In this study,the twinning-detwinning behavior and slip behavior of rolled AZ31 magnesium-alloy plates during a three-step intermittent dynamic compression process along the rolling direction(RD)and normal direction(N...In this study,the twinning-detwinning behavior and slip behavior of rolled AZ31 magnesium-alloy plates during a three-step intermittent dynamic compression process along the rolling direction(RD)and normal direction(ND),are investigated via quasi-in situ electron backscatter diffraction,and the causes of the twinning and detwinning behavior are explained according to Schmid law,local strain coordination,and slip trajectories.It is found that the twins are first nucleated and grow at a compressive strain of 3%along the RD.In addition to the Schmid factor(SF),the strain coordination factor(m’)also influences the selection of the twin variants during the twinning process,resulting in the nucleation of twins with a low SF.During the second and third steps of the application of continuous compressive strains with magnitudes and directions of 3%RD+3%ND and 3%RD+3%ND+2.5%ND,detwinning occurs to different extents.The observation of the detwinning behavior reveals that the order in which multiple twins within the same grain undergo complete detwinning is related to Schmid law and the strain concentration,with a low SF and a high strain concentration promoting complete detwinning.The interaction between slip dislocations and twin boundaries in the deformed grains as well as the pinning of dislocations at the tips of the {1012} tensile twins with a special structure result in incomplete detwinning.Understanding the microstructural evolution and twinning behavior of magnesium alloys under different deformation geometries is important for the development of high-strength and high-toughness magnesium alloys.展开更多
Investigations into the strain rate sensitivity of magnesium(Mg)alloys represent a current research focus in materials science.However,most studies have examined strain rate sensitivity in single alloy,lacking systema...Investigations into the strain rate sensitivity of magnesium(Mg)alloys represent a current research focus in materials science.However,most studies have examined strain rate sensitivity in single alloy,lacking systematic comparisons between different alloys.In the present study,a series of ZK60-xCe(x=0,0.3,0.8,1.3)alloys were fabricated via hot extrusion deformation.The microstructure evolution and strain rate sensitivity of these alloys under dynamic compressive loading were systematically investigated.According to thermal activation theory calculations,the strain rate sensitivities of ZK60-xCe alloys are predominantly governed by their deformation mechanisms.The enhanced strain rate sensitivity observed in Ce-containing ZK60 alloys is primarily attributed to their high dislocation density.This correlation stems from two key factors:(1)Ce-containing alloys demonstrate significantly higher ΔE and ΔT values compared to the base ZK60 alloy,providing the necessary energy conditions for high-density dislocation generation;and(2)the Ce addition effectively promotes (c+a) slip activation and facilitates cross-slip behavior.It is hoped that this work can provide a new perspective for the study of strain rate sensitivity in Mg alloys and offer a methodology for comparing strain rate sensitivity among different alloys.展开更多
The dynamic tensile properties and microstructural evolution of an extruded EW75 magnesium alloy deformed at ambient temperature and different high strain rates(from 1000 to 3000 s^(-1))along extrusion direction(ED)we...The dynamic tensile properties and microstructural evolution of an extruded EW75 magnesium alloy deformed at ambient temperature and different high strain rates(from 1000 to 3000 s^(-1))along extrusion direction(ED)were investigated by Split Hopkinson Tension Bar(SHTB).The corresponding deformation mechanisms,texture evolution and microstructure changes were analyzed by optical microscope(OM),electron backscatter diffraction(EBSD)and transmission electron microscope(TEM).The results show that the extruded EW75 magnesium alloy along ED exhibits a conventional positive strain rate sensitivity that the dynamic flow stresses increase with in creasing strain rate.Texture measurements show that after dynamic tension,the initial weak texture of extruded EW75 magnesium alloy tansforms to a relatively strong<10-10>//ED texture with increasing strain rates.The microstructural analysis demonstrates that dislocation motion are main deformatin mode to accommodate dynamic tensile deformation at high strain rates.In addition,the interactions of dislocation-dislocation and dislocation-second phase lead to the in crease of flow stress and strain hardening with increasing strain rate.展开更多
