The effect of presence of silver nanoparticles in pure N-methyl-2-pyrrolidone(NMP)solvent for ethylene gas absorption in an experimental pressure decaying setup has been investigated.All experiments were performed at ...The effect of presence of silver nanoparticles in pure N-methyl-2-pyrrolidone(NMP)solvent for ethylene gas absorption in an experimental pressure decaying setup has been investigated.All experiments were performed at temperatures of 278.15 K,298.15 K and 328.15 K and different pressures(up to ethylene dew point)as well as different concentrations of silver nanoparticles(0.05 g·L^(-1) and 0.1 g·L^(-1)).The kinetic data of absorption,Henry’s law constants,and heat of absorption were calculated.Comparison of the pure solvent and the nanofluids absorption results revealed that the presence of small amounts of nanoparticles could improve the absorption performance between 1.5%-18%.Finally,the effect of temperature,pressure,and nanoparticle concentration on the equilibrium results were investigated.展开更多
The electronic and magnetic properties of strontium hexa-ferrite(SrFe12O19)are studied in pure state(SrFe12O19)and with dopant in the positions 2 and 3 of Fe atoms(SrGdFe11O19-I and SrGdFe11O19-Ⅱ,respectively)by util...The electronic and magnetic properties of strontium hexa-ferrite(SrFe12O19)are studied in pure state(SrFe12O19)and with dopant in the positions 2 and 3 of Fe atoms(SrGdFe11O19-I and SrGdFe11O19-Ⅱ,respectively)by utilizing a variety of the density functional theory(DFT)approaches including the Perdew-Burke-Ernzerhof generalized gradient approximation(PBE-GGA)and GGA plus Hubbard U parameter(GGA+U).The pure SrFe12O19 is a hard magnetic half-metal with an integer magnetic moment of 64.00μB,while using the GGA+U functional,the magnetic intensity increases,resulting in a magnetic semiconductor with a high integer magnetic moment of 120μB.By doping the Gd atom in the two different positions of Fe,the magnetic moment is increased to 71.68μB and 68.00μB,respectively.The magnetic moment increases and remains an integer;hence,SrGdFe11O19-Ⅱcan be very useful for application in magnetic memories.Moreover,applying the Hubbard parameter turns SrGdFe11O19-I and SrGdFe11O19-Ⅱto magnetic semiconductors with a magnetic moment of 124μB,and the energy gap of both doped structures at spin down is found to be less than the pure case.By studying the electronic density diagram of the atoms of the crystal,it is found that the major effect to create magnetization in the pure case is due to the Fe atom.However,in the doped case,the elements Gd and Fe have the highest moment in the crystal respectively.展开更多
The studied area is located in 30th km of Bouien-Zahra road in Saveh in southern border of Khiaraj 1:100,000 Geology map rectangle (Danesfahan) in South of Takestan of Iran. This area is a part of volcano-plutonic bel...The studied area is located in 30th km of Bouien-Zahra road in Saveh in southern border of Khiaraj 1:100,000 Geology map rectangle (Danesfahan) in South of Takestan of Iran. This area is a part of volcano-plutonic belt of Urumia-Dokhtar. Rocky outcrops in this area are mainly in two types of volcanic and plutonic. Volcanic Rocks with the age of Eocene are Trachyte to trachyandesite and andesite to basalt-andesite. Plutonic stones with the age of Oligo-Miocene to Miocene are in types of quartz diorite, quartz monzonite, Monzonite and Semi-acidic volcanic domes and granite aplite. Due to having dominant fault systems with trends of NW-SE and NE-SW in an intersectional manner in this area, vein-veinlets Siliciclastic sulfide mineralization can be observed in line with the same faults. Monzonite intrusive rocks are considered as host stone of these mineralizations. The information obtained from field observations and laboratory studies confirms the main alteration along with mineralization in types of silicic and pyrite, sericite, carbonate, argillic and propylitic. Mineralogy Paragenesis in the study area includes Pyrite, chalcopyrite, bornite, colitis, malachite, hematite and goethite and the most important Gang minerals including quartz, calcite, albite, sericite, kaolinite, pyrophyllite, epidote, alunite and jarosite, and according to carried out studies, copper, gold and silver are among mineralizing elements and elements such as molybdenum, cadmium, arsenic and mercury show anomalies as accompanying and guidance elements in some of the samples. The grade of copper in this area in sulfide siliciclastic veins is 1% to 3% and the grade of gold is 130 ppm and the grade of silver is reportable from 0.5 ppm to 6 ppm. Based on the geothermometry studies of fluid inclusions, homogenization temperature from 150°C?to 300°C?and the salinity grade from 4 to 5.5 percent indicate the fact that an epithermal hydrothermal system in final stages controls the mineralization of the area.展开更多
文摘The effect of presence of silver nanoparticles in pure N-methyl-2-pyrrolidone(NMP)solvent for ethylene gas absorption in an experimental pressure decaying setup has been investigated.All experiments were performed at temperatures of 278.15 K,298.15 K and 328.15 K and different pressures(up to ethylene dew point)as well as different concentrations of silver nanoparticles(0.05 g·L^(-1) and 0.1 g·L^(-1)).The kinetic data of absorption,Henry’s law constants,and heat of absorption were calculated.Comparison of the pure solvent and the nanofluids absorption results revealed that the presence of small amounts of nanoparticles could improve the absorption performance between 1.5%-18%.Finally,the effect of temperature,pressure,and nanoparticle concentration on the equilibrium results were investigated.
