Wide-bandgap mixed-halide perovskites,particularly CsPbIBr_(2),hold great promise for multi-junction solar cells due to their well-matched bandgap and all-inorganic material system.However,their inherent susceptibilit...Wide-bandgap mixed-halide perovskites,particularly CsPbIBr_(2),hold great promise for multi-junction solar cells due to their well-matched bandgap and all-inorganic material system.However,their inherent susceptibility to light-induced phase segregation(LIPS)limits efficiency and stability.In this work,we investigate the effect of three organic additives-4-cyclopentene-1,3-dione(CPD),maleimide(HPD),and 3,4-dibromo-1H-pyrrole-2,5(2H,5H)-dione(BrPD)-on LIPS in wide-bandgap CsPbIBr_(2)perovskite films.The additives form various chemical interactions,including coordination bonds,hydrogen bonds,and ionic bonds,with I^(-)and undercoordinated Pb^(2+)ions,among which BrPD has the strongest interaction.This interaction regulates crystallization and improves film morphology.The BrPD-modified films have the largest grain size and the highest light stability,suppressing LIPS,enhancing carrier transfer,and improving device performance.BrPD-modified CsPbIBr_(2)-based solar cells achieve a power conversion efficiency(PCE)of 11.34%,outperforming the control(8.96%)and other additives.Moreover,BrPDmodified devices show excellent stability,retaining 94%of their initial PCE after 60 min of continuous light exposure.This work highlights the potential of strategically selected organic additives to enhance the stability and performance of perovskite solar cells,offering valuable insights for the design of high-efficiency and long-lasting perovskite-based optoelectronic devices.展开更多
Sustainable development for our life is important task,which is driven by key materials and technologies.In this roadmap,we discuss three main aspects in addressing environmental questions,green chemical processes and...Sustainable development for our life is important task,which is driven by key materials and technologies.In this roadmap,we discuss three main aspects in addressing environmental questions,green chemical processes and energy challenges.They are included,such as gas treatment and separation,wastewater treatment,waste gas treatment,solid waste treatment,lithium extraction,hydrogen production,water splitting,CO_(2) reduction,photocatalytic clean technologies,plastic degradation,fuel cells,lithium batteries,sodium batteries,aqueous batteries,solid state batteries,metal air batteries and supercapacitors.Their status,challenges,progress and future perspectives are also discussed.We hope that this paper can give clear views on sustainable development in materials and technologies.展开更多
The recycling and reutilization of spent lithium-ion batteries(LIBs)have become an important measure to alleviate problems like resource scarcity and environmental pollution.Although some progress has been made,batter...The recycling and reutilization of spent lithium-ion batteries(LIBs)have become an important measure to alleviate problems like resource scarcity and environmental pollution.Although some progress has been made,battery recycling technology still faces challenges in terms of efficiency,effectiveness and environmental sustainability.This review aims to systematically review and analyze the current status of spent LIB recycling,and conduct a detailed comparison and evaluation of different recycling processes.In addition,this review introduces emerging recycling techniques,including deep eutectic solvents,molten salt roasting,and direct regeneration,with the intent of enhancing recycling efficiency and diminishing environmental repercussions.Furthermore,to increase the added value of recycled materials,this review proposes the concept of upgrading recycled materials into high value-added functional materials,such as catalysts,adsorbents,and graphene.Through life cycle assessment,the paper also explores the economic and environmental impacts of current battery recycling and highlights the importance that future recycling technologies should achieve a balance between recycling efficiency,economics and environmental benefits.Finally,this review outlines the opportunities and challenges of recycling key materials for next-generation batteries,and proposes relevant policy recommendations to promote the green and sustainable development of batteries,circular economy,and ecological civilization.展开更多
The formation and growth of Li-dendrites caused by inhomogeneous Li deposition severely hinder the commercial applications of Li metal batteries due to the consequence of short-circuiting.Herein,we propose a Janus bil...The formation and growth of Li-dendrites caused by inhomogeneous Li deposition severely hinder the commercial applications of Li metal batteries due to the consequence of short-circuiting.Herein,we propose a Janus bilayer composed of black phosphorus(BP)and graphene oxide(GO)as an artificial interface with chemical/mechanical stability and well-regulated Li-ion flux distribution for Li metal anode protection.Owing to the synergy between the fast Li-ion transport of BP in the inner layer and the high mechanical and chemical stability of GO in the outer layer,the GO/BP with good electrolyte wettability acts as a Li-ion regulator that can induce homogeneous growth of Li to suppress the Li dendrites growth.Accordingly,long-term stability(500 h at 1 mA cm^(-2))with a low overpotential of 30 mV is achieved in the symmetric cell with GO/BP-Li anode.Furthermore,the Li–S cell with GO/BP-Li exhibits enhanced cycling performance with a high capacity retention rate of 76.2%over 500 cycles at 1 C.展开更多
Organic–inorganic perovskites solar cells(PSCs)have attracted great attention due to their rapid progress in power conversion efficiency(PCE).However,there is still an enormous challenge to achieve both high efficien...Organic–inorganic perovskites solar cells(PSCs)have attracted great attention due to their rapid progress in power conversion efficiency(PCE).However,there is still an enormous challenge to achieve both high efficiency and stability devices as the decomposition of perovskite materials under humid and light conditions.Herein,we demonstrate that high efficiency and stability of PSCs can be obtained by the reaction of three-dimensional(3D)perovskite with 1,4-butanediamine iodide(BEAI2)vapor.The incorporation of BEAI2 intensively promotes the crystallization of perovskite film with large grain size(~500 nm).Further characterization reveals that the post-treatment perovskite film delivered low interface trap density with long carrier lifetime(>200 ns),long carrier diffusion length(>600 nm)and large carrier mobility(>1.5 cm^2 V-1S-1).Solar cells employing such post-treatment films demonstrated 19.58%PCE without hysteresis.Moreover,the post-treatment devices can retain over 90%original efficiencies stored under ambient atmospheric conditions and exhibit better stability under 85℃and continuous illumination as a two-dimensional(2D)perovskite thin layer is formed on the surface/or at the grain boundaries of 3D perovskite.This study offers an effective way to obtain PSCs with high efficiency and stability.展开更多
