A Schiff base type ligand with the combination of the julolidine and the quinoline groups has been reported as a potential chemosensor in detecting the cobalt(II)ion among other heavy and transition metal ions in solu...A Schiff base type ligand with the combination of the julolidine and the quinoline groups has been reported as a potential chemosensor in detecting the cobalt(II)ion among other heavy and transition metal ions in solution.However,no crystal structure of such a ligand with any metal ions has been reported.In this work,its complexation with 3d transition metal ions(Mn(II),Co(II),Ni(II),Cu(II)and Zn(II))has been investigated with five new complexes being synthesised,and spectroscopically and structurally characterised.展开更多
基金the Western Sydney University Postgraduate Research Award and LL thanks the receipt of an Australian Postgraduate Award and the Western Sydney University Top-up AwardNDS thanks the AINSE Honours Scholarship Program.The crystallographic data collection for complexes 1–5 was undertaken on the MX1 beamline at the Australian Synchrotron,Victoria,Australia,through a collaborative access program(AS143MXCAP8503).
文摘A Schiff base type ligand with the combination of the julolidine and the quinoline groups has been reported as a potential chemosensor in detecting the cobalt(II)ion among other heavy and transition metal ions in solution.However,no crystal structure of such a ligand with any metal ions has been reported.In this work,its complexation with 3d transition metal ions(Mn(II),Co(II),Ni(II),Cu(II)and Zn(II))has been investigated with five new complexes being synthesised,and spectroscopically and structurally characterised.
