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电解锰渣固废制备建筑保温材料实验研究
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作者 李洪强 陈治平 +4 位作者 钱想想 蔡澄汉 刘甜甜 彭逸喆 刘丽芳 《湖南大学学报(自然科学版)》 北大核心 2025年第9期174-188,共15页
针对当前电解锰渣固废的资源化利用不足、工艺复杂、经济附加值较低等问题,为有效消纳和利用电解锰渣,在前期理论分析基础上采用实验的方法,研究了基础原料配比(电解锰渣的质量与电解锰渣及粉煤灰的质量和之比)、碱激发剂配比(水玻璃、... 针对当前电解锰渣固废的资源化利用不足、工艺复杂、经济附加值较低等问题,为有效消纳和利用电解锰渣,在前期理论分析基础上采用实验的方法,研究了基础原料配比(电解锰渣的质量与电解锰渣及粉煤灰的质量和之比)、碱激发剂配比(水玻璃、氢氧化钠和混合水的用量配比)、发泡剂和稳泡剂的种类与用量等因素对目标保温材料性能的影响.结果表明:基础原料配比和碱激发剂配比均会对SiO_(2)/Al_(2)O_(3)摩尔比、SiO_(2)/Na_(2)O摩尔比和水灰比产生影响,进而影响试样的力学性能;基础原料配比为0.7、SiO_(2)/Al_(2)O_(3)摩尔比为4.0、SiO_(2)/Na_(2)O摩尔比为2.5、水灰比为0.5时建筑结构材料试样的力学性能最优,其抗压强度为11.15 MPa,密度为1476 kg/m^(3);发泡剂和稳泡剂的种类与用量会对试样的各项性能产生影响,当发泡剂为双氧水,用量为4~6 g,稳泡剂为实验室自制稳泡剂,用量为2 g时,建筑保温材料试样的各项性能最优,其导热系数为0.104~0.131 W/(m·K),抗压强度为0.69~1.49 MPa,密度为433~533 kg/m^(3),成本为1294~1722元/m^(3).该研究为较大量消纳和利用电解锰渣提供了新思路,在满足保温隔热性能的同时降低建筑能源需求,经进一步优化后具有一定的工程应用价值. 展开更多
关键词 固体废弃物 电解锰渣 粉煤灰 保温材料 建筑节能
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基于地表水环境容量的湖南工业废水铊污染物排放控制研究 被引量:21
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作者 彭逸喆 黄凤莲 +3 位作者 姜苹红 罗琳 杨远 彭克俭 《生态环境学报》 CSCD 北大核心 2020年第10期2070-2080,共11页
根据水环境功能区划中流域水控制单元的划分和相应的水质保护目标,调查了湖南省湘、资、沅、澧四大流域工业用水功能区各控制单元相应集水区内的典型涉铊污染源,统计各控制单元含铊工业废水入河量。选择模型计算各控制单元铊污染物水环... 根据水环境功能区划中流域水控制单元的划分和相应的水质保护目标,调查了湖南省湘、资、沅、澧四大流域工业用水功能区各控制单元相应集水区内的典型涉铊污染源,统计各控制单元含铊工业废水入河量。选择模型计算各控制单元铊污染物水环境容量。按照容量总量管理兼顾目标总量管理的模式,提出各控制单元铊污染物排放的总量控制方案,计算该总量控制方案下工业废水铊污染物的最大允许排放量。湖南省四大水系中,铊污染物最大允许排放量的最低值出现在湘江长沙段,代码为湘长-033至湘长-038的控制单元,铊污染物最大允许排放量为0.0002 mg·L^−1;最高值出现在湘潭的湘江涓水,代码为湘湘118的控制单元,铊污染物最大允许排放量为0.98 mg·L^−1。按照“功能分区、污染物分类、标准分级、生产分期”的原则,在经济、技术合理并确保90%以上的控制单元满足地表水环境容量的前提下,通过水质模型建立水环境容量和废水排放量之间的换算关系,反向推算到工业企业铊污染物的排放控制要求。综合考虑人体健康、生态安全、水质达标等多个方面,厘定0.005 mg·L^−1为工业废水铊污染物排放标准,对工业废水铊污染物的直接排放和间接排放实行控制,从而实现水环境的目标管理。通过与国内外同类标准的比较与分析,评估了该标准约束下,当地的环境与经济效益。可判断,这种基于地表水环境容量且兼顾目标总量管理的铊污染物排放标准的厘定方法是科学的、合理的。 展开更多
关键词 铊污染物 水环境容量 排放限值
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Experimental Research on a Feasible Building Insulation Material Based Reed in China
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作者 LIU Tiantian peng yizhe +3 位作者 LIU Lifang CAI Chenghan WANG Shuang LI Hongqiang 《Journal of Thermal Science》 2025年第1期176-187,共12页
The seemingly useless reeds are prepared as thermal insulation materials,which not only meet the requirements of environmental sustainability but also enhance the added value of reeds,creating new economic benefits.Th... The seemingly useless reeds are prepared as thermal insulation materials,which not only meet the requirements of environmental sustainability but also enhance the added value of reeds,creating new economic benefits.The hydrophobicity of raw biomass surfaces leads to problems such as weak bonding strength and non-dense structure in the formed materials,as well as issues related to the residual insect infestations on the surface.In this study,reed straw was used as the raw material,and foamed geopolymer was used as the binder to prepare building insulation materials based reed.To improve the interfacial adhesion performance between reed straw and foamed geopolymer,a thermochemical modification method-thermal carbonization,was proposed.In this study,the mechanical properties and hydraulic properties of the studied materials with different degrees of surface thermal modification were tested,especially the fire resistance performance,and