The design and fabrication of high toughness electromagnetic interference(EMI)shielding composite films with diminished reflection are an imperative task to solve electromagnetic pollution problem.Ternary MXene/ANF(ar...The design and fabrication of high toughness electromagnetic interference(EMI)shielding composite films with diminished reflection are an imperative task to solve electromagnetic pollution problem.Ternary MXene/ANF(aramid nanofibers)–MoS_(2)composite films with nacre-like layered structure here are fabricated after the introduction of MoS_(2)into binary MXene/ANF composite system.The introduction of MoS_(2)fulfills an impressive“kill three birds with one stone”improvement effect:lubrication toughening mechanical performance,reduction in secondary reflection pollution of electromagnetic wave,and improvement in the performance of photothermal conversion.After the introduction of MoS_(2)into binary MXene/ANF(mass ratio of 50:50),the strain to failure and tensile strength increase from 22.1±1.7%and 105.7±6.4 MPa and to 25.8±0.7%and 167.3±9.1 MPa,respectively.The toughness elevates from 13.0±4.1 to 26.3±0.8 MJ m^(−3)(~102.3%)simultaneously.And the reflection shielding effectiveness(SE_(R))of MXene/ANF(mass ratio of 50:50)decreases~10.8%.EMI shielding effectiveness(EMI SE)elevates to 41.0 dB(8.2–12.4 GHz);After the introduction of MoS_(2)into binary MXene/ANF(mass ratio of 60:40),the strain to failure increases from 18.3±1.9%to 28.1±0.7%(~53.5%),the SE_(R)decreases~22.2%,and the corresponding EMI SE is 43.9 dB.The MoS_(2)also leads to a more efficient photothermal conversion performance(~45 to~55℃).Additionally,MXene/ANF–MoS_(2)composite films exhibit excellent electric heating performance,quick temperature elevation(15 s),excellent cycle stability(2,2.5,and 3 V),and long-term stability(2520 s).Combining with excellent mechanical performance with high MXene content,electric heating performance,and photothermal conversion performance,EMI shielding ternary MXene/ANF–MoS_(2)composite films could be applied in many industrial areas.This work broadens how to achieve a balance between mechanical properties and versatility of composites in the case of high-function fillers.展开更多
The high power density and intelligence of next-generation flexible electronic devices bring many challenges to fabricate flexible composite films with electromagnetic interference(EMI)shielding effectiveness(SE)prope...The high power density and intelligence of next-generation flexible electronic devices bring many challenges to fabricate flexible composite films with electromagnetic interference(EMI)shielding effectiveness(SE)property and excellent toughness via a simple method.Herein,inspired by the layered structure and biopolymer matrix networks in natural nacre,nacre-like layered Ti_(3)C2TX(MXene)/aramid nanofiber(ANF)films were fabricated through sol-gel,vacuum-assisted filtration,and hot-pressing.Three-dimensional(3D)interconnected aramid nanofibers networks between adjacent layered MXene result in an ultralong strain-to-failure of the film.Even though the functional filler MXene contents are as high as 60 wt.%and 70 wt.%,the strain-to-failure of the films could reach astonishing values of 18.34%±1.86%and 14.43%±1.26%,respectively.And the tensile strength could maintain about 85 MPa.Excitingly,with such a high filler,the film can also withstand double folding and vigorous rubbing without damage,which could better adapt to a harsh application environment.The result means that this work provides a convenient way to prepare other high functional filler composite films with excellent mechanical performance.The EMI SE values could reach 45 and 52.15 dB at 60 wt.%and 70 wt.%MXene in 8.2–12.4 GHz.Meanwhile,the films have prominent Joule heating properties,high sensitivity(<15 s),small voltage operation(0.5 V),and high operation constancy(1300 s).Therefore,nacre-inspired MXene/ANF composite films in this work have ability to apply in many areas including communication technology,military,and aerospace.展开更多
基金supported by the Talent Fund of Beijing Jiaotong University(No,2023XKRC015)the National Natural Science Foundation of China(Nos.52172081,52073010 and 52373259).
文摘The design and fabrication of high toughness electromagnetic interference(EMI)shielding composite films with diminished reflection are an imperative task to solve electromagnetic pollution problem.Ternary MXene/ANF(aramid nanofibers)–MoS_(2)composite films with nacre-like layered structure here are fabricated after the introduction of MoS_(2)into binary MXene/ANF composite system.The introduction of MoS_(2)fulfills an impressive“kill three birds with one stone”improvement effect:lubrication toughening mechanical performance,reduction in secondary reflection pollution of electromagnetic wave,and improvement in the performance of photothermal conversion.After the introduction of MoS_(2)into binary MXene/ANF(mass ratio of 50:50),the strain to failure and tensile strength increase from 22.1±1.7%and 105.7±6.4 MPa and to 25.8±0.7%and 167.3±9.1 MPa,respectively.The toughness elevates from 13.0±4.1 to 26.3±0.8 MJ m^(−3)(~102.3%)simultaneously.And the reflection shielding effectiveness(SE_(R))of MXene/ANF(mass ratio of 50:50)decreases~10.8%.EMI shielding effectiveness(EMI SE)elevates to 41.0 dB(8.2–12.4 GHz);After the introduction of MoS_(2)into binary MXene/ANF(mass ratio of 60:40),the strain to failure increases from 18.3±1.9%to 28.1±0.7%(~53.5%),the SE_(R)decreases~22.2%,and the corresponding EMI SE is 43.9 dB.The MoS_(2)also leads to a more efficient photothermal conversion performance(~45 to~55℃).Additionally,MXene/ANF–MoS_(2)composite films exhibit excellent electric heating performance,quick temperature elevation(15 s),excellent cycle stability(2,2.5,and 3 V),and long-term stability(2520 s).Combining with excellent mechanical performance with high MXene content,electric heating performance,and photothermal conversion performance,EMI shielding ternary MXene/ANF–MoS_(2)composite films could be applied in many industrial areas.This work broadens how to achieve a balance between mechanical properties and versatility of composites in the case of high-function fillers.
基金Financial support from the Talent Fund of Beijing Jiaotong University(No,2023XKRC015)the National Natural Science Foundation of China(No.52172081)is gratefully acknowledged.
文摘The high power density and intelligence of next-generation flexible electronic devices bring many challenges to fabricate flexible composite films with electromagnetic interference(EMI)shielding effectiveness(SE)property and excellent toughness via a simple method.Herein,inspired by the layered structure and biopolymer matrix networks in natural nacre,nacre-like layered Ti_(3)C2TX(MXene)/aramid nanofiber(ANF)films were fabricated through sol-gel,vacuum-assisted filtration,and hot-pressing.Three-dimensional(3D)interconnected aramid nanofibers networks between adjacent layered MXene result in an ultralong strain-to-failure of the film.Even though the functional filler MXene contents are as high as 60 wt.%and 70 wt.%,the strain-to-failure of the films could reach astonishing values of 18.34%±1.86%and 14.43%±1.26%,respectively.And the tensile strength could maintain about 85 MPa.Excitingly,with such a high filler,the film can also withstand double folding and vigorous rubbing without damage,which could better adapt to a harsh application environment.The result means that this work provides a convenient way to prepare other high functional filler composite films with excellent mechanical performance.The EMI SE values could reach 45 and 52.15 dB at 60 wt.%and 70 wt.%MXene in 8.2–12.4 GHz.Meanwhile,the films have prominent Joule heating properties,high sensitivity(<15 s),small voltage operation(0.5 V),and high operation constancy(1300 s).Therefore,nacre-inspired MXene/ANF composite films in this work have ability to apply in many areas including communication technology,military,and aerospace.
