Compared with traditional rain gauges and weather radars,hydrogel flexible electronic sensor capable of responding directly to rainfall events with promptness and authenticity,shows great prospects in real-time rainfa...Compared with traditional rain gauges and weather radars,hydrogel flexible electronic sensor capable of responding directly to rainfall events with promptness and authenticity,shows great prospects in real-time rainfall monitoring.Aluminum coordination hydrogel(Al-HG),one of the most qualified sensors suitable for rainfall monitoring,however,is currently impeded from widespread application by its weak mechanical properties due to the low binding strength between Al^(3+)and functional ligands.Herein,inspired by the antifreeze proteins(AFPs)that protect those Patagonian toothfishes by strongly binding to ice crystals at freezing temperatures,a low temperature-induced strategy is introduced to promote more and stronger ligand carboxyls firm combination with Al^(3+),thus forming a high-coordinated structure to deal with this challenge.Expectedly,the whole mechanical performance of the product Al-HG_(F1/F2) obtained by the low temperature-induced strategy is improved.For example,the tensile fracture toughness and the maximum compressive stress of Al-HG_(F1/F2) are 1.66 MJ·m^(-3) and 12.01 MPa,approximately twice those of the sample Al-HGF3/F0 obtained by traditional soaking method(0.86 MJ·m^(-3) and 7.38 MPa,respectively).Coupled with its good biocompatibility,ionic conductivity,and sensing ability,Al-HG_(F1/F2) demonstrates promising application for real-time rainfall monitoring in discrepant rainfall intensities,different zones,and even under extreme environments.This work aims to offer a stride toward mechanically robust aluminum coordination hydrogel sensors for real-time rainfall monitoring as well as provide insights into flood prevention and disaster mitigation.展开更多
In recent years,water evaporation-induced electricity has attracted a great deal of attention as an emerging green and renewable energy harvesting technology.Although abundant materials have been developed to fabricat...In recent years,water evaporation-induced electricity has attracted a great deal of attention as an emerging green and renewable energy harvesting technology.Although abundant materials have been developed to fabricate hydrovoltaic devices,the limitations of high costs,inconvenient storage and transport,low environmental benefits,and unadaptable shape have restricted their wide applications.Here,an electricity generator driven by water evaporation has been engineered based on natural biomass leather with inherent properties of good moisture permeability,excellent wettability,physicochemical stability,flexibility,and biocompatibility.Including numerous nano/microchannels together with rich oxygen-bearing functional groups,the natural leather-based water evaporator,Leather_(Emblic-NPs-SA/CB),could continuously produce electricity even staying outside,achieving a maximum output voltage of∼3 V with six-series connection.Furthermore,the leather-based water evaporator has enormous potential for use as a flexible self-powered electronic floor and seawater demineralizer due to its sensitive pressure sensing ability as well as its excellent photothermal conversion efficiency(96.3%)and thus fast water evaporation rate(2.65 kg m^(−2)h^(−1)).This work offers a new and functional material for the construction of hydrovoltaic devices to harvest the sustained green energy from water evaporation in arbitrary ambient environments,which shows great promise in their widespread applications.展开更多
基金supported by the National Natural Science Foundation of China(22308210)the Young Talent Fund of the Association for Science and Technology in Shaanxi of China(20240412)+1 种基金the RIKEN-MOST Project between the Ministry of Science and Technology of the People’s Republic of China(MOST)and RIKEN,the China Scholarship Council(202108610127)the Natural Science Foundation of Shaanxi University of Science&Technology(2019BT-44).
文摘Compared with traditional rain gauges and weather radars,hydrogel flexible electronic sensor capable of responding directly to rainfall events with promptness and authenticity,shows great prospects in real-time rainfall monitoring.Aluminum coordination hydrogel(Al-HG),one of the most qualified sensors suitable for rainfall monitoring,however,is currently impeded from widespread application by its weak mechanical properties due to the low binding strength between Al^(3+)and functional ligands.Herein,inspired by the antifreeze proteins(AFPs)that protect those Patagonian toothfishes by strongly binding to ice crystals at freezing temperatures,a low temperature-induced strategy is introduced to promote more and stronger ligand carboxyls firm combination with Al^(3+),thus forming a high-coordinated structure to deal with this challenge.Expectedly,the whole mechanical performance of the product Al-HG_(F1/F2) obtained by the low temperature-induced strategy is improved.For example,the tensile fracture toughness and the maximum compressive stress of Al-HG_(F1/F2) are 1.66 MJ·m^(-3) and 12.01 MPa,approximately twice those of the sample Al-HGF3/F0 obtained by traditional soaking method(0.86 MJ·m^(-3) and 7.38 MPa,respectively).Coupled with its good biocompatibility,ionic conductivity,and sensing ability,Al-HG_(F1/F2) demonstrates promising application for real-time rainfall monitoring in discrepant rainfall intensities,different zones,and even under extreme environments.This work aims to offer a stride toward mechanically robust aluminum coordination hydrogel sensors for real-time rainfall monitoring as well as provide insights into flood prevention and disaster mitigation.
基金supported by the National Natural Science Foundation of China(22308210)the Scientific Research Program Funded by Shaanxi Provincial Education Department(23JK0350)+3 种基金the Open Foundation of Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry,Ministry of Education,and Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and Technology,Shaanxi University of Science and Technology(KFKT2021-12)the Opening Project of Key Laboratory of Leather Chemistry and Engineering(Sichuan University),Ministry of Education(2022)the RIKEN-MOST Project between the Ministry of Science and Technology of the People's Republic of China(MOST)and RIKEN,the China Scholarship Council(202108610127)the Natural Science Foundation of Shaanxi University of Science&Technology(2019BT-44).
文摘In recent years,water evaporation-induced electricity has attracted a great deal of attention as an emerging green and renewable energy harvesting technology.Although abundant materials have been developed to fabricate hydrovoltaic devices,the limitations of high costs,inconvenient storage and transport,low environmental benefits,and unadaptable shape have restricted their wide applications.Here,an electricity generator driven by water evaporation has been engineered based on natural biomass leather with inherent properties of good moisture permeability,excellent wettability,physicochemical stability,flexibility,and biocompatibility.Including numerous nano/microchannels together with rich oxygen-bearing functional groups,the natural leather-based water evaporator,Leather_(Emblic-NPs-SA/CB),could continuously produce electricity even staying outside,achieving a maximum output voltage of∼3 V with six-series connection.Furthermore,the leather-based water evaporator has enormous potential for use as a flexible self-powered electronic floor and seawater demineralizer due to its sensitive pressure sensing ability as well as its excellent photothermal conversion efficiency(96.3%)and thus fast water evaporation rate(2.65 kg m^(−2)h^(−1)).This work offers a new and functional material for the construction of hydrovoltaic devices to harvest the sustained green energy from water evaporation in arbitrary ambient environments,which shows great promise in their widespread applications.