Tomato(Solanum lycopersicum)is a perishable fruit because of its fast water loss and susceptibility to pathogens in the post-harvest stage,which leads to huge economic losses every year.In this study,firstly from 19 t...Tomato(Solanum lycopersicum)is a perishable fruit because of its fast water loss and susceptibility to pathogens in the post-harvest stage,which leads to huge economic losses every year.In this study,firstly from 19 tomato cultivars,we screened out two cultivars,Riogrand and SalarF1,having long and short shelf-life spans,respectively.Secondly,shelf-life analysis was carried out for both cultivars at room temperature.Results exhibited that Riogrand showed higher firmness and less weight loss than SalarF1.The ethylene production was higher in SalarF1,compared with Riogrand during post-harvest storages.We performed transcriptomic analysis of both cultivars in different storage stages.We discovered 2913,2188,and 11,119 differentially expressed genes(DEGs)for three post-harvest stages(0,20,and 40 Days Post-Harvest(DPH)),respectively.These genes are enriched in ethylene biosynthesis and response,as well as cell wall-related genes.Ethylene response factor(ERF)ERF2 and ERF4 were highly expressed in SalarF1 with a short shelf life in 40 DPH,and the ethylene biosynthetic genes ACO1,ACO4,ACS6,and ACS2 were significantly upregulated in SalarF1.Regarding cell wall loosening and cell wall-related genes XTH3,XTH7,XTH23,1,3;1,4-β-D-Gluc-like,pGlcT1,Cellulase,PGH1,PL5,PL-like 1,PL-like 2 exhibited the highest levels of significance,being notably upregulated in the last stage of SalarF1.The quantitative real-time polymerase chain reaction(qRT-PCR)analysis validated these gene expressions,which is in line with the transcriptome analysis.The findings suggested that the extension of tomato fruit shelf life is mostly dependent on ethylene biosynthesis,signaling pathway genes,cell wall loosening,and cell wall-associated genes.展开更多
Magnesium-air(Mg-air)batteries have emerged as a promising sustainable energy storage technology,offering exceptional theoretical energy density,low cost,and environmental compatibility.Despite these advantages,their ...Magnesium-air(Mg-air)batteries have emerged as a promising sustainable energy storage technology,offering exceptional theoretical energy density,low cost,and environmental compatibility.Despite these advantages,their development remains largely confined to experimental phase.A critical barrier to commercialization is the poor corrosion resistance of the anode resulting in low anodic efficiency.This article presents a comprehensive review of strategies aimed at improving the utilization efficiency of Mg anodes,with a particular focus on addressing corrosion issues from a microstructural standpoint.Firstly,the principle of Mg-air batteries has been outlined and the corrosion behavior has been discussed.The review then delves into a variety of representative anode materials.Special attention is given to innovative material designs that mitigate the challenges typically encountered by Mg-air batteries.Finally,the paper provides an outlook on future research directions,identifying critical technological barriers and highlighting areas that warrant further investigation.By offering a detailed analysis of material structures,this article aims to contribute valuable insights for advancing the development of high-performance Mg-air batteries.展开更多
Organic-inorganic hybrid perovskite solar cells achieve remarkable efficiencies(>26%)yet face stability challenges.Quasi-2D alternating-cation-interlayer perovskites offer enhanced stability through hydrophobic spa...Organic-inorganic hybrid perovskite solar cells achieve remarkable efficiencies(>26%)yet face stability challenges.Quasi-2D alternating-cation-interlayer perovskites offer enhanced stability through hydrophobic spacer cations but suffer from vertical phase segregation and buried interface defects.Herein,we introduce dicyanodiamide(DCD)to simultaneously address these dual limitations in GA(MA)_(n)Pb_(n)I_(3n+1)perovskites.The guanidine group in DCD passivates undercoordinated Pb^(2+)and MA^(+)vacancies at the perovskite/TiO_(2)interface,while cyano groups eliminate oxygen vacancies in TiO_(2)via Ti^(4+)-CN coordination,reducing interfacial trap density by 73%with respect to the control sample.In addition,DCD regulates crystallization kinetics,suppressing low-n-phase aggregation and promoting vertical alignment of high-n phases,which benefit for carrier transport.This dual-functional modification enhances charge transport and stabilizes energy-level alignment.The optimized devices achieve a record power conversion efficiency of 21.54%(vs.19.05%control)and retain 94%initial efficiency after 1200 h,outperforming unmodified counterparts(84%retention).Combining defect passivation with phase homogenization,this work establishes a molecular bridge strategy to decouple stability-efficiency trade-offs in low-dimensional perovskites,providing a universal framework for interface engineering in high-performance optoelectronics.展开更多
低维钙钛矿太阳能电池(Low-Dimensional Perovskite Solar Cells,LD PSCs)是一种稳定性好、疏水性强的新型钙钛矿光伏器件,在新能源领域受到了广泛的关注。本实验以领域内的前沿进展为出发点,提供丁胺(Butylammonium,BA)离子、半胱氨酸...低维钙钛矿太阳能电池(Low-Dimensional Perovskite Solar Cells,LD PSCs)是一种稳定性好、疏水性强的新型钙钛矿光伏器件,在新能源领域受到了广泛的关注。本实验以领域内的前沿进展为出发点,提供丁胺(Butylammonium,BA)离子、半胱氨酸(2-氨基-3-巯基丙酸,Cysteine,Cys)离子作为有机间隔阳离子,合成了低维钙钛矿晶体并制备出以(BA)2(MA)n-1PbnI3n+1或(Cys)2(MA)n-1PbnI3n+1为活性层的钙钛矿太阳能电池,并通过X射线衍射检测、紫外-可见吸收检测等手段对产品进行表征,之后测定了钙钛矿器件的能量转换效率。本实验难度适中,涉及光伏器件的制备与表征,旨在激励本科生对前沿光电研究产生兴趣、培养其科研能力。展开更多
Multifunctional photodetectors boost the development of traditional optical communication technology and emerging artificial intelligence fields, such as robotics and autonomous driving. However, the current implement...Multifunctional photodetectors boost the development of traditional optical communication technology and emerging artificial intelligence fields, such as robotics and autonomous driving. However, the current implementation of multifunctional detectors is based on the physical combination of optical lenses, gratings, and multiple photodetectors, the large size and its complex structure hinder the miniaturization, lightweight, and integration of devices. In contrast, perovskite materials have achieved remarkable progress in the field of multifunctional photodetectors due to their diverse crystal structures, simple morphology manipulation, and excellent optoelectronic properties. In this review, we first overview the crystal structures and morphology manipulation techniques of perovskite materials and then summarize the working mechanism and performance parameters of multifunctional photodetectors. Furthermore, the fabrication strategies of multifunctional perovskite photodetectors and their advancements are highlighted, including polarized light detection, spectral detection, angle-sensing detection, and selfpowered detection. Finally, the existing problems of multifunctional detectors and the perspectives of their future development are presented.展开更多
Forest trees can establish symbiotic associations with dark septate endophytes(DSEs)and ectomycorrhizal fungi(ECMF)simultaneously.However,the combined effects of these two fungi on the growth and cadmium(Cd)tolerance ...Forest trees can establish symbiotic associations with dark septate endophytes(DSEs)and ectomycorrhizal fungi(ECMF)simultaneously.However,the combined effects of these two fungi on the growth and cadmium(Cd)tolerance of host plants remain largely unexplored.To address this knowledge gap,a pot experiment was conducted to examine the effects of the interaction between an ECMF strain(Suillus granulatus)and a DSE strain(Pseudopyrenochaeta sp.)on Pinus tabulaeformis under Cd stress,by assessing plant growth and physiological parameters,nutrient uptake,and soil properties.Notably,the colonization rates of both fungal strains were found to increase in response to Cd stress,with the extent of this increase being influenced by the specific fungal species and the Cd level in the soil.Compared to the non-inoculation treatment,single inoculation with fungal strain resulted in enhanced biomass,root development,and nutrient contents in P.tabulaeformis seedlings under Cd stress.Furthermore,a synergistic effect was observed when these seedlings were co-inoculated with S.granulatus and Pseudopyrenochaeta sp.,as indicated by significantly greater measurements in various indicators compared to both the single and non-inoculation treatments.Fungal inoculation effectively regulated the antioxidant defense responses and photosynthesis of P.tabulaeformis seedlings subjected to Cd stress,particularly in the co-inoculation treatment.In addition,fungal inoculation facilitated the Cd accumulation in P.tabulaeformis,suggesting a promising potential for the implementation of bioremediation strategies in the areas contaminated with heavy metals.The findings from this study indicate that the utilization of root symbiotic fungi obtained from stress environments could potentially enhance the growth performance and tolerance of P.tabulaeformis towards heavy metals,and co-inoculation of both fungal groups may result in even more pronounced synergistic effects on the overall fitness of the plant.展开更多
