A discrete[Ce(L1)(NO_(3))_(3)](1;L1=macrocyclic Schiff base ligand)complex exhibits both ferroelectricity and magnetic bistability together,which is extremely rare and challenging to achieve.The presence of the Second...A discrete[Ce(L1)(NO_(3))_(3)](1;L1=macrocyclic Schiff base ligand)complex exhibits both ferroelectricity and magnetic bistability together,which is extremely rare and challenging to achieve.The presence of the Second Harmonic Generation(SHG)signal in 1 implies the presence of a non-centrosymmetric space/point group associated with this complex.The ferroelectric phase transition temperature in 1 is observed at room temperature(_(3)0_(3)K),which is confirmed by dielectric measurements.Switching the spontaneous polarization in 1 requires a low external electric field(2 V).展开更多
基金funding agencies(SERB(CRG/2019/004185),SPR/2019/001145,CSIR(01(2933)/18/EMR-II)and IIT Bombay)for the financial support.
文摘A discrete[Ce(L1)(NO_(3))_(3)](1;L1=macrocyclic Schiff base ligand)complex exhibits both ferroelectricity and magnetic bistability together,which is extremely rare and challenging to achieve.The presence of the Second Harmonic Generation(SHG)signal in 1 implies the presence of a non-centrosymmetric space/point group associated with this complex.The ferroelectric phase transition temperature in 1 is observed at room temperature(_(3)0_(3)K),which is confirmed by dielectric measurements.Switching the spontaneous polarization in 1 requires a low external electric field(2 V).