文摘The electronic and magnetic properties of strontium hexa-ferrite(SrFe12O19)are studied in pure state(SrFe12O19)and with dopant in the positions 2 and 3 of Fe atoms(SrGdFe11O19-I and SrGdFe11O19-Ⅱ,respectively)by utilizing a variety of the density functional theory(DFT)approaches including the Perdew-Burke-Ernzerhof generalized gradient approximation(PBE-GGA)and GGA plus Hubbard U parameter(GGA+U).The pure SrFe12O19 is a hard magnetic half-metal with an integer magnetic moment of 64.00μB,while using the GGA+U functional,the magnetic intensity increases,resulting in a magnetic semiconductor with a high integer magnetic moment of 120μB.By doping the Gd atom in the two different positions of Fe,the magnetic moment is increased to 71.68μB and 68.00μB,respectively.The magnetic moment increases and remains an integer;hence,SrGdFe11O19-Ⅱcan be very useful for application in magnetic memories.Moreover,applying the Hubbard parameter turns SrGdFe11O19-I and SrGdFe11O19-Ⅱto magnetic semiconductors with a magnetic moment of 124μB,and the energy gap of both doped structures at spin down is found to be less than the pure case.By studying the electronic density diagram of the atoms of the crystal,it is found that the major effect to create magnetization in the pure case is due to the Fe atom.However,in the doped case,the elements Gd and Fe have the highest moment in the crystal respectively.
文摘The studied area is located in 30th km of Bouien-Zahra road in Saveh in southern border of Khiaraj 1:100,000 Geology map rectangle (Danesfahan) in South of Takestan of Iran. This area is a part of volcano-plutonic belt of Urumia-Dokhtar. Rocky outcrops in this area are mainly in two types of volcanic and plutonic. Volcanic Rocks with the age of Eocene are Trachyte to trachyandesite and andesite to basalt-andesite. Plutonic stones with the age of Oligo-Miocene to Miocene are in types of quartz diorite, quartz monzonite, Monzonite and Semi-acidic volcanic domes and granite aplite. Due to having dominant fault systems with trends of NW-SE and NE-SW in an intersectional manner in this area, vein-veinlets Siliciclastic sulfide mineralization can be observed in line with the same faults. Monzonite intrusive rocks are considered as host stone of these mineralizations. The information obtained from field observations and laboratory studies confirms the main alteration along with mineralization in types of silicic and pyrite, sericite, carbonate, argillic and propylitic. Mineralogy Paragenesis in the study area includes Pyrite, chalcopyrite, bornite, colitis, malachite, hematite and goethite and the most important Gang minerals including quartz, calcite, albite, sericite, kaolinite, pyrophyllite, epidote, alunite and jarosite, and according to carried out studies, copper, gold and silver are among mineralizing elements and elements such as molybdenum, cadmium, arsenic and mercury show anomalies as accompanying and guidance elements in some of the samples. The grade of copper in this area in sulfide siliciclastic veins is 1% to 3% and the grade of gold is 130 ppm and the grade of silver is reportable from 0.5 ppm to 6 ppm. Based on the geothermometry studies of fluid inclusions, homogenization temperature from 150°C?to 300°C?and the salinity grade from 4 to 5.5 percent indicate the fact that an epithermal hydrothermal system in final stages controls the mineralization of the area.