We study the influence of external magnetic field on the shift of the resonant frequency in the photoassociation of ultracold Cs atoms, which are captured in a magnetically levitated optical crossed dipole trap. With ...We study the influence of external magnetic field on the shift of the resonant frequency in the photoassociation of ultracold Cs atoms, which are captured in a magnetically levitated optical crossed dipole trap. With the increase of the photoassociation laser intensity, the linear variation of the frequency shift is measured by recording the photoassociation spectra of the long-range 0_u^+ state of Cs molecule below the 6S_(1/2)+ 6P_(1/2) dissociation limit at different magnetic fields.The slope of the frequency shift to the intensity of the photoassociation laser exhibits a strong dependence on the external magnetic field. The experimental data is simulated with an analytic theory model, in which a single channel rectangular potential with the tunable well depth is introduced to acquire the influence of the magnetic field on the atomic behavior in the effective range where photoassociation occurs.展开更多
Rechargeable metal-ion batteries, such as lithium-ion batteries(LIBs) and sodium-ion batteries(SIBs),have raised more attention because of the large demand for energy storage solutions. Undoubtedly, electrode material...Rechargeable metal-ion batteries, such as lithium-ion batteries(LIBs) and sodium-ion batteries(SIBs),have raised more attention because of the large demand for energy storage solutions. Undoubtedly, electrode materials and electrolytes are key parts of batteries, exhibiting critical influence on the reversible capacity and span life of the metal-ion battery. Nonetheless, researchers commonly express concerns regarding the stability of both electrodes and electrolytes. Given its commendable stability attributes,high-entropy materials have garnered widespread acclaim and have been applied in many fields since their inception, notably in energy storage. However, while certain high-entropy designs have achieved substantial breakthroughs, some have failed to meet anticipated outcomes within the high energy density energy storage materials. Moreover, there is a lack of comprehensive summary research on the corresponding mechanisms and design principles of high-entropy designs. This review examines the current high-entropy designs for cathodes, anodes, and electrolytes, aiming to summarize the design principle,potential mechanisms, and electrochemical performance. We focus on their structural characteristics,interface characteristics, and prospective development trends. At last, we provide a fair evaluation along-side succinct development suggestions.展开更多
Single event latch-up (SEL) is a significant issue for electronics design in space application, which would cause large currents in electronic devices, and may lead to burning out of devices. A new monitoring circuit ...Single event latch-up (SEL) is a significant issue for electronics design in space application, which would cause large currents in electronic devices, and may lead to burning out of devices. A new monitoring circuit based on current-comparing method is designed to protect the electronics away from SEL’s damage in radiation environment. The response time of protection circuit has been analyzed. The signal simulation results indicated that the operating time of the SEL protection circuit is dependent on the action time of current comparator and system application recovery time. The function of the monitoring circuit protection device away from SEL’s damage has validated through experiment at last.展开更多
A concentric gravity wave event was captured by a photographer in NagarzêCounty(90.28°N,28.33°E)between 02:00 and 04:00(local time)on May 11,2019.This concentric gravity wave event was also observed by ...A concentric gravity wave event was captured by a photographer in NagarzêCounty(90.28°N,28.33°E)between 02:00 and 04:00(local time)on May 11,2019.This concentric gravity wave event was also observed by the Suomi National Polar-orbiting Partnership satellite and the all-sky airglow imager at Yangbajing station(90.5°E,30.1°N).The temporal and spatial information on gravity waves from the photographs provided a rare opportunity to study the propagation of gravity waves over the Tibetan Plateau.According to wind and temperature data from the MERRA-2 reanalysis(Modern-Era Retrospective analysis for Research and Applications,Version 2)and empirical models(NRLMSISE-00[Naval Research Laboratory Mass Spectrometer and Incoherent Scatter Radar Exosphere]and HWM[horizontal wind model]),we inversely derived the propagation trajectory from the observed wave pattern to the source region by using the ray-tracing method.The source of the concentric gravity wave was identified as deep convection in Bangladesh(90.6°E,25.0°N).The maximum background wind speed in the propagation direction(31.05 m/s)was less than the phase speed of 53 m/s,which is consistent with the wind-filtering theory.展开更多
Drilling for karst hydrothermal resources in eastern China has posed challenges,including disparities between the temperature and yield of geothermal water.It is evident that relying solely on geothermal anomalies or ...Drilling for karst hydrothermal resources in eastern China has posed challenges,including disparities between the temperature and yield of geothermal water.It is evident that relying solely on geothermal anomalies or indications of karst reservoirs is inadequate for the exploration of karst hydrothermal resources.This study seeks to elucidate the cause of geothermal sweet spots by analyzing the interplay between geothermal anomalies and karst reservoirs and the underlying geological conditions for karst hydrothermal enrichment.Key findings include:(1)the Bohai Bay Basin has been geologically favorable for the development of karst hydrothermal resources since the Mesozoic era;(2)the karst hydrothermal enrichment varies significantly between the basin’s margin and its interior.On the basin margin,the enrichment is largely driven by groundwater activity and faults,particularly where faults facilitate the upwelling of geothermal water.In contrast,within the basin’s interior,karst hydrothermal resources are predominantly influenced by buried hills and are especially enriched in areas facilitating the discharge of deep geothermal waters.展开更多
