The synthesis and characterization of(thiolfan*)Zr(OtBu)_(2)(thiolfan*=1,1’-di(2,4-di-tert-butyl-6-thiophenoxide)ferrocene)is reported,as well as its activity toward the ring-opening polymerizations of L-lactide and...The synthesis and characterization of(thiolfan*)Zr(OtBu)_(2)(thiolfan*=1,1’-di(2,4-di-tert-butyl-6-thiophenoxide)ferrocene)is reported,as well as its activity toward the ring-opening polymerizations of L-lactide andε-caprolactone.展开更多
基金NSF,Grant 1362999 to PLD and CHE-1048804 for NMR spectroscopythe John Simon Guggenheim Memorial Foundation.We thank Jonathan Brosmer,who assisted with the synthesis of the metal complexes,Mark Abubekerov,who assisted with polymer workups,and Junnian Wei,who offered helpful advice for both polymerization reactions and syntheses.
文摘The synthesis and characterization of(thiolfan*)Zr(OtBu)_(2)(thiolfan*=1,1’-di(2,4-di-tert-butyl-6-thiophenoxide)ferrocene)is reported,as well as its activity toward the ring-opening polymerizations of L-lactide andε-caprolactone.