The dynamic compression experiments with Split-Hopkinson Pressure Bar(SHPB)were performed on AZ31 magnesium alloy rolled sheet specimens in the normal direction(AZ31-ND)with{0002}texture at the temperature of 293-523 ...The dynamic compression experiments with Split-Hopkinson Pressure Bar(SHPB)were performed on AZ31 magnesium alloy rolled sheet specimens in the normal direction(AZ31-ND)with{0002}texture at the temperature of 293-523 K and the strain rate of 0.001-2200 s^−1.The temperature term in Johnson-Cook(JC)constitutive model had been reasonably modified.This advantage made constitutive model promising for decribing the dynamic deformation behavior of AZ31-ND with{0002}texture more accurately.The obtained true stress-true plastic strain curves agreed well with the measured results in a wide range of strain rates and temperatures.The thermal softeninging,strain and strain rate hardening effect on the AZ31-ND with{0002}texture were discussed.The adiabatic shear band(ASB)of AZ31-ND with{0002}texture hat shaped specimen was successfully predicted by combining modified JC constitutive model and numerical simulation,which was also validated by Electron Back-Scattered Diffraction(EBSD)map under the same boundary condition.展开更多
Electronic structure and elastic properties of MgCu_(2),Mg_(2)Ca and MgZn_(2)phases were investigated by means of first-principles calculations from CASTEP program based on density functional theory(DFT).The calculate...Electronic structure and elastic properties of MgCu_(2),Mg_(2)Ca and MgZn_(2)phases were investigated by means of first-principles calculations from CASTEP program based on density functional theory(DFT).The calculated lattice parameters were in good agreement with the experimental and literature values.The calculated heats of formation and cohesive energies shown that MgCu_(2)has the strongest alloying ability and structural stability.The elastic constants of MgCu_(2),Mg_(2)Ca and MgZn_(2)phases were calculated,the bulk moduli,shear moduli,Young's moduli and Poisson's ratio were derived.The calculated results shown that MgCu_(2),Mg_(2)Ca and MgZn_(2)are all ductile phases.Among the three phases,MgCu_(2)has the strongest stiffness and the plasticity of MgZn_(2)phase is the best.The density of states(DOS),Mulliken electron occupation number and charge density difference of MgCu_(2),Mg_(2)Ca and MgZn_(2)phases were discussed to analyze the mechanism of structural stability and mechanical properties.展开更多
Herein, a hot tearing measured system with external excitation coil and a differential thermal analysis system with applied magnetic field were used to study the effects of low-frequency alternating magnetic field on ...Herein, a hot tearing measured system with external excitation coil and a differential thermal analysis system with applied magnetic field were used to study the effects of low-frequency alternating magnetic field on the solidification behavior and hot tearing susceptibility(HTS) of the AXJ530 alloy under different magnetic field parameters. The hot tearing volume of the castings was measured via paraffin infiltration method. The microstructure of the hot tearing zone of the casting was observed using optical microscopy and scanning electron microscopy, and the phase composition was analyzed using X-ray diffraction and energy depressive spectroscopy. The experimental results show that the solidification interval of AXJ530 alloy was shortened and the dendrite coherency temperature of the alloy decreased with the increase in frequency of alternating magnetic field. Under appropriate magnetic field parameters, the electromagnetic force could enhance the convection in the melt to promote the flow of the residual liquid phase, refine the microstructure, and optimize the feeding channel in the late solidification stage, which reduced the HTS of the alloy. However, when the magnetic field frequency was increased to 15 Hz, the induced current generated excessive Joule heat to the melt. At this time, the thermal action of the magnetic field coarsened the microstructure of the alloy, resulting in an increase in HTS of the alloy.展开更多
Fine grained Mg-7Gd-5Y-1.2Nd-0.5Zr alloy was investigated by dynamic compression tests using a Split Hopkinson Pressure Bar under the strain rates in the range 1000-2000 s^(-1) and the temperature range 293-573 K alon...Fine grained Mg-7Gd-5Y-1.2Nd-0.5Zr alloy was investigated by dynamic compression tests using a Split Hopkinson Pressure Bar under the strain rates in the range 1000-2000 s^(-1) and the temperature range 293-573 K along the normal direction.The microstructure was measured by optical microscopy,electron back-scattering diffraction,transmission electron microscopy and X-ray diffractometry.The results showed that Mg-7Gd-5Y-1.2Nd-0.5Zr alloy had the positive strain rate strengthening effect and thermal softening effect at high temperature.The solid solution of Gd and Y atoms in Mg-7Gd-5Y-1.2Nd-0.5Zr alloy reduced the asymmetry of α-Mg crystals and changed the critical shear stress of various deformation mechanisms.The main deformation mechanisms were prismatic slip and pyramidal(a)slip,{102}tension twinning,and dynamic recrystallization caused by local deformation such as particle-stimulated nucleation.c 2020 Published by Elsevier B.V.on behalf of Chongqing University.展开更多
