In this study, aluminum-doped zinc oxide(AZO) thin films were deposited onto a low-temperature polyethylene terephthalate(PET) substrate using DC magnetron sputtering. Deposition parameters included power range of 100...In this study, aluminum-doped zinc oxide(AZO) thin films were deposited onto a low-temperature polyethylene terephthalate(PET) substrate using DC magnetron sputtering. Deposition parameters included power range of 100-300 W, a working pressure of 15 mTorr, and a substrate temperature of 50 ℃. Post-deposition, flash lamp annealing(FLA) was employed as a rapid thermal processing method with a pulse duration of 1.7 ms and energy density of 7 J·cm-2, aimed at enhancing the film's quality while preserving the temperature-sensitive PET substrate. FLA offers advantages over conventional annealing,including shorter processing times and improved material properties. The structural, optical, and electrical characteristics of the AZO films were assessed using X-ray diffraction, field emission scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy, ultraviolet-visible spectroscopy, and Hall effect measurements. The results demonstrated that properties of AZO films varied with deposition and annealing conditions. Films deposited at 200 W and subjected to FLA exhibited superior crystallinity, with average visible light transmittance exceeding 80% and resistivity as low as 0.38 Ω·cm representing 95%improvement in transmittance. Electrical analysis revealed that carrier concentration, mobility, and resistivity were influenced by both sputtering and annealing parameters. These findings underscore the effectiveness of FLA in optimizing AZO thin film properties, highlighting potential in optoelectronics applications.展开更多
Polychloroprene (PC) based contact adhesives are widely used in various applications;however, there is a possibility to improve the properties of PC adhesive. Modifications of polymers can enhance the properties of th...Polychloroprene (PC) based contact adhesives are widely used in various applications;however, there is a possibility to improve the properties of PC adhesive. Modifications of polymers can enhance the properties of the material, e.g. increase in thermal stability, compatibility, rigidity, physical response, flexibility and improve the polymer process ability. In the current study, improved formulation of solvent-based adhesive was developed, and the properties were further enhanced by the addition of nano-reinforcement of multiwall carbon nanotubes (MWCNTs). The addition of nano-reinforcement was optimized to obtain improvement in the bond strength and also to enhance its resistance at a high temperature (~100<span style="white-space:nowrap;">°</span>C). This paper discusses the uniform dispersion of MWCNTs during the synthesis of polychloroprene solvent-based adhesive, thereby improving its structural properties. Incorporation of MWCNTs-solvent-based adhesives resulted in a 20% - 35% improvement in 180<span style="white-space:nowrap;">°</span> peel strength determined on flexible substrates such as canvas, leather. The reinforced based adhesive also exhibited improved thermal stability and weather resistance compared with unreinforced adhesive. The MWCNTs- solvent-based contact adhesives is a potential candidate in an industrially relevant branch of adhesives commonly used in structural applications, e.g., footwear, plastic, leather, automobile, construction industries, etc.展开更多
基金supported by the MOTIE (Ministry of Trade,Industry,and Energy)in Korea,under the Fostering Global Talents for Innovative Growth Program (P0017308)supervised by the Korea Institute for Advancement of Technology (KIAT)+1 种基金supported by the MSIT (Ministry of Science and ICT),Korea,under the ITRC (Information Technology Research Center)support program (IITP-2024-2020-0-01655)supervised by the IITP (Institute of Information and Communications Technology Planning and Evaluation).
文摘In this study, aluminum-doped zinc oxide(AZO) thin films were deposited onto a low-temperature polyethylene terephthalate(PET) substrate using DC magnetron sputtering. Deposition parameters included power range of 100-300 W, a working pressure of 15 mTorr, and a substrate temperature of 50 ℃. Post-deposition, flash lamp annealing(FLA) was employed as a rapid thermal processing method with a pulse duration of 1.7 ms and energy density of 7 J·cm-2, aimed at enhancing the film's quality while preserving the temperature-sensitive PET substrate. FLA offers advantages over conventional annealing,including shorter processing times and improved material properties. The structural, optical, and electrical characteristics of the AZO films were assessed using X-ray diffraction, field emission scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy, ultraviolet-visible spectroscopy, and Hall effect measurements. The results demonstrated that properties of AZO films varied with deposition and annealing conditions. Films deposited at 200 W and subjected to FLA exhibited superior crystallinity, with average visible light transmittance exceeding 80% and resistivity as low as 0.38 Ω·cm representing 95%improvement in transmittance. Electrical analysis revealed that carrier concentration, mobility, and resistivity were influenced by both sputtering and annealing parameters. These findings underscore the effectiveness of FLA in optimizing AZO thin film properties, highlighting potential in optoelectronics applications.
文摘Polychloroprene (PC) based contact adhesives are widely used in various applications;however, there is a possibility to improve the properties of PC adhesive. Modifications of polymers can enhance the properties of the material, e.g. increase in thermal stability, compatibility, rigidity, physical response, flexibility and improve the polymer process ability. In the current study, improved formulation of solvent-based adhesive was developed, and the properties were further enhanced by the addition of nano-reinforcement of multiwall carbon nanotubes (MWCNTs). The addition of nano-reinforcement was optimized to obtain improvement in the bond strength and also to enhance its resistance at a high temperature (~100<span style="white-space:nowrap;">°</span>C). This paper discusses the uniform dispersion of MWCNTs during the synthesis of polychloroprene solvent-based adhesive, thereby improving its structural properties. Incorporation of MWCNTs-solvent-based adhesives resulted in a 20% - 35% improvement in 180<span style="white-space:nowrap;">°</span> peel strength determined on flexible substrates such as canvas, leather. The reinforced based adhesive also exhibited improved thermal stability and weather resistance compared with unreinforced adhesive. The MWCNTs- solvent-based contact adhesives is a potential candidate in an industrially relevant branch of adhesives commonly used in structural applications, e.g., footwear, plastic, leather, automobile, construction industries, etc.