Perovskite tandem solar cells(TSCs)hold substantial promise for surpassing the efficiency limits of single-junction solar cells.Nevertheless,achieving high open-circuit voltage(VOC)in wide-bandgap perovskite devices r...Perovskite tandem solar cells(TSCs)hold substantial promise for surpassing the efficiency limits of single-junction solar cells.Nevertheless,achieving high open-circuit voltage(VOC)in wide-bandgap perovskite devices remains a challenge due to significant VOC-losses.Here,we introduce a heterogeneous interface anchoring strategy aimed at enhancing interfacial properties by incorporating a silane coupling agent between the perovskite and hole transport layers.Trimethoxysilane(TMOS),an amphiphilic molecule,strengthens interfacial adhesion through enhanced chemical interactions,thereby promoting efficient hole extraction.Additionally,the terminal functional groups of TMOS molecules interact with lead ions,modulating the perovskite film crystallization and improving their overall quality.Devices treated with TMOS exhibit a marked reduction in non-radiative recombination,leading to a significant increase in VOC.Notably,3-cyanopropyltrimethoxysilane(CN-TMOS)optimizes the uniformity and interfacial contact of the perovskite film,achieving a VOC of 1.345 V and a power conversion efficiency(PCE)of 19.69%.The corresponding VOC-loss,relative to the bandgap,is reduced to 0.425 V,one of the lowest values reported for wide-bandgap perovskite single-junction solar cells.Extending this strategy to all-perovskite TSCs,we achieve a PCE of 28.45%and exceptional operational stability,retaining over 90%of the initial efficiency after 500 h of continuous operation under 1 sun illumination.展开更多
The power conversion effciency(PCE)of flexible perovskite solar cells(PSCs)has increased rapidly,while the mechanical flexibility and environmental stability are still far from satisfactory.Previous studies show the e...The power conversion effciency(PCE)of flexible perovskite solar cells(PSCs)has increased rapidly,while the mechanical flexibility and environmental stability are still far from satisfactory.Previous studies show the environmental degradation and ductile cracks of perovskite films usually begin at the grain boundaries(GBs).Herein,sulfonated graphene oxide(s-GO)is employed to construct a cementitious GBs by interacting with the[Pb I6]4–at GBs.The resultant s-GO-[Pb I6]4–complex can effectively passivate the defects of vacant iodine,and the devices with s-GO exhibit remarkable waterproofness and flexibility due to the tough and water-insoluble GBs.The champion PCE of 20.56%(1.01 cm^(2))in a device treated with s-GO is achieved.This device retains 90%of its original PCE after 180 d stored in the ambient condition,as well as over 80%retention after 10,000 bending cycles at a curvature radius of 3 mm.展开更多
For maximum utilization of solar energy,photovoltaic(PV)power systems should be operated at the maximum power point(MPP)which can be achieved using maximum power point tracking(MPPT)methods.However,the occurrence of m...For maximum utilization of solar energy,photovoltaic(PV)power systems should be operated at the maximum power point(MPP)which can be achieved using maximum power point tracking(MPPT)methods.However,the occurrence of multi-peak on P-V curve of a PV array due to the changing environmental conditions such as being partially shaded increases the complexity of the tracking process.The global MPP cannot always be achieved by the conventional MPPT methods.Therefore a novel MPPT method for PV systems using flower pollination(FP)algorithm is proposed in this paper and the Levy flight is used to improve the convergence of FP algorithm.MPPT model of the PV system is established in MATLAB to verify the effectiveness of the proposed method,and the proposed method is compared with two well established MPPT methods.The simulation results indicate that the proposed MPPT method can quickly track the changes in external environment and effectively handle the partially shaded condition.展开更多
Emerging organic–inorganic metal halide perovskite materials have become the focus of the optoelectronics research community owing to their excellent photoelectric properties.Nevertheless,challenges still exist for t...Emerging organic–inorganic metal halide perovskite materials have become the focus of the optoelectronics research community owing to their excellent photoelectric properties.Nevertheless,challenges still exist for transferring the lab-made devices to largearea industrial modules.Inkjet printing(IJP)technology provides a promising way to fill the gap because of its precise droplet control and uniform large-scale deposition functions.Hence,an in-depth understanding of inkjet-printed perovskite films in terms of droplet manipulation and crystallization regulation is critical for upscaling the perovskite devices to commercial usage.In this review,we give an overview of inkjet-printed high-quality perovskite films and provide guidelines on inkjet-printing large-scale highperformance perovskite devices.First,we analyze theories of droplet formation and perovskite nucleation/crystallization dynamics and then focus on summarizing the perovskite film-formation strategies via IJP,in the aspects of ink engineering,the printing process,and posttreatment.Furthermore,we review the recent advances of inkjet-printed perovskite films on optoelectronic devices,such as perovskite solar cells,perovskite light-emitting diodes,and perovskite photodetectors.Finally,we highlight the“Trilogy Strategies,”including ink engineering,printing process,and posttreatment for printing high-quality perovskite films.展开更多
基金supported financially by the National Key R&D Program of China(Grant No.2023YFE0111500)the National Natural Science Foundation of China(Grant Nos.52321006,T2394480,T2394484,22109143,22475196,22479131)+11 种基金the Research Grants Council of Hong Kong(CRF C4005-22YRGC Senior Research Fellowship Scheme(SRFS2223-5S01))the Joint Fund for Provincial Science and Technology R&D Program of Henan(grant no.242301420051)the Opening Project of the State Key Laboratory of Advanced Technology for Float Glass(grant no.2022KF04)the China Postdoctoral Innovative Talent Support Program(grant no.BX2021271)the China Postdoctoral Science Foundation(grant no.2022M712851)the Graduate Education Reform Project of Henan Province(Grant No.2023SJGLX136Y)the Key R&D Special Program of Henan Province(Grant No.241111242000)the Program for Science&Technology Innovation Talents in Universities of Henan Province(Grant No.25HASTIT005)the Training Plan for Young Backbone Teachers of Zhengzhou University(Grant No.2023ZDGGJS017)the Joint Research Project of Puyang ShengtongJuyuan New Materials Co.Ltd.(Grant No.20230128A)。
文摘Wide-bandgap mixed-halide perovskites,particularly CsPbIBr_(2),hold great promise for multi-junction solar cells due to their well-matched bandgap and all-inorganic material system.However,their inherent susceptibility to light-induced phase segregation(LIPS)limits efficiency and stability.In this work,we investigate the effect of three organic additives-4-cyclopentene-1,3-dione(CPD),maleimide(HPD),and 3,4-dibromo-1H-pyrrole-2,5(2H,5H)-dione(BrPD)-on LIPS in wide-bandgap CsPbIBr_(2)perovskite films.The additives form various chemical interactions,including coordination bonds,hydrogen bonds,and ionic bonds,with I^(-)and undercoordinated Pb^(2+)ions,among which BrPD has the strongest interaction.This interaction regulates crystallization and improves film morphology.The BrPD-modified films have the largest grain size and the highest light stability,suppressing LIPS,enhancing carrier transfer,and improving device performance.BrPD-modified CsPbIBr_(2)-based solar cells achieve a power conversion efficiency(PCE)of 11.34%,outperforming the control(8.96%)and other additives.Moreover,BrPDmodified devices show excellent stability,retaining 94%of their initial PCE after 60 min of continuous light exposure.This work highlights the potential of strategically selected organic additives to enhance the stability and performance of perovskite solar cells,offering valuable insights for the design of high-efficiency and long-lasting perovskite-based optoelectronic devices.
