Surface enhanced Raman spectroscopy (SERS) has been applied to obtain structural information of surface species adsorbed at electrode surface in the electrode potential range of severe hydrogen evolution, which is ver...Surface enhanced Raman spectroscopy (SERS) has been applied to obtain structural information of surface species adsorbed at electrode surface in the electrode potential range of severe hydrogen evolution, which is very difficult to be gained by using most of spectroelectrochemical and conventional electrochemical methods.展开更多
The development of the instrumentation of a scanning electrochemical microscopy (SECM) is presented. The core of the SECM sensing system is constructed based on piezo-bimorph scanners, a mechanical micropositioner of ...The development of the instrumentation of a scanning electrochemical microscopy (SECM) is presented. The core of the SECM sensing system is constructed based on piezo-bimorph scanners, a mechanical micropositioner of multi-dimensional adjustment and ultramicroelectrodes. The control of the electrochemical cell and the SECM system is realized by a battery powered bipoteniostat and analog control circuits respectively with the control of a microcomputer work station. The demonstrations of SECM experiments are given on both a standard IDA sample and a silver electrode. Discussions on the resolution and quality of SECM image are made.展开更多
文摘Surface enhanced Raman spectroscopy (SERS) has been applied to obtain structural information of surface species adsorbed at electrode surface in the electrode potential range of severe hydrogen evolution, which is very difficult to be gained by using most of spectroelectrochemical and conventional electrochemical methods.
基金supported by the National Natural Science Foundation of China.
文摘The development of the instrumentation of a scanning electrochemical microscopy (SECM) is presented. The core of the SECM sensing system is constructed based on piezo-bimorph scanners, a mechanical micropositioner of multi-dimensional adjustment and ultramicroelectrodes. The control of the electrochemical cell and the SECM system is realized by a battery powered bipoteniostat and analog control circuits respectively with the control of a microcomputer work station. The demonstrations of SECM experiments are given on both a standard IDA sample and a silver electrode. Discussions on the resolution and quality of SECM image are made.