The volume fraction and morphology of the TCP-phase formed in two kinds of Ni- Mo-Cr-Re superalloys under different heat treatment conditions were investigated in this paper. In Re-5% alloy, with increasing of the hea...The volume fraction and morphology of the TCP-phase formed in two kinds of Ni- Mo-Cr-Re superalloys under different heat treatment conditions were investigated in this paper. In Re-5% alloy, with increasing of the heat treatment temperature and prolonging the holding time, the volume fraction of TCP-phase decreased and the TCP-phase size increased. At relatively lower temperature, the TCP-phase prefers to present in the dendrite cores. In Re-10% alloy, the volume fraction and size have the same change tendency as that of in Re-5% alloy, but the morphology will change from needle-like and block-like to sphere when the temperature increases. The TCP-phases formed in these two Ni-Mo-Cr-Re alloys are σ and P phase.展开更多
The influences of Ca and Y additions on the microstructure and corrosion resistance of vacuum die-cast AZ91 alloys were investigated by optical microscope,electron scanning microscope,weight-loss test,and electrochemi...The influences of Ca and Y additions on the microstructure and corrosion resistance of vacuum die-cast AZ91 alloys were investigated by optical microscope,electron scanning microscope,weight-loss test,and electrochemical corrosion experiment.The results indicate that the Ca or Ca and Y additions refined the microstructure and decreased the amount of Mg17Al12 phase on grain boundaries in the alloys.Meanwhile,the addition of Ca and Y led to the formation of network Al2 Ca phase and rod-like Al2 Y phase,improved the corrosion resistance of AZ91 magnesium alloy.Compared with AZ91 alloy,the corrosion rate of AZ91–1.5Ca–1.0Y alloy was decreased to 16.2%,and its corrosion current density was dropped by one order of magnitude after immersion in 3.5 wt% NaCl solution for 24 h.展开更多
The effect of long-period stacking ordered(LPSO)phase on hot tearing susceptibility of Mg-1 Zn-xY serial alloys were investigated experimentally using a home-made T-type hot tearing mold.The characteristic parameters ...The effect of long-period stacking ordered(LPSO)phase on hot tearing susceptibility of Mg-1 Zn-xY serial alloys were investigated experimentally using a home-made T-type hot tearing mold.The characteristic parameters related to HTS during the solidification process were calculated by thermal analysis.The microstructure and morphology of the crack zone were characterized by optical microscope(OM),scanning electron microscopy(SEM)and electron dispersive spectrometer(EDS),and the phases of the alloys were analyzed by X-ray diffraction(XRD).The result showed that the long-period stacking ordered(LPSO)phase formed when m(Zn)/m(Y)<1,and the LPSO content increased with increasing of Y.The presence of the LPSO phase in Mg-lZn-xY alloys could benefit the hot tearing refilling and decrease the HTS of the alloys.With in creasing the content of LPSO phase,the HTS of the alloys decreased.LPSO phase increased the skeleton strength,and reduced the HTS of Mg-lZn-xY alloys.展开更多
The effects of addition of minor amount of(0.5 wt.%) antimony(Sb) or gadolinium(Gd) and combined addition of Sb and Gd(0.5 wt.%,respectively) on the hot tearing susceptibility(HTS) of Mg-5Al-3Ca alloy were investigate...The effects of addition of minor amount of(0.5 wt.%) antimony(Sb) or gadolinium(Gd) and combined addition of Sb and Gd(0.5 wt.%,respectively) on the hot tearing susceptibility(HTS) of Mg-5Al-3Ca alloy were investigated experimentally using a “T-shaped” hot tearing measuring system. Various solidification parameters of the alloys were measured and calculated through thermal analysis experiments. The microstructure, grain size, and morphology of the crack zone were characterized by scanning electron microscopy and electron backscatter diffraction, and the crystal phases of the alloys were analyzed by X-ray diffraction and energy-dispersive X-ray spectroscopy. The results showed that the addition of 0.5 wt.% Gd resulted in the increase in the vulnerable temperature range(Tv) and reduced the eutectic structure content that could participate in feeding, thereby improving the HTS of the alloy. However, addition of 0.5 wt.% Sb or combined addition of Gd and Sb(0.5 wt.%, respectively) to the Mg-5Al-3Ca alloy shortened the Tvand improved the skeleton strength of the alloy, thereby reducing HTS. Moreover, significantly refined structure of Mg-5Al-3Ca-0.5Gd-0.5Sb alloy improved the feeding ability of the eutectic structure, thus the alloy exhibited the lowest HTS.展开更多
