Gas-boriding in N2-H2-BCl3 atmosphere resulted in the formation of a thick layer on Inconel 600 alloy.The microstructure of layer produced at 920℃for 2 h consisted of a mixture of chromium borides and nickel borides....Gas-boriding in N2-H2-BCl3 atmosphere resulted in the formation of a thick layer on Inconel 600 alloy.The microstructure of layer produced at 920℃for 2 h consisted of a mixture of chromium borides and nickel borides.The objective of investigations was to determine the influence of the chemical and phase compositions of borided layer on its mechanical properties.The nanoindentation was carried out using Berkovich diamond tip under a load of 50 m N.The gas-borided layer was characterized by high indentation hardness HIT from 1542.6 HV to 2228.7 HV and high elastic modulus EIT from 226.9 to 296.4 GPa.It was found that the mixture with higher percentage of chromium borides was the reason for the increase in HIT and EIT values.The fracture toughness(KC)was measured using Vickers microindentation technique under a load of 0.98 N.The presence of high compressive stresses in normal direction to the top surface caused the strong anisotropy of the borided layer,in respect of fracture toughness.The high difference between the lowest(0.5763 MPa·m^1/2)and the highest(4.5794 MPa·m^1/2)fracture toughness was obtained.This situation was caused by the differences in chemical and phase compositions of tested areas,presence of porosity and residual stresses.Generally,the higher KC values were obtained in areas with lower chromium content.展开更多
The two-stage gas boriding in N_(2)−H_(2)−BCl_(3)atmosphere was applied to producing a two-zoned borided layer on Nisil-alloy.The process was carried out at 910℃ for 2 h.The microstructure consisted of two zones diff...The two-stage gas boriding in N_(2)−H_(2)−BCl_(3)atmosphere was applied to producing a two-zoned borided layer on Nisil-alloy.The process was carried out at 910℃ for 2 h.The microstructure consisted of two zones differing in their phase composition.The outer layer contained only a mixture of nickel borides(Ni_(2)B,Ni_(3)B)only.The inner zone contained additionally nickel silicides(Ni_(2)Si,Ni_(3)Si)occurring together with nickel borides.The aim of this study was to determine the presence of nickel silicides on the mechanical properties of the borided layer produced on Ni-based alloy.The hardness and elastic modulus were measured using the nanoindenter with a Berkovich diamond tip under a load of 50 mN.The average values of indentation hardness(HI)and indentation elastic modulus(E_(I))obtained in the outer zone were respectively(16.32±1.03)GPa and(232±16.15)GPa.The presence of nickel silicides in the inner zone reduced the indentation hardness(6.8−12.54 GPa)and elastic modulus(111.79−153.99 GPa).The fracture toughness of the boride layers was investigated using a Vickers microindentation under a load of 0.981 N.It was confirmed that the presence of nickel silicides caused an increase in brittleness(by about 40%)of the gas-borided layer.展开更多
Laser alloying was used for production of thick layers on surface of Nimonic 80A-alloy.For laser surface modification,three types of pre-coated pastes were applied:with amorphous boron,with amorphous boron and molybde...Laser alloying was used for production of thick layers on surface of Nimonic 80A-alloy.For laser surface modification,three types of pre-coated pastes were applied:with amorphous boron,with amorphous boron and molybdenum as well as with amorphous boron and niobium.The microstructure,hardness and wear resistance of produced layers were studied in details.The presence of different types of borides in re-melted zone depended on the paste composition and caused an increase in hardness up to about HV 1000.The wear resistance was evaluated by calculation of mass wear intensity factor Imw and relative mass loss of specimen and counter-specimen.The wear behavior of the tested frictional pairs was determined by 3D interference microscopy,scanning electron microscopy equipped with EDS microanalyzer.The significant increase in abrasive wear resistance was observed in comparison to untreated Nimonic 80A-alloy.The lowest mass loss intensity factor was characteristic of laser-alloyed Nimonic 80A-alloy with boron and niobium(Imw=1.234 mg/(cm2?h)).Laser alloyed-layers indicated abrasive wear mechanism with clearly visible grooves.Laser alloying with boron and niobium resulted in the additional oxidative wear mechanism.In this case,EDS patterns revealed presence of oxygen on the worn surface of specimen.展开更多
