A new compound Na_(5)Mn_(4)(PO_(4))_(4)F_(4)·2H_(2)O was successfully obtained,featuring a typical channel structure composed of rarely mixed valence Mn^(2+)/Mn^(3+)spin chains and PO_(4) tetrahedra,where H_(2)O ...A new compound Na_(5)Mn_(4)(PO_(4))_(4)F_(4)·2H_(2)O was successfully obtained,featuring a typical channel structure composed of rarely mixed valence Mn^(2+)/Mn^(3+)spin chains and PO_(4) tetrahedra,where H_(2)O molecules are located inside the channels.Magnetic measurements show that this compound possesses successive multiple magnetic transitions at low temperature.展开更多
基金financially supported by the National Natural Science Foundation of China(NSFC)(no.22175173).
文摘A new compound Na_(5)Mn_(4)(PO_(4))_(4)F_(4)·2H_(2)O was successfully obtained,featuring a typical channel structure composed of rarely mixed valence Mn^(2+)/Mn^(3+)spin chains and PO_(4) tetrahedra,where H_(2)O molecules are located inside the channels.Magnetic measurements show that this compound possesses successive multiple magnetic transitions at low temperature.