The current work deals with the precipitation behaviors and mechanical properties of the high zinc content of the Mg-Zn-Cu system alloys using gravity casting.Differential scanning calorimetry(DSC)was conducted to des...The current work deals with the precipitation behaviors and mechanical properties of the high zinc content of the Mg-Zn-Cu system alloys using gravity casting.Differential scanning calorimetry(DSC)was conducted to describe the solidification process and precipitation behaviors.Thermodynamic calculations were carried out to determine the precipitation conditions using the Thermo-calc software.The microstructures were characterized by an optical microscope(OM),scanning electron microscope(SEM),electron probe micro analysis(EPMA),transmission electron microscopy(TEM),and confocal laser scanning microscope(CLSM).Tensile tests and micro-hardness tests were applied to investigate the mechanical properties.The results substantiated that the Mg Zn Cu phase precipitates in Cu-containing alloys and that the precipitate content,as well as the precipitate temperature,increased with the Cu content from 0 to 3 wt.%according to the thermodynamic calculations and the DSC results.The measured micro-hardness of the alloy was 53.2,57.9,55.8,and 52.5 VHN,respectively.The ultimate tensile strength(UTS),yield strength(YS),and elongation(EL)revealed a λ-like trend of the alloys,and Mg-7Zn-1Cu alloy exhibits the optimum tensile properties with the UTS of 258.9 MPa,YS of 126.2 MPa,and the EL of 14.2%.展开更多
基金supported by the General Project of Liaoning Provincial Department of Education(NO:JYTMS20231199)Project of Liaoning Education Department(No:LKMZ20220462 and No:LJKMZ20220467)+1 种基金Basic scientific research project of Liaoning Provincial Department of Education(key research project)(No:JYTZD2023108)Liaoning Nature Fund Guidance Plan(No:42022-BS.179)。
文摘In this study,the twinning-detwinning behavior and slip behavior of rolled AZ31 magnesium-alloy plates during a three-step intermittent dynamic compression process along the rolling direction(RD)and normal direction(ND),are investigated via quasi-in situ electron backscatter diffraction,and the causes of the twinning and detwinning behavior are explained according to Schmid law,local strain coordination,and slip trajectories.It is found that the twins are first nucleated and grow at a compressive strain of 3%along the RD.In addition to the Schmid factor(SF),the strain coordination factor(m’)also influences the selection of the twin variants during the twinning process,resulting in the nucleation of twins with a low SF.During the second and third steps of the application of continuous compressive strains with magnitudes and directions of 3%RD+3%ND and 3%RD+3%ND+2.5%ND,detwinning occurs to different extents.The observation of the detwinning behavior reveals that the order in which multiple twins within the same grain undergo complete detwinning is related to Schmid law and the strain concentration,with a low SF and a high strain concentration promoting complete detwinning.The interaction between slip dislocations and twin boundaries in the deformed grains as well as the pinning of dislocations at the tips of the {1012} tensile twins with a special structure result in incomplete detwinning.Understanding the microstructural evolution and twinning behavior of magnesium alloys under different deformation geometries is important for the development of high-strength and high-toughness magnesium alloys.
基金financial supports from the General Project of Liaoning Provincial Department of Education[No.LJKMZ20220462]and[No.LJKMZ20220467]Liaoning Nature Fund Guidance Plan[No.2022-BS-179]。
文摘Investigations into the strain rate sensitivity of magnesium(Mg)alloys represent a current research focus in materials science.However,most studies have examined strain rate sensitivity in single alloy,lacking systematic comparisons between different alloys.In the present study,a series of ZK60-xCe(x=0,0.3,0.8,1.3)alloys were fabricated via hot extrusion deformation.The microstructure evolution and strain rate sensitivity of these alloys under dynamic compressive loading were systematically investigated.According to thermal activation theory calculations,the strain rate sensitivities of ZK60-xCe alloys are predominantly governed by their deformation mechanisms.The enhanced strain rate sensitivity observed in Ce-containing ZK60 alloys is primarily attributed to their high dislocation density.This correlation stems from two key factors:(1)Ce-containing alloys demonstrate significantly higher ΔE and ΔT values compared to the base ZK60 alloy,providing the necessary energy conditions for high-density dislocation generation;and(2)the Ce addition effectively promotes (c+a) slip activation and facilitates cross-slip behavior.It is hoped that this work can provide a new perspective for the study of strain rate sensitivity in Mg alloys and offer a methodology for comparing strain rate sensitivity among different alloys.
