A new Ag(I)complex based on tris(2-pyridyl)phosphine(Py_(3)P),[Ag_(2)(Py_(3)P)_(3)(SCN)_(2)],has been synthesized and chemically characterized.Theoretical calculations and photophysical investigations reveal thermally...A new Ag(I)complex based on tris(2-pyridyl)phosphine(Py_(3)P),[Ag_(2)(Py_(3)P)_(3)(SCN)_(2)],has been synthesized and chemically characterized.Theoretical calculations and photophysical investigations reveal thermally activated delayed fluorescence(TADF)coupled with outstanding solvato-and vapor-luminescent behavior.展开更多
基金supported by Russian Science Foundation(Project 18-73-10086).
文摘A new Ag(I)complex based on tris(2-pyridyl)phosphine(Py_(3)P),[Ag_(2)(Py_(3)P)_(3)(SCN)_(2)],has been synthesized and chemically characterized.Theoretical calculations and photophysical investigations reveal thermally activated delayed fluorescence(TADF)coupled with outstanding solvato-and vapor-luminescent behavior.