A naturally occurring nitrogen heterocycle-based Schiff base sensor 8-methyl-2-oxo-1,2-dihydroquinoline-3-carboxaldehyde-4N-phenylsemicarbazone(8MPS)was synthesized;a highly sensitive and selective“on-off-on”chemose...A naturally occurring nitrogen heterocycle-based Schiff base sensor 8-methyl-2-oxo-1,2-dihydroquinoline-3-carboxaldehyde-4N-phenylsemicarbazone(8MPS)was synthesized;a highly sensitive and selective“on-off-on”chemosensor for aspartic acid in aqueous solution was established.展开更多
The reaction of[RuHCl(CO)(PPh_(3))_(3)]with an equimolar amount of salicylaldehyde-4(N)-methylthiosemicarbazone[H_(2)-(Sal-mtsc)]resulted in two entities,namely[Ru(H-Sal-mtsc)Cl(CO)(PPh_(3))_(2)](1)and[Ru(Salmtsc)(CO)...The reaction of[RuHCl(CO)(PPh_(3))_(3)]with an equimolar amount of salicylaldehyde-4(N)-methylthiosemicarbazone[H_(2)-(Sal-mtsc)]resulted in two entities,namely[Ru(H-Sal-mtsc)Cl(CO)(PPh_(3))_(2)](1)and[Ru(Salmtsc)(CO)(PPh_(3))_(2)](2)from a single tub.展开更多
基金the Department of Science and Technology and Ministry of Science and Technology,Government of India,New Delhi,India,for the INSPIRE Fellowship.Grant number for the INSPIRE Fellowship is IF150603,dated 10.04.2015.
文摘A naturally occurring nitrogen heterocycle-based Schiff base sensor 8-methyl-2-oxo-1,2-dihydroquinoline-3-carboxaldehyde-4N-phenylsemicarbazone(8MPS)was synthesized;a highly sensitive and selective“on-off-on”chemosensor for aspartic acid in aqueous solution was established.
基金support received from the Department of Science and Technology(DST),India and the Council of Science and Industrial Research(CSIR),New Delhi is gratefully acknowledged.
文摘The reaction of[RuHCl(CO)(PPh_(3))_(3)]with an equimolar amount of salicylaldehyde-4(N)-methylthiosemicarbazone[H_(2)-(Sal-mtsc)]resulted in two entities,namely[Ru(H-Sal-mtsc)Cl(CO)(PPh_(3))_(2)](1)and[Ru(Salmtsc)(CO)(PPh_(3))_(2)](2)from a single tub.