基金The authors would like to thank Professor Kui Zhang,Beijing General Research Institute for Nonferrous Metal,for providing EW75 magnesium alloy for this work and acknowledge the funding from the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(Grant No.17KJD430006)Scientific and Technological Innovation Team Foundation of Wuxi Institute of Technology(No.30593118001)Scientific Research Project of Wuxi Institute of Technology(No.ZK201901).The help of EBSD experiment provided by Yukyung Shin from Helmholtz-Zentrum Geesthacht is gratefully acknowledged.
文摘The dynamic tensile properties and microstructural evolution of an extruded EW75 magnesium alloy deformed at ambient temperature and different high strain rates(from 1000 to 3000 s^(-1))along extrusion direction(ED)were investigated by Split Hopkinson Tension Bar(SHTB).The corresponding deformation mechanisms,texture evolution and microstructure changes were analyzed by optical microscope(OM),electron backscatter diffraction(EBSD)and transmission electron microscope(TEM).The results show that the extruded EW75 magnesium alloy along ED exhibits a conventional positive strain rate sensitivity that the dynamic flow stresses increase with in creasing strain rate.Texture measurements show that after dynamic tension,the initial weak texture of extruded EW75 magnesium alloy tansforms to a relatively strong<10-10>//ED texture with increasing strain rates.The microstructural analysis demonstrates that dislocation motion are main deformatin mode to accommodate dynamic tensile deformation at high strain rates.In addition,the interactions of dislocation-dislocation and dislocation-second phase lead to the in crease of flow stress and strain hardening with increasing strain rate.
基金This work was supported by Surface of the State Natural Science Fund Projects(No.51571145)City of Ningbo“science and technology innovation 2025”major special project(new energy vehicle lightweight magnesium alloy material precision forming technology).
文摘The dynamic compression experiments with Split-Hopkinson Pressure Bar(SHPB)were performed on AZ31 magnesium alloy rolled sheet specimens in the normal direction(AZ31-ND)with{0002}texture at the temperature of 293-523 K and the strain rate of 0.001-2200 s^−1.The temperature term in Johnson-Cook(JC)constitutive model had been reasonably modified.This advantage made constitutive model promising for decribing the dynamic deformation behavior of AZ31-ND with{0002}texture more accurately.The obtained true stress-true plastic strain curves agreed well with the measured results in a wide range of strain rates and temperatures.The thermal softeninging,strain and strain rate hardening effect on the AZ31-ND with{0002}texture were discussed.The adiabatic shear band(ASB)of AZ31-ND with{0002}texture hat shaped specimen was successfully predicted by combining modified JC constitutive model and numerical simulation,which was also validated by Electron Back-Scattered Diffraction(EBSD)map under the same boundary condition.
基金This work is supported by National Key Technology Research and Development Program of Ministry of Science and Technology of China(2011BAE22B00)Program for Liaoning Innovative Research Team in University.
文摘Electronic structure and elastic properties of MgCu_(2),Mg_(2)Ca and MgZn_(2)phases were investigated by means of first-principles calculations from CASTEP program based on density functional theory(DFT).The calculated lattice parameters were in good agreement with the experimental and literature values.The calculated heats of formation and cohesive energies shown that MgCu_(2)has the strongest alloying ability and structural stability.The elastic constants of MgCu_(2),Mg_(2)Ca and MgZn_(2)phases were calculated,the bulk moduli,shear moduli,Young's moduli and Poisson's ratio were derived.The calculated results shown that MgCu_(2),Mg_(2)Ca and MgZn_(2)are all ductile phases.Among the three phases,MgCu_(2)has the strongest stiffness and the plasticity of MgZn_(2)phase is the best.The density of states(DOS),Mulliken electron occupation number and charge density difference of MgCu_(2),Mg_(2)Ca and MgZn_(2)phases were discussed to analyze the mechanism of structural stability and mechanical properties.
