Organic dye pollutants present in wastewater pose a significant global challenge.Among pollutants,the synthetic dye Rhodamine B(RB)stands out due to its non-biodegradable nature and associated neurotoxic,carcinogenic,...Organic dye pollutants present in wastewater pose a significant global challenge.Among pollutants,the synthetic dye Rhodamine B(RB)stands out due to its non-biodegradable nature and associated neurotoxic,carcinogenic,and respiratory irritant properties.Extensive research has been conducted on the efficacy of adsorption and photodegradation techniques for the removal of RB from wastewater.While adsorption and advanced oxidation processes(AOPs)have gained considerable attention for their effectiveness in recent years,the underlying behaviors and mechanisms of these technologies remain incompletely understood.Therefore,a comprehensive of recent research progress in this domain is imperative to clarify the basics and present the up-to-date achievements.This review provides an in-depth exploration of the fundamentals,advancements,and future trajectories of RB wastewater treatment technologies,mainly encompassing adsorption and photodegradation.This work starts with a general introduction of outlining the sources,toxicity,and diverse applicable removal strategies.Subsequently,it thoroughly examines crucial techniques within non-photochemical,photochemical,and adsorption technologies,such as UV light assisted AOP,catalyst assisted AOP,ozonation,Fenton system,electrochemical AOP,and adsorption technology.The primary objective is to furnish a broad overview of these techniques,elucidating their effectiveness,limitations,and applicability.Following this,the review encapsulates state-of-theart computational simulations pertaining to RB adsorption and interactions with clays and other adsorbents.Lastly,it delves into column adsorption of RB dye,and elucidates various influencing factors,including bed height,feed concentration,pollutant(RB)feeding or flow rate,and column regeneration.This panoramic review aims to provide valuable insights into suitable techniques,research gaps,and the applicability of nonphotochemical,photochemical,and adsorption technologies in the treatment of wastewater containing RB dye.展开更多
Zinc and cadmium pollutants cause a significant environmental effect that cannot be ignored.Due to their considerable amount in an aqueous environment,industries are seeking suitable adsorbents that are environmentall...Zinc and cadmium pollutants cause a significant environmental effect that cannot be ignored.Due to their considerable amount in an aqueous environment,industries are seeking suitable adsorbents that are environmentally friendly and inexpensive for removing metals from wastewater before disposing of them in surface waters.This research employed original MXene(MX)and chitosan-modified MXene(CSMX)to extract zinc(Zn(Ⅱ))and cadmium(Cd(Ⅱ))metal ions from water-based solutions.The composite material produced was analyzed using techniques such as X-ray Diffraction(XRD),Scanning Electron Microscopy(SEM),Fourier Transform Infrared Spectroscopy(FTIR),and Brunauer-Emmett-Teller(BET).The effects of contact duration,p H of the solution,and initial concentration of metal ions on the adsorption process of Zn(Ⅱ)and Cd(Ⅱ)onto both MX and CSMX composites were investigated.MX and prepared CSMX composite presented a high adsorption capacity for both studied heavy metals,which were 91.55 and 73.82 mg/g for Zn(Ⅱ)and Cd(Ⅱ)onto MX,106.84 and 93.07 mg/g for Cd(Ⅱ)and Zn(Ⅱ)onto CSMX composite,respectively.Furthermore,the maximum competitive adsorption capacities for Zn(Ⅱ)onto MX and CSMX composites are 77.29 and 93.47 mg/g,and for are Cd(Ⅱ)60.30 and 79.66 mg/g,respectively.Hence,the removal capacities for both single and competitive metal ions were superior to CSMX composite.However,the adsorption capacities after five successive regeneration sequences were only dropped by 13.2%for Zn(Ⅱ)and 17.4%for Cd(Ⅱ)onto the CSMX composite compared to the first cycle.These results confirm that both metals could be efficiently terminated from wastewater,which makes the prepared CSMX composite a favorable candidate adsorbent in practical applications.展开更多
文摘Organic dye pollutants present in wastewater pose a significant global challenge.Among pollutants,the synthetic dye Rhodamine B(RB)stands out due to its non-biodegradable nature and associated neurotoxic,carcinogenic,and respiratory irritant properties.Extensive research has been conducted on the efficacy of adsorption and photodegradation techniques for the removal of RB from wastewater.While adsorption and advanced oxidation processes(AOPs)have gained considerable attention for their effectiveness in recent years,the underlying behaviors and mechanisms of these technologies remain incompletely understood.Therefore,a comprehensive of recent research progress in this domain is imperative to clarify the basics and present the up-to-date achievements.This review provides an in-depth exploration of the fundamentals,advancements,and future trajectories of RB wastewater treatment technologies,mainly encompassing adsorption and photodegradation.This work starts with a general introduction of outlining the sources,toxicity,and diverse applicable removal strategies.Subsequently,it thoroughly examines crucial techniques within non-photochemical,photochemical,and adsorption technologies,such as UV light assisted AOP,catalyst assisted AOP,ozonation,Fenton system,electrochemical AOP,and adsorption technology.The primary objective is to furnish a broad overview of these techniques,elucidating their effectiveness,limitations,and applicability.Following this,the review encapsulates state-of-theart computational simulations pertaining to RB adsorption and interactions with clays and other adsorbents.Lastly,it delves into column adsorption of RB dye,and elucidates various influencing factors,including bed height,feed concentration,pollutant(RB)feeding or flow rate,and column regeneration.This panoramic review aims to provide valuable insights into suitable techniques,research gaps,and the applicability of nonphotochemical,photochemical,and adsorption technologies in the treatment of wastewater containing RB dye.
文摘Zinc and cadmium pollutants cause a significant environmental effect that cannot be ignored.Due to their considerable amount in an aqueous environment,industries are seeking suitable adsorbents that are environmentally friendly and inexpensive for removing metals from wastewater before disposing of them in surface waters.This research employed original MXene(MX)and chitosan-modified MXene(CSMX)to extract zinc(Zn(Ⅱ))and cadmium(Cd(Ⅱ))metal ions from water-based solutions.The composite material produced was analyzed using techniques such as X-ray Diffraction(XRD),Scanning Electron Microscopy(SEM),Fourier Transform Infrared Spectroscopy(FTIR),and Brunauer-Emmett-Teller(BET).The effects of contact duration,p H of the solution,and initial concentration of metal ions on the adsorption process of Zn(Ⅱ)and Cd(Ⅱ)onto both MX and CSMX composites were investigated.MX and prepared CSMX composite presented a high adsorption capacity for both studied heavy metals,which were 91.55 and 73.82 mg/g for Zn(Ⅱ)and Cd(Ⅱ)onto MX,106.84 and 93.07 mg/g for Cd(Ⅱ)and Zn(Ⅱ)onto CSMX composite,respectively.Furthermore,the maximum competitive adsorption capacities for Zn(Ⅱ)onto MX and CSMX composites are 77.29 and 93.47 mg/g,and for are Cd(Ⅱ)60.30 and 79.66 mg/g,respectively.Hence,the removal capacities for both single and competitive metal ions were superior to CSMX composite.However,the adsorption capacities after five successive regeneration sequences were only dropped by 13.2%for Zn(Ⅱ)and 17.4%for Cd(Ⅱ)onto the CSMX composite compared to the first cycle.These results confirm that both metals could be efficiently terminated from wastewater,which makes the prepared CSMX composite a favorable candidate adsorbent in practical applications.
