Ultralong organic phosphorescent materials have invoked considerable attention for their great potential in sensing,data encryption,information anti-counterfeiting and so forth.However,effective ways to achieve highly...Ultralong organic phosphorescent materials have invoked considerable attention for their great potential in sensing,data encryption,information anti-counterfeiting and so forth.However,effective ways to achieve highly efficient ultralong organic phosphorescence(UOP)in metal-free organic materials remain a great challenge.Herein,we designed three isomers based on asymmetric triazines with various bromine substituted positions.Impressively,phosphorescence efficiency of p-BrAT in solid state can reach up to 9.7%with a long lifetime of 386 ms,which was one of the highest efficient UOP materials reported so far.Theoretical calculations further demonstrated that para-substitution exhibited the most effective radiative transition for triplet excitons.These results will provide an effective approach to achieving highly efficient UOP materials.展开更多
Developing ultralong organic phosphorescence(UOP)materials with smart response to external stimuli is of great interest in photonics applications,whereas the manipulation of molecular stacking on tuning such dynamic U...Developing ultralong organic phosphorescence(UOP)materials with smart response to external stimuli is of great interest in photonics applications,whereas the manipulation of molecular stacking on tuning such dynamic UOP is still a formidable challenge.Herein,we have reported two polymorphs with distinct photoactivated dynamic UOP behavior based on a pyridine derivative for the first time.Our experiment revealed that the dynamic UOP behavior including photoactivation and deactivation feature is highly dependent on irradiation intensity and environmental atmosphere.Additionally,given the unique dynamic UOP feature,these phosphors have been successfully applied to phosphorescence-dependent molecular logic gate and timing data storage.This result not only paves a way to design smart functional materials but also expands the scope of the applications on organic phosphorescence materials.展开更多
Ultralong organic phosphorescence(UOP)crystals have attracted increased attention due to the distinct photophysical property of a long-lived lifetime.However,organic crystals are generally brittle,leading to a serious...Ultralong organic phosphorescence(UOP)crystals have attracted increased attention due to the distinct photophysical property of a long-lived lifetime.However,organic crystals are generally brittle,leading to a serious problem for their application in flexible technology.Herein,we report three types of elastic organic crystals(EOCs)with ultralong phosphorescence via introducing halogen atoms(Cl,Br,I)intoπ-conjugated phosphorescent molecules.Especially,the crystal containing iodine atoms displayed both excellent elasticity(ε=3.01%)and high phosphorescent efficiency(Φ_(Ph)=19.1%)owing to the strong halogen bonds.Taking advantage of its highly efficient UOP and excellent elasticity,we successfully used a DCz4I crystal for anti-counterfeiting application.These findings may provide guidance for the development of elastic crystals with afterglow and expand the scope of potential applications on flexible materials.展开更多
基金supported by the National Natural Science Foundation of China(Nos.21875104 and 51673095)National Basic Research Program of China(973 Program,No.2015CB932200)+4 种基金Natural Science Fund for Distinguished Young Scholars(No.BK20180037)the Natural Science Fund for Colleges and Universities(No.17KJB430020)"High-Level Talents in Six Industries"(No.XCL-025)of Jiangsu ProvinceNanjing Tech Start-up Grant(Nos.3983500158 and 3983500169)the High Performance Computing Centre of Nanjing Tech University for supporting the computational resources
文摘Ultralong organic phosphorescent materials have invoked considerable attention for their great potential in sensing,data encryption,information anti-counterfeiting and so forth.However,effective ways to achieve highly efficient ultralong organic phosphorescence(UOP)in metal-free organic materials remain a great challenge.Herein,we designed three isomers based on asymmetric triazines with various bromine substituted positions.Impressively,phosphorescence efficiency of p-BrAT in solid state can reach up to 9.7%with a long lifetime of 386 ms,which was one of the highest efficient UOP materials reported so far.Theoretical calculations further demonstrated that para-substitution exhibited the most effective radiative transition for triplet excitons.These results will provide an effective approach to achieving highly efficient UOP materials.
基金This work is supported by the National Natural Science Foundation of China(21875104,21975120,21973043,51673095,and 91833302)Natural Science Fund for Distinguished Young Scholars of Jiangsu Province(BK20180037).
文摘Developing ultralong organic phosphorescence(UOP)materials with smart response to external stimuli is of great interest in photonics applications,whereas the manipulation of molecular stacking on tuning such dynamic UOP is still a formidable challenge.Herein,we have reported two polymorphs with distinct photoactivated dynamic UOP behavior based on a pyridine derivative for the first time.Our experiment revealed that the dynamic UOP behavior including photoactivation and deactivation feature is highly dependent on irradiation intensity and environmental atmosphere.Additionally,given the unique dynamic UOP feature,these phosphors have been successfully applied to phosphorescence-dependent molecular logic gate and timing data storage.This result not only paves a way to design smart functional materials but also expands the scope of the applications on organic phosphorescence materials.
基金supported by the National Natural Science Foundation of China(21875104,21975120,21973043,9183330461935017,and 51673095)Natural Science Fund for Distinguished Young Scholars of Jiangsu Province(BK20180037)+1 种基金Projects of International Cooperation and Exchanges NSFC(51811530018)the Fundamental Research Funds for the Central Universities。
文摘Ultralong organic phosphorescence(UOP)crystals have attracted increased attention due to the distinct photophysical property of a long-lived lifetime.However,organic crystals are generally brittle,leading to a serious problem for their application in flexible technology.Herein,we report three types of elastic organic crystals(EOCs)with ultralong phosphorescence via introducing halogen atoms(Cl,Br,I)intoπ-conjugated phosphorescent molecules.Especially,the crystal containing iodine atoms displayed both excellent elasticity(ε=3.01%)and high phosphorescent efficiency(Φ_(Ph)=19.1%)owing to the strong halogen bonds.Taking advantage of its highly efficient UOP and excellent elasticity,we successfully used a DCz4I crystal for anti-counterfeiting application.These findings may provide guidance for the development of elastic crystals with afterglow and expand the scope of potential applications on flexible materials.
