A new borosilicate zeolite|N_(2)H_(36)C_(16)|[Si_(22)B_(2)O_(48)]·H_(2)O,denoted as EMM-26,has been synthesized by employing a linear dicationic organic structure directing agent 1,6-bis(N-methylpyrrolidinium)hex...A new borosilicate zeolite|N_(2)H_(36)C_(16)|[Si_(22)B_(2)O_(48)]·H_(2)O,denoted as EMM-26,has been synthesized by employing a linear dicationic organic structure directing agent 1,6-bis(N-methylpyrrolidinium)hexane(OSDA).EMM-26 has a novel zeolite framework and contains two-dimensional(2D)intersecting 10×10-ring channels.Its structure was solved from sub-micrometer sized crystals using rotation electron diffraction(RED)and refined against both the RED and synchrotron powder diffraction data.展开更多
文摘A new borosilicate zeolite|N_(2)H_(36)C_(16)|[Si_(22)B_(2)O_(48)]·H_(2)O,denoted as EMM-26,has been synthesized by employing a linear dicationic organic structure directing agent 1,6-bis(N-methylpyrrolidinium)hexane(OSDA).EMM-26 has a novel zeolite framework and contains two-dimensional(2D)intersecting 10×10-ring channels.Its structure was solved from sub-micrometer sized crystals using rotation electron diffraction(RED)and refined against both the RED and synchrotron powder diffraction data.