基金the LiaoNing Revitalization Talents Program(No.XLYC1807021)the Innovation Talent Program in Sciences and Technologies for Young and Middle-aged Scientists of Shenyang(No.RC180111)the Doctoral Scientific Research Foundation of Liaoning Province(No.51504153)。
文摘Herein, a hot tearing measured system with external excitation coil and a differential thermal analysis system with applied magnetic field were used to study the effects of low-frequency alternating magnetic field on the solidification behavior and hot tearing susceptibility(HTS) of the AXJ530 alloy under different magnetic field parameters. The hot tearing volume of the castings was measured via paraffin infiltration method. The microstructure of the hot tearing zone of the casting was observed using optical microscopy and scanning electron microscopy, and the phase composition was analyzed using X-ray diffraction and energy depressive spectroscopy. The experimental results show that the solidification interval of AXJ530 alloy was shortened and the dendrite coherency temperature of the alloy decreased with the increase in frequency of alternating magnetic field. Under appropriate magnetic field parameters, the electromagnetic force could enhance the convection in the melt to promote the flow of the residual liquid phase, refine the microstructure, and optimize the feeding channel in the late solidification stage, which reduced the HTS of the alloy. However, when the magnetic field frequency was increased to 15 Hz, the induced current generated excessive Joule heat to the melt. At this time, the thermal action of the magnetic field coarsened the microstructure of the alloy, resulting in an increase in HTS of the alloy.
基金National Natural Science Foundation of China(Nos.51571145,51404137)City of Ningbo"science and technology innovation 2025"major special project(new energy vehicle lightweight magnesium alloy material precision forming technology)(No.2018B10045).
文摘Fine grained Mg-7Gd-5Y-1.2Nd-0.5Zr alloy was investigated by dynamic compression tests using a Split Hopkinson Pressure Bar under the strain rates in the range 1000-2000 s^(-1) and the temperature range 293-573 K along the normal direction.The microstructure was measured by optical microscopy,electron back-scattering diffraction,transmission electron microscopy and X-ray diffractometry.The results showed that Mg-7Gd-5Y-1.2Nd-0.5Zr alloy had the positive strain rate strengthening effect and thermal softening effect at high temperature.The solid solution of Gd and Y atoms in Mg-7Gd-5Y-1.2Nd-0.5Zr alloy reduced the asymmetry of α-Mg crystals and changed the critical shear stress of various deformation mechanisms.The main deformation mechanisms were prismatic slip and pyramidal(a)slip,{102}tension twinning,and dynamic recrystallization caused by local deformation such as particle-stimulated nucleation.c 2020 Published by Elsevier B.V.on behalf of Chongqing University.
基金the financial support from the National High Magnetic Field Laboratory under NSF DMR-0084173
文摘The volume fraction and morphology of the TCP-phase formed in two kinds of Ni- Mo-Cr-Re superalloys under different heat treatment conditions were investigated in this paper. In Re-5% alloy, with increasing of the heat treatment temperature and prolonging the holding time, the volume fraction of TCP-phase decreased and the TCP-phase size increased. At relatively lower temperature, the TCP-phase prefers to present in the dendrite cores. In Re-10% alloy, the volume fraction and size have the same change tendency as that of in Re-5% alloy, but the morphology will change from needle-like and block-like to sphere when the temperature increases. The TCP-phases formed in these two Ni-Mo-Cr-Re alloys are σ and P phase.
文摘The influences of Ca and Y additions on the microstructure and corrosion resistance of vacuum die-cast AZ91 alloys were investigated by optical microscope,electron scanning microscope,weight-loss test,and electrochemical corrosion experiment.The results indicate that the Ca or Ca and Y additions refined the microstructure and decreased the amount of Mg17Al12 phase on grain boundaries in the alloys.Meanwhile,the addition of Ca and Y led to the formation of network Al2 Ca phase and rod-like Al2 Y phase,improved the corrosion resistance of AZ91 magnesium alloy.Compared with AZ91 alloy,the corrosion rate of AZ91–1.5Ca–1.0Y alloy was decreased to 16.2%,and its corrosion current density was dropped by one order of magnitude after immersion in 3.5 wt% NaCl solution for 24 h.
基金High Level Innovation Team of Liaoning Province(XLYC1908006)Innovation Talent Program in Science and Technology for Young and Middle-aged Scientists of Shenyang(No.RC.180111)+2 种基金Project of Liaoning Education Department(Nos.LQGD2019002 and LJGD2019004)Liaoning nature fund guidance plan(No.2019-ZD-0210)Liaoning Revitalization Talents Program(Nos.XLYC 1807021 and 1907007).
