Solid surfaces of HOPG, pure copper, chromium, zinc, copper and SUS304 steel were observed in ambient air with an a.c. non-contact mode of atomic force microscope(AFM). A type of film-like-domains (adsorptive) was det...Solid surfaces of HOPG, pure copper, chromium, zinc, copper and SUS304 steel were observed in ambient air with an a.c. non-contact mode of atomic force microscope(AFM). A type of film-like-domains (adsorptive) was detected on the above surfaces. The thickness of the adsorptive was about 1.2-2.4 nm in this case. The film-like-adsorptive was confirmed to be a liquid layer by the static contact-mode scanning, the measurement of the elasticity and viscosity images, and the detection of the condensation/ evaporation phenomena when the relative humidity changed. The liquid layer is considered to be condensed water covered with organic contaminant.展开更多
A simple method was presented to produce a micro-droplet of sulphuric acid on a pre-selected micro-zone on a pure iron surface with the tip of an AFM cantilever. The three-dimensional shape of the droplet was imaged w...A simple method was presented to produce a micro-droplet of sulphuric acid on a pre-selected micro-zone on a pure iron surface with the tip of an AFM cantilever. The three-dimensional shape of the droplet was imaged with the AC non-contact mode of the AFM, and the liquid/solid interface was observed in situ during corrosion using the contact mode. The substrate surface beneath the droplet was lowered by approximately 19 nm after 3.6 ks of adhesion. This method has important implications for experimental studies of micro-zone corrosion or lubrication.展开更多
基金Part of this work was supported by MEXT.HAITEKU, 2004- JSPS Grant-in-Aid for scientific research(18560093)
文摘Solid surfaces of HOPG, pure copper, chromium, zinc, copper and SUS304 steel were observed in ambient air with an a.c. non-contact mode of atomic force microscope(AFM). A type of film-like-domains (adsorptive) was detected on the above surfaces. The thickness of the adsorptive was about 1.2-2.4 nm in this case. The film-like-adsorptive was confirmed to be a liquid layer by the static contact-mode scanning, the measurement of the elasticity and viscosity images, and the detection of the condensation/ evaporation phenomena when the relative humidity changed. The liquid layer is considered to be condensed water covered with organic contaminant.
基金Part of this work was supported by MEXT.HAITEKU, 2004- JSPS Grant-in-Aid for Scientific Research (18560093)
文摘A simple method was presented to produce a micro-droplet of sulphuric acid on a pre-selected micro-zone on a pure iron surface with the tip of an AFM cantilever. The three-dimensional shape of the droplet was imaged with the AC non-contact mode of the AFM, and the liquid/solid interface was observed in situ during corrosion using the contact mode. The substrate surface beneath the droplet was lowered by approximately 19 nm after 3.6 ks of adhesion. This method has important implications for experimental studies of micro-zone corrosion or lubrication.
