areal capacity of2.02 m Ah cm^(-2)and maintains long-term durability over 3600 cycles at 2 mA cm^(-2).This work provides valuable insights into designing efficient and durable hybrid energy storage systems.展开更多
For the needs of bladder urinary volume noninvasive monitoring in clinical, we present a noninvasive bladder urinary volume monitoring system based on bio-impedance. The system uses a four-electrode structure,which is...For the needs of bladder urinary volume noninvasive monitoring in clinical, we present a noninvasive bladder urinary volume monitoring system based on bio-impedance. The system uses a four-electrode structure,which is composed of a pair of excitation electrodes and a pair of measurement electrodes. The Direct Digital Frequency Synthesis (DDS) is applied to generate a 50 kHz sine current excitation source. The impedance information extracted from phase sensibility demodulation technology is transferred to a computer through Zigbee wireless technology for real-time monitoring. Two experiments are taken to verify the accuracy and feasibility of the system. The experiments results show that the system can accurately measure the corresponding electrical impedance change of the bladder. The system provides a new way to continuously and noninvasively monitor the bladder urinary volume of patients with bladder dysfunction.展开更多
基金financially supported by the National Natural Science Foundation of China(No.22302177)the Public Technology Application Project of Jinhua City(No.2022–4-067)the Self Designed Scientific Research of Zhejiang Normal University(No.2021ZS0604)。
文摘Aqueous zinc-based energy storage devices(ZESDs)have garnered considerable interest because of their high specific capacity,abundant zinc reserves,excellent safety,and environmental friendliness.In recent years,various types of boron,nitrogen co-doped carbon(BNC)materials have been developed to improve electrochemical performance of ZESDs.To promote the advancement of these technologies,we herein give a comprehensive review of the progress in BNC materials for ZESDs.The different synthetic methods employed in the preparation of BNC materials,including direct carbonization,template method,chemical vapor deposition,hydrothermal method,etc.,are summarized.These methods play a vital role in tailoring the structure,composition,and properties of BNC materials to optimize their performance in energy storage applications.Furthermore,some key achievements of BNC materials in zinc-air batteries and zinc-ion hybrid supercapacitors are elaborated.Lastly,future challenges and development directions of BNC materials in ZESDs are prospected.This comprehensive review could serve as a valuable resource in the energy storage field,providing insights into the potential of BNC materials in zinc-based energy storage technologies.
基金financially supported by the National Natural Science Foundation of China(22302177)the Key Science and Technology Project of Jinhua City(2024-1-004)the Self Designed Scientific Research of Zhejiang Normal University(2021ZS0604)。
文摘Aqueous Zn-I_(2)-Mn hybrid batteries demonstrate enhanced capacity,superior redox reaction kinetics,and prolonged cycle life compared to their Zn-I_(2)and Zn-Mn counterparts,making them promising candidates for grid-scale energy storage.Nevertheless,challenges remain in developing multifunctional positive electrode materials and elucidating the mechanistic synergy governing iodine and manganese redox reactions.Herein,we present a high-performance free-standing electrode composed of birnessite(KMnO)nanosheet arrays in situ grown on carbon cloth(CC@KMnO)for constructing a Zn-I_(2)-Mn hybrid battery.Combined theoretical studies and in situ characterizations reveal that CC@KMnO enhances iodine species adsorption,lowers the Gibbs free energy change for iodine reduction,and significantly accelerates I^(-)/I_(3)^(-)/I_(5)^(-)redox kinetics while suppressing polyiodide shuttling and corrosion effects.Synchronously,the Zn I_(2)electrolyte facilitates the dissolution of residual and exfoliated KMnO,thereby improving manganese redox reaction kinetics,reversibility,and enhancing cycling stability.Leveraging this mutually reinforcing effect,the Zn-I_(2)-Mn hybrid battery achieves an impressive areal capacity of2.02 m Ah cm^(-2)and maintains long-term durability over 3600 cycles at 2 mA cm^(-2).This work provides valuable insights into designing efficient and durable hybrid energy storage systems.
文摘For the needs of bladder urinary volume noninvasive monitoring in clinical, we present a noninvasive bladder urinary volume monitoring system based on bio-impedance. The system uses a four-electrode structure,which is composed of a pair of excitation electrodes and a pair of measurement electrodes. The Direct Digital Frequency Synthesis (DDS) is applied to generate a 50 kHz sine current excitation source. The impedance information extracted from phase sensibility demodulation technology is transferred to a computer through Zigbee wireless technology for real-time monitoring. Two experiments are taken to verify the accuracy and feasibility of the system. The experiments results show that the system can accurately measure the corresponding electrical impedance change of the bladder. The system provides a new way to continuously and noninvasively monitor the bladder urinary volume of patients with bladder dysfunction.