基金supported by the Russian Science Foundation(No.22-13-00035)the National Outstanding Young Scientists Fund(No.52125002)+14 种基金the National Key Research and Development Program of China(Nos.2023YFC3904800 and 2022YFB4002501)the National Natural Science Foundation of China(Nos.52400228,52300139,22308063,52103340,U22A20418,22578302,52202208,52400163,52205054,22075171,52177214,22405201,52371072,52171078,52377218)the Key Research and Development Project of Science and Technology Department of Zhejiang Province(No.2024C03284(SD2))the Research Development Fund of Zhejiang A&F University(No.2024LFR042)the President Research Funds from Xiamen University(No.ZK1111)Nanqiang Youth Scholar program of Xiamen University,the Young Elite Scientists Sponsorship Program by CAST(No.2023QNRC001)Natural Science Foundation of Xiamen(No.3502z202471037)Open Fund of the State Environmental Protection Key Laboratory of Urban Air Particulate Matter Pollution Prevention and Control,College of Environmental Science and Engineering,Nankai University(No.NKPMLF202409)the Key Project of Research and Development Plan of Jiangxi Province(No.20243BBI91001)Natural Science Foundation of Shanghai(No.23ZR1423400)the Postdoctoral Science Research Program of Shaanxi(No.2023BSHEDzZ159)Xidian University Specially Funded Project for Interdisciplinary Exploration(No.TZJH2024062)the Open Project of Yunnan Precious Metals Laboratory Co.,Ltd.(No.YPML-20240502058)the Fundamental Research Program of Shanxi Province(No.202303021212159)the Natural Science Foundation of Shanxi Normal University(No.JCYJ2024017).
文摘Sustainable development for our life is important task,which is driven by key materials and technologies.In this roadmap,we discuss three main aspects in addressing environmental questions,green chemical processes and energy challenges.They are included,such as gas treatment and separation,wastewater treatment,waste gas treatment,solid waste treatment,lithium extraction,hydrogen production,water splitting,CO_(2) reduction,photocatalytic clean technologies,plastic degradation,fuel cells,lithium batteries,sodium batteries,aqueous batteries,solid state batteries,metal air batteries and supercapacitors.Their status,challenges,progress and future perspectives are also discussed.We hope that this paper can give clear views on sustainable development in materials and technologies.
基金financially supported by the National Natural Science Foundation of China(NSFC)(52274295)the Natural Science Foundation of Hebei Province(E2020501001,E2021501029,A2021501007,E2022501028,E2022501029)+5 种基金the Natural Science Foundation-Steel,the Iron Foundation of Hebei Province(No.E2022501030)the Performance subsidy fund for Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province(22567627H)the Science and Technology Project of Hebei Education Department(ZD2022158)the Central Guided Local Science and Technology Development Fund Project of Hebei province(226Z4401G)the China Scholarship Council(No.202206080061,202206050119)the 2023 Hebei Provincial Postgraduate Student Innovation Ability training funding project(CXZZSS2023195)。
文摘The recycling and reutilization of spent lithium-ion batteries(LIBs)have become an important measure to alleviate problems like resource scarcity and environmental pollution.Although some progress has been made,battery recycling technology still faces challenges in terms of efficiency,effectiveness and environmental sustainability.This review aims to systematically review and analyze the current status of spent LIB recycling,and conduct a detailed comparison and evaluation of different recycling processes.In addition,this review introduces emerging recycling techniques,including deep eutectic solvents,molten salt roasting,and direct regeneration,with the intent of enhancing recycling efficiency and diminishing environmental repercussions.Furthermore,to increase the added value of recycled materials,this review proposes the concept of upgrading recycled materials into high value-added functional materials,such as catalysts,adsorbents,and graphene.Through life cycle assessment,the paper also explores the economic and environmental impacts of current battery recycling and highlights the importance that future recycling technologies should achieve a balance between recycling efficiency,economics and environmental benefits.Finally,this review outlines the opportunities and challenges of recycling key materials for next-generation batteries,and proposes relevant policy recommendations to promote the green and sustainable development of batteries,circular economy,and ecological civilization.
基金financially supported by the National Natural Science Foundation of China(21771154)the Shenzhen Fundamental Research Programs(JCYJ20190809161013453)+1 种基金the Fundamental Research Funds for the Central Universities(20720220031)the 111 Project(B16029)。
文摘The formation and growth of Li-dendrites caused by inhomogeneous Li deposition severely hinder the commercial applications of Li metal batteries due to the consequence of short-circuiting.Herein,we propose a Janus bilayer composed of black phosphorus(BP)and graphene oxide(GO)as an artificial interface with chemical/mechanical stability and well-regulated Li-ion flux distribution for Li metal anode protection.Owing to the synergy between the fast Li-ion transport of BP in the inner layer and the high mechanical and chemical stability of GO in the outer layer,the GO/BP with good electrolyte wettability acts as a Li-ion regulator that can induce homogeneous growth of Li to suppress the Li dendrites growth.Accordingly,long-term stability(500 h at 1 mA cm^(-2))with a low overpotential of 30 mV is achieved in the symmetric cell with GO/BP-Li anode.Furthermore,the Li–S cell with GO/BP-Li exhibits enhanced cycling performance with a high capacity retention rate of 76.2%over 500 cycles at 1 C.
基金the financial support by the National Natural Science Foundation of China(Grant nos.21605090,31600527)。
文摘Organic–inorganic perovskites solar cells(PSCs)have attracted great attention due to their rapid progress in power conversion efficiency(PCE).However,there is still an enormous challenge to achieve both high efficiency and stability devices as the decomposition of perovskite materials under humid and light conditions.Herein,we demonstrate that high efficiency and stability of PSCs can be obtained by the reaction of three-dimensional(3D)perovskite with 1,4-butanediamine iodide(BEAI2)vapor.The incorporation of BEAI2 intensively promotes the crystallization of perovskite film with large grain size(~500 nm).Further characterization reveals that the post-treatment perovskite film delivered low interface trap density with long carrier lifetime(>200 ns),long carrier diffusion length(>600 nm)and large carrier mobility(>1.5 cm^2 V-1S-1).Solar cells employing such post-treatment films demonstrated 19.58%PCE without hysteresis.Moreover,the post-treatment devices can retain over 90%original efficiencies stored under ambient atmospheric conditions and exhibit better stability under 85℃and continuous illumination as a two-dimensional(2D)perovskite thin layer is formed on the surface/or at the grain boundaries of 3D perovskite.This study offers an effective way to obtain PSCs with high efficiency and stability.
基金supported by the National Natural Science Foundation of China(Grant No.U23A20204)the“Wanjiang Scholar Program(Anhui Province)”.
文摘Tomato(Solanum lycopersicum)is a perishable fruit because of its fast water loss and susceptibility to pathogens in the post-harvest stage,which leads to huge economic losses every year.In this study,firstly from 19 tomato cultivars,we screened out two cultivars,Riogrand and SalarF1,having long and short shelf-life spans,respectively.Secondly,shelf-life analysis was carried out for both cultivars at room temperature.Results exhibited that Riogrand showed higher firmness and less weight loss than SalarF1.The ethylene production was higher in SalarF1,compared with Riogrand during post-harvest storages.We performed transcriptomic analysis of both cultivars in different storage stages.We discovered 2913,2188,and 11,119 differentially expressed genes(DEGs)for three post-harvest stages(0,20,and 40 Days Post-Harvest(DPH)),respectively.These genes are enriched in ethylene biosynthesis and response,as well as cell wall-related genes.Ethylene response factor(ERF)ERF2 and ERF4 were highly expressed in SalarF1 with a short shelf life in 40 DPH,and the ethylene biosynthetic genes ACO1,ACO4,ACS6,and ACS2 were significantly upregulated in SalarF1.Regarding cell wall loosening and cell wall-related genes XTH3,XTH7,XTH23,1,3;1,4-β-D-Gluc-like,pGlcT1,Cellulase,PGH1,PL5,PL-like 1,PL-like 2 exhibited the highest levels of significance,being notably upregulated in the last stage of SalarF1.The quantitative real-time polymerase chain reaction(qRT-PCR)analysis validated these gene expressions,which is in line with the transcriptome analysis.The findings suggested that the extension of tomato fruit shelf life is mostly dependent on ethylene biosynthesis,signaling pathway genes,cell wall loosening,and cell wall-associated genes.