weathering resistance performance rarely found in published literature.When the surface thermal modification condition of reed straw was 250℃(30 min),the comprehensive performance of reed-based building insulation materials was the best,when the studied material density was 321.3 kg/m^(3);the compressive strength was 0.59 MPa;the thermal conductivity was 0.101 W/(m·K);the pH was 11.27;the moisture absorption rate was 25.1%,and the compressive strength loss rate in wet-dry cycles was 18.5%.In addition,it had excellent fire resistance performance and weathering resistance performance.This new material can be widely used to improve the thermal insulation of traditional buildings and as sandwich filler in prefabricated buildings,such as preparing insulating walls. 展开更多
关键词 pre-treatment of reeds interface adhesion properties building insulation material based reed fire resistance performance weathering resistance performance
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Preparation of Building Insulation Materials from Electrolytic Manganese Residue for Solid Waste Disposal
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作者 CHEN Zhiping LI Hongqiang +5 位作者 LIU Tiantian peng yizhe LIU Lifang ZHAO Li CAI Chenghan XU Faxi 《Journal of Thermal Science》 2025年第5期1879-1911,共33页
In addressing the challenges of solid waste disposal, this study proposed to utilize electrolytic manganese residue to produce building insulation materials. The research focused on the factors such as precursor mater... In addressing the challenges of solid waste disposal, this study proposed to utilize electrolytic manganese residue to produce building insulation materials. The research focused on the factors such as precursor material ratio, alkali activator ratio, foaming agent and foam stabilizer on the target insulation materials properties. The findings indicated that SiO_(2)/Al_(2)O_(3) molar ratio, SiO_(2)/Na_(2)O molar ratio, and liquid/solid mass ratio impact the mechanical properties of the samples. The best mechanical performance of building structural material samples was characterized by a compressive strength of 11.15 MPa and a density of 1476 kg/m3. The optimal properties for building insulation materials were a thermal conductivity of 0.131–0.104 W/(m·K), compressive strength of 1.49–0.69 MPa, and density of 533–433 kg/m^(3), with a cost of 1722–1294 CNY/m^(3). This research provides a new approach for large-scale electrolytic manganese residue utilization while enhancing insulation performance and reducing energy consumption in buildings, with promising prospects for further engineering development. 展开更多
关键词 solid waste disposal electrolytic manganese residue fly ash insulation materials building energy conservation
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Experimental Study on a Feasible Bio-Insulation Material for Buildings Taken Reed and Raw Soil as Resources
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作者 LIU Anye LI Hongqiang +3 位作者 CAI Chenghan peng yizhe LIU Lifang BAI Chengying 《Journal of Thermal Science》 2025年第4期1314-1327,共14页