文摘The effect of long-period stacking ordered(LPSO)phase on hot tearing susceptibility of Mg-1 Zn-xY serial alloys were investigated experimentally using a home-made T-type hot tearing mold.The characteristic parameters related to HTS during the solidification process were calculated by thermal analysis.The microstructure and morphology of the crack zone were characterized by optical microscope(OM),scanning electron microscopy(SEM)and electron dispersive spectrometer(EDS),and the phases of the alloys were analyzed by X-ray diffraction(XRD).The result showed that the long-period stacking ordered(LPSO)phase formed when m(Zn)/m(Y)<1,and the LPSO content increased with increasing of Y.The presence of the LPSO phase in Mg-lZn-xY alloys could benefit the hot tearing refilling and decrease the HTS of the alloys.With in creasing the content of LPSO phase,the HTS of the alloys decreased.LPSO phase increased the skeleton strength,and reduced the HTS of Mg-lZn-xY alloys.
基金financial support from Joint Research Fund Liaoning-Shenyang National Laboratory for Materials Science (2019JH3/30100014)Liaoning Bai Qian Wan Talents Program. Liaoning Revitalization Talents Program (Nos. XLYC1807021 and 1907007)+2 种基金High Level Innovation Team of Liaoning Province(XLYC1908006)Project of Liaoning Education Department(Nos. LQGD2019002, and LJGD2020008)Liaoning Nature Fund Guidance Plan (No. 2019-ZD-0210)。
文摘The effects of addition of minor amount of(0.5 wt.%) antimony(Sb) or gadolinium(Gd) and combined addition of Sb and Gd(0.5 wt.%,respectively) on the hot tearing susceptibility(HTS) of Mg-5Al-3Ca alloy were investigated experimentally using a “T-shaped” hot tearing measuring system. Various solidification parameters of the alloys were measured and calculated through thermal analysis experiments. The microstructure, grain size, and morphology of the crack zone were characterized by scanning electron microscopy and electron backscatter diffraction, and the crystal phases of the alloys were analyzed by X-ray diffraction and energy-dispersive X-ray spectroscopy. The results showed that the addition of 0.5 wt.% Gd resulted in the increase in the vulnerable temperature range(Tv) and reduced the eutectic structure content that could participate in feeding, thereby improving the HTS of the alloy. However, addition of 0.5 wt.% Sb or combined addition of Gd and Sb(0.5 wt.%, respectively) to the Mg-5Al-3Ca alloy shortened the Tvand improved the skeleton strength of the alloy, thereby reducing HTS. Moreover, significantly refined structure of Mg-5Al-3Ca-0.5Gd-0.5Sb alloy improved the feeding ability of the eutectic structure, thus the alloy exhibited the lowest HTS.
基金financial support from the National key research and development program(2021YFB3702005)National Natural Science Foundation of China(51974155)+2 种基金Major Science and Technology Projects of Liaoning Province(2020JH1/10100001)Outstanding Young Scientific and Technological Talents Project of University of Science and Technology Liaoning(2023YQ07)the High-level innovation team of Liaoning Province(XLYC1908006)。
文摘The current work deals with the precipitation behaviors and mechanical properties of the high zinc content of the Mg-Zn-Cu system alloys using gravity casting.Differential scanning calorimetry(DSC)was conducted to describe the solidification process and precipitation behaviors.Thermodynamic calculations were carried out to determine the precipitation conditions using the Thermo-calc software.The microstructures were characterized by an optical microscope(OM),scanning electron microscope(SEM),electron probe micro analysis(EPMA),transmission electron microscopy(TEM),and confocal laser scanning microscope(CLSM).Tensile tests and micro-hardness tests were applied to investigate the mechanical properties.The results substantiated that the Mg Zn Cu phase precipitates in Cu-containing alloys and that the precipitate content,as well as the precipitate temperature,increased with the Cu content from 0 to 3 wt.%according to the thermodynamic calculations and the DSC results.The measured micro-hardness of the alloy was 53.2,57.9,55.8,and 52.5 VHN,respectively.The ultimate tensile strength(UTS),yield strength(YS),and elongation(EL)revealed a λ-like trend of the alloys,and Mg-7Zn-1Cu alloy exhibits the optimum tensile properties with the UTS of 258.9 MPa,YS of 126.2 MPa,and the EL of 14.2%.