基金financially supported by the National Natural Science Foundation of China(52274295)Hebei Province Science and Technology Research and Development Platform Special Innovation Capability Enhancement Plan Project(24464402D)+3 种基金the Fundamental Research Funds for the Central Universities(N2423051,N2423005)the Science and Technology Project of Hebei Education Department(QN2024238)The Basic Research Program Project of Shijiazhuang City for Universities Stationed in Hebei Province(241790937A)2025 Hebei Provincial Post-graduate Student Innovation Ability Training Funding Project(CXZZBS2025202,CXZZSS2025157)。
文摘Magnesium-air(Mg-air)batteries have emerged as a promising sustainable energy storage technology,offering exceptional theoretical energy density,low cost,and environmental compatibility.Despite these advantages,their development remains largely confined to experimental phase.A critical barrier to commercialization is the poor corrosion resistance of the anode resulting in low anodic efficiency.This article presents a comprehensive review of strategies aimed at improving the utilization efficiency of Mg anodes,with a particular focus on addressing corrosion issues from a microstructural standpoint.Firstly,the principle of Mg-air batteries has been outlined and the corrosion behavior has been discussed.The review then delves into a variety of representative anode materials.Special attention is given to innovative material designs that mitigate the challenges typically encountered by Mg-air batteries.Finally,the paper provides an outlook on future research directions,identifying critical technological barriers and highlighting areas that warrant further investigation.By offering a detailed analysis of material structures,this article aims to contribute valuable insights for advancing the development of high-performance Mg-air batteries.
基金support from the National Key R&D Program of China(Grant No.2023YFE0111500)the National Natural Science Foundation of China(Grant No.52321006,T2394480,T2394484,22109143,22479131)+8 种基金Beijing National Laboratory for Molecular Sciences(BNLMS-CXXM-202005)the China Postdoctoral Innovative Talent Support Program(Grant No.BX2021271)the China Postdoctoral Science Foundation(2022M712851)the Opening Project of State Key Laboratory of Advanced Technology for Float Glass(Grant No.2022KF04)Graduate Education Reform Project of Henan Province(Grant No.2023SJGLX136Y)Key R&D Special Program of Henan Province(Grant No.241111242000)Program for Science and Technology Innovation Talents in Universities of Henan Province(Grant No.25HASTIT005)Training Plan for Young Backbone Teachers of Zhengzhou University(Grant No.2023ZDGGJS017)the Joint Research Project of Puyang Shengtong Juyuan New Materials Co.,Ltd.(Grant No.20230128A).
文摘Organic-inorganic hybrid perovskite solar cells achieve remarkable efficiencies(>26%)yet face stability challenges.Quasi-2D alternating-cation-interlayer perovskites offer enhanced stability through hydrophobic spacer cations but suffer from vertical phase segregation and buried interface defects.Herein,we introduce dicyanodiamide(DCD)to simultaneously address these dual limitations in GA(MA)_(n)Pb_(n)I_(3n+1)perovskites.The guanidine group in DCD passivates undercoordinated Pb^(2+)and MA^(+)vacancies at the perovskite/TiO_(2)interface,while cyano groups eliminate oxygen vacancies in TiO_(2)via Ti^(4+)-CN coordination,reducing interfacial trap density by 73%with respect to the control sample.In addition,DCD regulates crystallization kinetics,suppressing low-n-phase aggregation and promoting vertical alignment of high-n phases,which benefit for carrier transport.This dual-functional modification enhances charge transport and stabilizes energy-level alignment.The optimized devices achieve a record power conversion efficiency of 21.54%(vs.19.05%control)and retain 94%initial efficiency after 1200 h,outperforming unmodified counterparts(84%retention).Combining defect passivation with phase homogenization,this work establishes a molecular bridge strategy to decouple stability-efficiency trade-offs in low-dimensional perovskites,providing a universal framework for interface engineering in high-performance optoelectronics.
文摘低维钙钛矿太阳能电池(Low-Dimensional Perovskite Solar Cells,LD PSCs)是一种稳定性好、疏水性强的新型钙钛矿光伏器件,在新能源领域受到了广泛的关注。本实验以领域内的前沿进展为出发点,提供丁胺(Butylammonium,BA)离子、半胱氨酸(2-氨基-3-巯基丙酸,Cysteine,Cys)离子作为有机间隔阳离子,合成了低维钙钛矿晶体并制备出以(BA)2(MA)n-1PbnI3n+1或(Cys)2(MA)n-1PbnI3n+1为活性层的钙钛矿太阳能电池,并通过X射线衍射检测、紫外-可见吸收检测等手段对产品进行表征,之后测定了钙钛矿器件的能量转换效率。本实验难度适中,涉及光伏器件的制备与表征,旨在激励本科生对前沿光电研究产生兴趣、培养其科研能力。
基金supported financially by the National Key R&D Program of China (Nos. 2018YFA0208501 and 2018YFA0703200)the National Natural Science Foundation of China (NSFC, Nos. 52103236, 91963212, 21875260)Beijing National Laboratory for Molecular Sciences (No. BNLMSCXXM-202005)。
文摘Multifunctional photodetectors boost the development of traditional optical communication technology and emerging artificial intelligence fields, such as robotics and autonomous driving. However, the current implementation of multifunctional detectors is based on the physical combination of optical lenses, gratings, and multiple photodetectors, the large size and its complex structure hinder the miniaturization, lightweight, and integration of devices. In contrast, perovskite materials have achieved remarkable progress in the field of multifunctional photodetectors due to their diverse crystal structures, simple morphology manipulation, and excellent optoelectronic properties. In this review, we first overview the crystal structures and morphology manipulation techniques of perovskite materials and then summarize the working mechanism and performance parameters of multifunctional photodetectors. Furthermore, the fabrication strategies of multifunctional perovskite photodetectors and their advancements are highlighted, including polarized light detection, spectral detection, angle-sensing detection, and selfpowered detection. Finally, the existing problems of multifunctional detectors and the perspectives of their future development are presented.
