Three types of NdFeB magnets with the same composition and different grain sizes were prepared,and then the grain boundary diffusion was conducted using metal Tb under the same technical parameters.The effect of grain...Three types of NdFeB magnets with the same composition and different grain sizes were prepared,and then the grain boundary diffusion was conducted using metal Tb under the same technical parameters.The effect of grain size on the grain boundary diffusion process and properties of sintered NdFeB magnets was investigated.The diffusion process was assessed using X-ray diffractometer,field emission scanning electron microscope,and electron probe microanalyzer.The magnetic properties of the magnet before and after diffusion were investigated.The results show that the grain refinement of the magnet leads to higher Tb utilization efficiency and results in higher coercivity at different temperatures.It can be attributed to the formation of a deeper and more complete core-shell structure,resulting in better magnetic isolation and higher anisotropy of the Nd_(2)Fe_(14)B grains.This work may shed light on developing high coercivity with low heavy rare earth elements through grain refinement.展开更多
基金Key Research and Development Program of Shandong Province(2021CXGC010310)Shandong Province Science and Technology Small and Medium Sized Enterprise Innovation Ability Enhancement Project(2023TSGC0287,2024TSGC0519)+1 种基金Shandong Provincial Natural Science Foundation(ZR2022ME222)National Natural Science Foundation of China(51702187)。
文摘Three types of NdFeB magnets with the same composition and different grain sizes were prepared,and then the grain boundary diffusion was conducted using metal Tb under the same technical parameters.The effect of grain size on the grain boundary diffusion process and properties of sintered NdFeB magnets was investigated.The diffusion process was assessed using X-ray diffractometer,field emission scanning electron microscope,and electron probe microanalyzer.The magnetic properties of the magnet before and after diffusion were investigated.The results show that the grain refinement of the magnet leads to higher Tb utilization efficiency and results in higher coercivity at different temperatures.It can be attributed to the formation of a deeper and more complete core-shell structure,resulting in better magnetic isolation and higher anisotropy of the Nd_(2)Fe_(14)B grains.This work may shed light on developing high coercivity with low heavy rare earth elements through grain refinement.