In response to the challenges posed by the transformation of China's reed industry,leading to difficulties in reed utilization,and the significant increment in raw soil from the expansion of urban infrastructure,t... In response to the challenges posed by the transformation of China's reed industry,leading to difficulties in reed utilization,and the significant increment in raw soil from the expansion of urban infrastructure,the authors proposed a novel method of coupling reed with raw soil to produce an ecological building insulation material.The aim is to enhance the thermal comfort of rural buildings and achieve building energy saving.The research has applied theoretical and experimental methods as the core means of exploration for key factors in the preparation of the novel ecological insulation material.These factors include raw soil content and curing methods.Key performance indicators such as thermal insulation,mechanical properties,fire resistance,water resistance,moisture resistance,and acoustic performance have been utilized for evaluation.The research results indicate that the proposed process and method for the preparation of the ecological insulation material effectively utilize reed and raw soil,achieving excellent multi-target performance.When the content of raw soil is in the range of 0-40%,the material's thermal conductivity ranges from 0.097 W/(m·K)to 0.104 W/(m·K),compressive strength from0.70 MPa to 0.79 MPa,water absorption rate from 29.42%to 38.95%,moisture absorption rate from 13.33%to31.48%,and the maximum sound absorption coefficient is 0.80,with a maximum sound insulation of 56.66 dB.Additionally,a non-combustible A-grade fire resistance was achieved.To expand the application space and scope of the novel material,the research team further explored on-site construction material preparation processes and conducted experimental research,focusing on the key aspect of the"curing process".The low temperature curing method of industrial heating blanket was proposed.The research results indicated that the method is feasible.At an environmental temperature of 25℃,with different curing times and curing temperatures,the material's thermal conductivity ranges from 0.089 W/(m·K)to 0.109 W/(m·K),and the compressive strength is between 0.14 MPa and 0.70 MPa,meeting the relevant parameter requirements.This research opens up avenues for other types of biomass with high economic added value applications and can be directly applied to improving the thermal environment of residential buildings,contributing to building energy saving,rural revitalization,and the implementation of dual-carbon strategies in China. 展开更多
关键词 reed resource utilization raw soil application ecological insulation material rural building energy efficiency solid waste transformation
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固废制备新型建筑保温材料实验研究
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作者 李洪强 彭逸喆 +4 位作者 陈治平 刘丽芳 钱想想 蔡澄汉 赵岩志 《湖南大学学报(自然科学版)》 2025年第11期164-177,共14页
针对固体废弃物资源化利用中存在的消纳量小、成本较高、工艺复杂等问题,提出一种消纳量大、成本较低、工艺简单的建筑保温材料制备方案.该方案以电解锰渣和粉煤灰两种固体废弃物作为硅铝酸盐原料,以水玻璃作为碱激发剂,采用双氧水发泡... 针对固体废弃物资源化利用中存在的消纳量小、成本较高、工艺复杂等问题,提出一种消纳量大、成本较低、工艺简单的建筑保温材料制备方案.该方案以电解锰渣和粉煤灰两种固体废弃物作为硅铝酸盐原料,以水玻璃作为碱激发剂,采用双氧水发泡工艺,制备出保温、力学性能优异,且成本较低的材料.结果表明,水玻璃用量在一定范围内材料可以制备成型,且能够有效稳泡.电解锰渣的掺入量范围为0%~60%,推荐掺入量为30%,最高掺入量为60%.当电解锰渣掺入量为30%、水玻璃用量为355.4~465.4 g、双氧水用量为8 g、稳泡剂用量为2 g时,导热系数为0.084~0.093 W·m^(-1)·K^(-1),抗压强度为0.92~1.43 MPa,密度为457~475 kg·m^(-3),制备每立方米新型保温材料所需原料成本约为750元.与采用偏高岭土作为前驱材料,氢氧化钠和水玻璃作为碱激发剂的同类保温材料相比,新型建筑保温材料成本仅为其24%左右.此外,该新型建筑保温材料毒液浸出浓度低,对重金属有良好的固化作用. 展开更多
关键词 固废 电解锰渣 粉煤灰 建筑保温材料 成本
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