基金financially supported by Ministry of ScienceHigher Education in Poland as a part of the “02/24/DSPB” Project
文摘Gas-boriding in N2-H2-BCl3 atmosphere resulted in the formation of a thick layer on Inconel 600 alloy.The microstructure of layer produced at 920℃for 2 h consisted of a mixture of chromium borides and nickel borides.The objective of investigations was to determine the influence of the chemical and phase compositions of borided layer on its mechanical properties.The nanoindentation was carried out using Berkovich diamond tip under a load of 50 m N.The gas-borided layer was characterized by high indentation hardness HIT from 1542.6 HV to 2228.7 HV and high elastic modulus EIT from 226.9 to 296.4 GPa.It was found that the mixture with higher percentage of chromium borides was the reason for the increase in HIT and EIT values.The fracture toughness(KC)was measured using Vickers microindentation technique under a load of 0.98 N.The presence of high compressive stresses in normal direction to the top surface caused the strong anisotropy of the borided layer,in respect of fracture toughness.The high difference between the lowest(0.5763 MPa·m^1/2)and the highest(4.5794 MPa·m^1/2)fracture toughness was obtained.This situation was caused by the differences in chemical and phase compositions of tested areas,presence of porosity and residual stresses.Generally,the higher KC values were obtained in areas with lower chromium content.
基金This work has been financially supported by Ministry of Science and Higher Education in Poland as a part of the Project No.0513/SBAD.
文摘The two-stage gas boriding in N_(2)−H_(2)−BCl_(3)atmosphere was applied to producing a two-zoned borided layer on Nisil-alloy.The process was carried out at 910℃ for 2 h.The microstructure consisted of two zones differing in their phase composition.The outer layer contained only a mixture of nickel borides(Ni_(2)B,Ni_(3)B)only.The inner zone contained additionally nickel silicides(Ni_(2)Si,Ni_(3)Si)occurring together with nickel borides.The aim of this study was to determine the presence of nickel silicides on the mechanical properties of the borided layer produced on Ni-based alloy.The hardness and elastic modulus were measured using the nanoindenter with a Berkovich diamond tip under a load of 50 mN.The average values of indentation hardness(HI)and indentation elastic modulus(E_(I))obtained in the outer zone were respectively(16.32±1.03)GPa and(232±16.15)GPa.The presence of nickel silicides in the inner zone reduced the indentation hardness(6.8−12.54 GPa)and elastic modulus(111.79−153.99 GPa).The fracture toughness of the boride layers was investigated using a Vickers microindentation under a load of 0.981 N.It was confirmed that the presence of nickel silicides caused an increase in brittleness(by about 40%)of the gas-borided layer.
基金financially supported within the project "Engineer of the Future.Improving the didactic potential of the Poznan University of Technology"-POKL.04.03.00-00-259/12,implemented within the Human Capital Operational Programme,co-financed by the European Union within the European Social Fundby Ministry of Science and Higher Education in Poland as a part of the 02/24/DSPB project
文摘Laser alloying was used for production of thick layers on surface of Nimonic 80A-alloy.For laser surface modification,three types of pre-coated pastes were applied:with amorphous boron,with amorphous boron and molybdenum as well as with amorphous boron and niobium.The microstructure,hardness and wear resistance of produced layers were studied in details.The presence of different types of borides in re-melted zone depended on the paste composition and caused an increase in hardness up to about HV 1000.The wear resistance was evaluated by calculation of mass wear intensity factor Imw and relative mass loss of specimen and counter-specimen.The wear behavior of the tested frictional pairs was determined by 3D interference microscopy,scanning electron microscopy equipped with EDS microanalyzer.The significant increase in abrasive wear resistance was observed in comparison to untreated Nimonic 80A-alloy.The lowest mass loss intensity factor was characteristic of laser-alloyed Nimonic 80A-alloy with boron and niobium(Imw=1.234 mg/(cm2?h)).Laser alloyed-layers indicated abrasive wear mechanism with clearly visible grooves.Laser alloying with boron and niobium resulted in the additional oxidative wear mechanism.In this case,EDS patterns revealed presence of oxygen on the worn surface of specimen.
