The reaction of[RuHCl(CO)(PPh_(3))_(3)]with an equimolar amount of salicylaldehyde-4(N)-methylthiosemicarbazone[H_(2)-(Sal-mtsc)]resulted in two entities,namely[Ru(H-Sal-mtsc)Cl(CO)(PPh_(3))_(2)](1)and[Ru(Salmtsc)(CO)...The reaction of[RuHCl(CO)(PPh_(3))_(3)]with an equimolar amount of salicylaldehyde-4(N)-methylthiosemicarbazone[H_(2)-(Sal-mtsc)]resulted in two entities,namely[Ru(H-Sal-mtsc)Cl(CO)(PPh_(3))_(2)](1)and[Ru(Salmtsc)(CO)(PPh_(3))_(2)](2)from a single tub.展开更多
基金support received from the Department of Science and Technology(DST),India and the Council of Science and Industrial Research(CSIR),New Delhi is gratefully acknowledged.
文摘The reaction of[RuHCl(CO)(PPh_(3))_(3)]with an equimolar amount of salicylaldehyde-4(N)-methylthiosemicarbazone[H_(2)-(Sal-mtsc)]resulted in two entities,namely[Ru(H-Sal-mtsc)Cl(CO)(PPh_(3))_(2)](1)and[Ru(Salmtsc)(CO)(PPh_(3))_(2)](2)from a single tub.