基金funded by the National Natural Science Foundation of China(No.32001112)the Natural Science Foundation of Hebei Province,China(Nos.C2020204169 and C2023204238)。
文摘Forest trees can establish symbiotic associations with dark septate endophytes(DSEs)and ectomycorrhizal fungi(ECMF)simultaneously.However,the combined effects of these two fungi on the growth and cadmium(Cd)tolerance of host plants remain largely unexplored.To address this knowledge gap,a pot experiment was conducted to examine the effects of the interaction between an ECMF strain(Suillus granulatus)and a DSE strain(Pseudopyrenochaeta sp.)on Pinus tabulaeformis under Cd stress,by assessing plant growth and physiological parameters,nutrient uptake,and soil properties.Notably,the colonization rates of both fungal strains were found to increase in response to Cd stress,with the extent of this increase being influenced by the specific fungal species and the Cd level in the soil.Compared to the non-inoculation treatment,single inoculation with fungal strain resulted in enhanced biomass,root development,and nutrient contents in P.tabulaeformis seedlings under Cd stress.Furthermore,a synergistic effect was observed when these seedlings were co-inoculated with S.granulatus and Pseudopyrenochaeta sp.,as indicated by significantly greater measurements in various indicators compared to both the single and non-inoculation treatments.Fungal inoculation effectively regulated the antioxidant defense responses and photosynthesis of P.tabulaeformis seedlings subjected to Cd stress,particularly in the co-inoculation treatment.In addition,fungal inoculation facilitated the Cd accumulation in P.tabulaeformis,suggesting a promising potential for the implementation of bioremediation strategies in the areas contaminated with heavy metals.The findings from this study indicate that the utilization of root symbiotic fungi obtained from stress environments could potentially enhance the growth performance and tolerance of P.tabulaeformis towards heavy metals,and co-inoculation of both fungal groups may result in even more pronounced synergistic effects on the overall fitness of the plant.
基金Project supported by the National Key Research and Development Program of China(Grant No.2017YFA0304203)the Chang Jiang Scholars and Innovative Research Team in the University of the Ministry of Education of China(Grant No.IRT13076)+2 种基金the National Natural Science Foundation of China(Grant Nos.61722507,61675121,61705123,and 11434007)the Fund for Shanxi 1331 Project Key Subjects Construction,Chinathe Applied Basic Research Project of Shanxi Province,China(Grant No.201701D221002)
文摘We study the influence of external magnetic field on the shift of the resonant frequency in the photoassociation of ultracold Cs atoms, which are captured in a magnetically levitated optical crossed dipole trap. With the increase of the photoassociation laser intensity, the linear variation of the frequency shift is measured by recording the photoassociation spectra of the long-range 0_u^+ state of Cs molecule below the 6S_(1/2)+ 6P_(1/2) dissociation limit at different magnetic fields.The slope of the frequency shift to the intensity of the photoassociation laser exhibits a strong dependence on the external magnetic field. The experimental data is simulated with an analytic theory model, in which a single channel rectangular potential with the tunable well depth is introduced to acquire the influence of the magnetic field on the atomic behavior in the effective range where photoassociation occurs.
基金financially National Natural Science Foundation of China (NSFC) (52274295)Natural Science Foundation of Hebei Province (E2021501029, E2020501001, A2021501007, E2022501028, E2022501029)+11 种基金Natural Science Foundation - Steel and Iron Foundation of Hebei Province (No. E2022501030)Fundamental Research Funds for the Central Universities (No. N2323025, N2323013, N2302016, N2223009, N2223010, N2123035, N2023040)Performance subsidy fund for Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province (22567627H)Science and Technology Project of Hebei Education Department (ZD2022158)2023 Hebei Provincial doctoral candidate Innovation Ability training funding project (CXZZBS2023163)2023 Hebei Provincial Postgraduate Student Innovation Ability training funding project (CXZZSS2023195)Central Guided Local Science and Technology Development Fund Project of Hebei province (226Z4401G)The Fundamental Research Funds for the Central Universities (N2423052)Hebei Provincial Doctoral Candidate Innovation Ability Training Funding Project(CXZZBS2024176)The Science and Technology Project of Qinhuangdao City (202302B006)Science and Technology Project of Hebei Education Department (ZD2022158 and QN2024238)The Basic Research Project of Shijiazhuang City。
文摘Rechargeable metal-ion batteries, such as lithium-ion batteries(LIBs) and sodium-ion batteries(SIBs),have raised more attention because of the large demand for energy storage solutions. Undoubtedly, electrode materials and electrolytes are key parts of batteries, exhibiting critical influence on the reversible capacity and span life of the metal-ion battery. Nonetheless, researchers commonly express concerns regarding the stability of both electrodes and electrolytes. Given its commendable stability attributes,high-entropy materials have garnered widespread acclaim and have been applied in many fields since their inception, notably in energy storage. However, while certain high-entropy designs have achieved substantial breakthroughs, some have failed to meet anticipated outcomes within the high energy density energy storage materials. Moreover, there is a lack of comprehensive summary research on the corresponding mechanisms and design principles of high-entropy designs. This review examines the current high-entropy designs for cathodes, anodes, and electrolytes, aiming to summarize the design principle,potential mechanisms, and electrochemical performance. We focus on their structural characteristics,interface characteristics, and prospective development trends. At last, we provide a fair evaluation along-side succinct development suggestions.
文摘Single event latch-up (SEL) is a significant issue for electronics design in space application, which would cause large currents in electronic devices, and may lead to burning out of devices. A new monitoring circuit based on current-comparing method is designed to protect the electronics away from SEL’s damage in radiation environment. The response time of protection circuit has been analyzed. The signal simulation results indicated that the operating time of the SEL protection circuit is dependent on the action time of current comparator and system application recovery time. The function of the monitoring circuit protection device away from SEL’s damage has validated through experiment at last.
基金funded by the Science Foundation of Chongqing(Grant No.cstc2020jcyj-msxmX0914)the Informatization Plan of the Chinese Academy of Sciences(Grant No.CAS-WX2021PY-0101)the Specialized Re-search Fund for State Key Laboratories.
文摘A concentric gravity wave event was captured by a photographer in NagarzêCounty(90.28°N,28.33°E)between 02:00 and 04:00(local time)on May 11,2019.This concentric gravity wave event was also observed by the Suomi National Polar-orbiting Partnership satellite and the all-sky airglow imager at Yangbajing station(90.5°E,30.1°N).The temporal and spatial information on gravity waves from the photographs provided a rare opportunity to study the propagation of gravity waves over the Tibetan Plateau.According to wind and temperature data from the MERRA-2 reanalysis(Modern-Era Retrospective analysis for Research and Applications,Version 2)and empirical models(NRLMSISE-00[Naval Research Laboratory Mass Spectrometer and Incoherent Scatter Radar Exosphere]and HWM[horizontal wind model]),we inversely derived the propagation trajectory from the observed wave pattern to the source region by using the ray-tracing method.The source of the concentric gravity wave was identified as deep convection in Bangladesh(90.6°E,25.0°N).The maximum background wind speed in the propagation direction(31.05 m/s)was less than the phase speed of 53 m/s,which is consistent with the wind-filtering theory.
基金financially supported by a project of the Ministry of Science and Technology,SINOPEC(No.P13071)a project of the Petroleum Exploration and Production Research Institute,SINOPEC(No.YK514003).
文摘Drilling for karst hydrothermal resources in eastern China has posed challenges,including disparities between the temperature and yield of geothermal water.It is evident that relying solely on geothermal anomalies or indications of karst reservoirs is inadequate for the exploration of karst hydrothermal resources.This study seeks to elucidate the cause of geothermal sweet spots by analyzing the interplay between geothermal anomalies and karst reservoirs and the underlying geological conditions for karst hydrothermal enrichment.Key findings include:(1)the Bohai Bay Basin has been geologically favorable for the development of karst hydrothermal resources since the Mesozoic era;(2)the karst hydrothermal enrichment varies significantly between the basin’s margin and its interior.On the basin margin,the enrichment is largely driven by groundwater activity and faults,particularly where faults facilitate the upwelling of geothermal water.In contrast,within the basin’s interior,karst hydrothermal resources are predominantly influenced by buried hills and are especially enriched in areas facilitating the discharge of deep geothermal waters.
基金supported by the National Key R&D Program of China(2023YFE0111500)the National Natural Science Foundation of China(52321006,T2394480,T2394484,22109143,22475196,and 22479131)+9 种基金the Joint Fund for Provincial Science and Technology R&D Program of Henan(242301420051)the Opening Project of the State Key Laboratory of Advanced Technology for Float Glass(2022KF04)the China Postdoctoral Innovative Talent Support Program(BX2021271)the China Postdoctoral Science Foundation(2022M712851)the Graduate Education Reform Project of Henan Province(2023SJGLX136Y)the Key R&D Special Program of Henan Province(241111242000)the Program for Science&Technology Innovation Talents in Universities of Henan Province(25HASTIT005)the Henan Provincial Excellent Youth Science Foundation(252300421172)the Training Plan for Young Backbone Teachers of Zhengzhou University(2023zDGGJS017)and the Joint Research Project of Puyang Shengtong Juyuan New Materials Co.,Ltd.(20230128A).
文摘Perovskite tandem solar cells(TSCs)hold substantial promise for surpassing the efficiency limits of single-junction solar cells.Nevertheless,achieving high open-circuit voltage(VOC)in wide-bandgap perovskite devices remains a challenge due to significant VOC-losses.Here,we introduce a heterogeneous interface anchoring strategy aimed at enhancing interfacial properties by incorporating a silane coupling agent between the perovskite and hole transport layers.Trimethoxysilane(TMOS),an amphiphilic molecule,strengthens interfacial adhesion through enhanced chemical interactions,thereby promoting efficient hole extraction.Additionally,the terminal functional groups of TMOS molecules interact with lead ions,modulating the perovskite film crystallization and improving their overall quality.Devices treated with TMOS exhibit a marked reduction in non-radiative recombination,leading to a significant increase in VOC.Notably,3-cyanopropyltrimethoxysilane(CN-TMOS)optimizes the uniformity and interfacial contact of the perovskite film,achieving a VOC of 1.345 V and a power conversion efficiency(PCE)of 19.69%.The corresponding VOC-loss,relative to the bandgap,is reduced to 0.425 V,one of the lowest values reported for wide-bandgap perovskite single-junction solar cells.Extending this strategy to all-perovskite TSCs,we achieve a PCE of 28.45%and exceptional operational stability,retaining over 90%of the initial efficiency after 500 h of continuous operation under 1 sun illumination.
基金support from the National Natural Science Foundation of China(NSFC)(51673091,51833004,and 51425304)NSFC-Guangdong Joint funding(U1801256)+2 种基金support from the National Key R&D Program of China(2018YFA0208501)the National Natural Science Foundation of China(51803217,91963212,51961145102,and 51773206)K.C.Wong Education Foundation。
文摘The power conversion effciency(PCE)of flexible perovskite solar cells(PSCs)has increased rapidly,while the mechanical flexibility and environmental stability are still far from satisfactory.Previous studies show the environmental degradation and ductile cracks of perovskite films usually begin at the grain boundaries(GBs).Herein,sulfonated graphene oxide(s-GO)is employed to construct a cementitious GBs by interacting with the[Pb I6]4–at GBs.The resultant s-GO-[Pb I6]4–complex can effectively passivate the defects of vacant iodine,and the devices with s-GO exhibit remarkable waterproofness and flexibility due to the tough and water-insoluble GBs.The champion PCE of 20.56%(1.01 cm^(2))in a device treated with s-GO is achieved.This device retains 90%of its original PCE after 180 d stored in the ambient condition,as well as over 80%retention after 10,000 bending cycles at a curvature radius of 3 mm.
文摘For maximum utilization of solar energy,photovoltaic(PV)power systems should be operated at the maximum power point(MPP)which can be achieved using maximum power point tracking(MPPT)methods.However,the occurrence of multi-peak on P-V curve of a PV array due to the changing environmental conditions such as being partially shaded increases the complexity of the tracking process.The global MPP cannot always be achieved by the conventional MPPT methods.Therefore a novel MPPT method for PV systems using flower pollination(FP)algorithm is proposed in this paper and the Levy flight is used to improve the convergence of FP algorithm.MPPT model of the PV system is established in MATLAB to verify the effectiveness of the proposed method,and the proposed method is compared with two well established MPPT methods.The simulation results indicate that the proposed MPPT method can quickly track the changes in external environment and effectively handle the partially shaded condition.
基金the financial support of the National Key R&D Program of China(grant no.2018YFA0208501)the National Natural Science Foundation of China(grant nos.51803217,51773206,91963212,2210090429,62104216,and 51961145102[BRICS project])+6 种基金Beijing National Laboratory for Molecular Sciences(grant nos.BNLMS-CXXM-202005 and 2019BMS20003)the K.C.Wong Education Foundationthe Beijing National Laboratory for Molecular Sciences(grant no.BNLMSCXXM-202005)the Key R&D and Promotion Project of Henan Province(grant no.192102210032)the Open Project of State Key Laboratory of Silicon Materials(grant no.SKL2019-10)the China Postdoctoral Innovative Talent Support Program(grant no.BX2021271)the Outstanding Young Talent Research Fund of Zhengzhou University.
文摘Emerging organic–inorganic metal halide perovskite materials have become the focus of the optoelectronics research community owing to their excellent photoelectric properties.Nevertheless,challenges still exist for transferring the lab-made devices to largearea industrial modules.Inkjet printing(IJP)technology provides a promising way to fill the gap because of its precise droplet control and uniform large-scale deposition functions.Hence,an in-depth understanding of inkjet-printed perovskite films in terms of droplet manipulation and crystallization regulation is critical for upscaling the perovskite devices to commercial usage.In this review,we give an overview of inkjet-printed high-quality perovskite films and provide guidelines on inkjet-printing large-scale highperformance perovskite devices.First,we analyze theories of droplet formation and perovskite nucleation/crystallization dynamics and then focus on summarizing the perovskite film-formation strategies via IJP,in the aspects of ink engineering,the printing process,and posttreatment.Furthermore,we review the recent advances of inkjet-printed perovskite films on optoelectronic devices,such as perovskite solar cells,perovskite light-emitting diodes,and perovskite photodetectors.Finally,we highlight the“Trilogy Strategies,”including ink engineering,printing process,and posttreatment for printing high-quality perovskite films.
